Patent classifications
C08J11/16
Recycled pulp, absorbent, non-woven fabric, and sanitary article
Recycled pulp that derives from a used sanitary article includes an antibacterial activity value of 2.0 or more and an acid. Recycled pulp that derives from a used sanitary article includes an antibacterial activity value of 2.0 or more and an ash content of 0.65% by weight or less, and further includes an acid. The acid is a citric acid. The recycled pulp further includes a cationic antibacterial agent. The cationic antibacterial agent is a quaternary ammonium salt. The cationic antibacterial agent is a benzalkonium chloride or a cetylpyridinium chloride. At least a portion of the cationic antibacterial agent is adsorbed on the recycled pulp.
PRE-TREAMENT OF POLYOLEFIN WASTE TO IMPROVE DEPOLYMERIZATION
Pre-treatment methods for polyolefin-based feed streams before depolymerization are described. Polyolefins are separated from other material in the polyolefin-based feed stream using density differences in an aqueous solution, which allows for a pre-treatment method that does not affect the depolymerization catalyst. By removing the non-polyolefin materials from the feed stream, the depolymerization of the polyolefin material can proceed at lower temperatures for longer cycles. This results in a more efficient process with a smaller carbon footprint.
PRE-TREAMENT OF POLYOLEFIN WASTE TO IMPROVE DEPOLYMERIZATION
Pre-treatment methods for polyolefin-based feed streams before depolymerization are described. Polyolefins are separated from other material in the polyolefin-based feed stream using density differences in an aqueous solution, which allows for a pre-treatment method that does not affect the depolymerization catalyst. By removing the non-polyolefin materials from the feed stream, the depolymerization of the polyolefin material can proceed at lower temperatures for longer cycles. This results in a more efficient process with a smaller carbon footprint.
CLOSED-LOOP THERMOPLASTIC COPOLYMERS
The disclosed technology provides a thermoplastic copolymer comprising: a plurality of difunctional triketone species; (b) a plurality of a first diamine species, wherein the first diamine species contains one or more primary amine groups and/or one or more secondary amine groups, and wherein the first diamine species does not contain a tertiary amine group; a plurality of a second diamine species, wherein the second diamine species contains one or more primary amine groups and/or one or more secondary amine groups, wherein the second diamine species does not contain a tertiary amine group, and wherein the second diamine species is different than the first diamine species; and optionally, a plurality of monofunctional amine-reactive groups. Some embodiments provide segmented thermoplastic copolymers. Methods of making and using the thermoplastic copolymer are also described, including depolymerizing the thermoplastic copolymer to form recycled monomers. The recycled monomers may then be repolymerized in a closed-loop system.
CLOSED-LOOP THERMOPLASTIC COPOLYMERS
The disclosed technology provides a thermoplastic copolymer comprising: a plurality of difunctional triketone species; (b) a plurality of a first diamine species, wherein the first diamine species contains one or more primary amine groups and/or one or more secondary amine groups, and wherein the first diamine species does not contain a tertiary amine group; a plurality of a second diamine species, wherein the second diamine species contains one or more primary amine groups and/or one or more secondary amine groups, wherein the second diamine species does not contain a tertiary amine group, and wherein the second diamine species is different than the first diamine species; and optionally, a plurality of monofunctional amine-reactive groups. Some embodiments provide segmented thermoplastic copolymers. Methods of making and using the thermoplastic copolymer are also described, including depolymerizing the thermoplastic copolymer to form recycled monomers. The recycled monomers may then be repolymerized in a closed-loop system.
POLYMER RECYCLATE PROCESSES AND PRODUCTS
Methods for processing LLDPE recyclates including, but not limited to, polyethylene and polypropylene and compositions therefrom are provided. LLDPE recyclate can be visbroken to improve processing characteristics and/or devolatilized to remove waste byproducts to produce processed LLDPE recyclates. Processed LLDPE recyclates are compounded with pre-consumer polyolefins to produce blend compositions having acceptable or even improved processing characteristics. Such pre-consumer polyolefins can also be visbroken to further tailor processing characteristics of such polymer blends. A combination of extruders and/or extruder zones can be used at the same or different locations for visbreaking and/or compounding of both LLDPE recyclate and/or pre-consumer polyolefins.
Method For Treatment Of Waste Material And Reactor System Thereof
The reactor system comprises a reactor vessel with at least one inlet and a first and a second outlet, which reactor vessel is configured for depolymerisation of a condensation polymer and which first and second outlet are configured for removal of a first and a second part of a reaction mixture. The reactor system further comprises a heat exchanger downstream of the first outlet. Herein the second outlet is arranged at a lower position of the reactor vessel than the first outlet. The first outlet is configured for removal of the first part being a dispersion and/or solution comprising said condensation polymer and depolymerisation products thereof in a solvent. Said first part is led to the heat exchanger. The second outlet is configured for removal of the second part including agglomerates. The reactor system is used for depolymerisation of a condensation polymer.
Recycling of superabsorbent polymer with an extensional flow device
Poly(acrylic acid)-based superabsorbent polymer (SAP) in a feed stream is converted into poly(acrylic acid) (PAA) in an extensional flow device. The total energy used to degrade the SAP into PAA is less than about 50 MJ/kg SAP.
Recycling of superabsorbent polymer with an extensional flow device
Poly(acrylic acid)-based superabsorbent polymer (SAP) in a feed stream is converted into poly(acrylic acid) (PAA) in an extensional flow device. The total energy used to degrade the SAP into PAA is less than about 50 MJ/kg SAP.
Catalytic microwave depolymerisation of plastic for production of monomer and waxes
There is described a microwave pyrolysis process for the depolymerization of plastic for the production of monomers, waxes and heavy oils including the steps of: a) steam purge of the plastic from about 0.5% to about 50% w/w of a catalyst, in a media; b) pyrolysis of the plastic and the catalyst in the media with a microwave (MW) for a time sufficient to allow generation of heat providing a thermal treatment between 300° C. and 650° C. through absorption of microwaves by the catalyst and the media. The catalyst includes a compound having a high dielectric loss at the frequency of the MW to absorb microwaves, transfer heat to the plastic and initiate a pyrolysis reaction.