C08J2323/20

Particle size control of metallocene catalyst systems in loop slurry polymerization reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

POLYMERIC MATERIALS

A combination comprising a receptacle of defined internal volume, which contains a chemical reaction product. The product may be made in apparatus for undertaking a chemical reaction which comprises an elongate housing and a receptacle. The elongate housing may include a cooling means and end fittings which may include ports where fluids may be introduced and/or removed.

Particle size control of metallocene catalyst systems in loop slurry polymerization reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

DIELECTRIC MATERIAL AND MANUFACTURING METHOD THEREOF

Provided are a dielectric material and a method for manufacturing the same. The dielectric material includes: subjecting a foamed sphere obtained by a primary foaming to a second foaming in a second moulding chamber filled with CO.sub.2 at a second temperature in the range of 20° C. below T.sub.m to 5° C. below T.sub.m and under a second pressure of 15-20 MPa for 30-3600 min to obtain the dielectric material, wherein the primary foaming comprises specific steps of: foaming a foaming material sphere with a diameter of 20-800 mm in a first moulding chamber filled with CO.sub.2 at a first temperature in the range of 80° C. below T.sub.m to 20° C. below T.sub.m and under a first pressure of 15-20 MPa to obtain the foamed sphere. Further provided is a dielectric material manufactured by the method above.

Particle Size Control of Metallocene Catalyst Systems in Loop Slurry Polymerization Reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

Particle Size Control of Metallocene Catalyst Systems in Loop Slurry Polymerization Reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

Particle Size Control of Metallocene Catalyst Systems in Loop Slurry Polymerization Reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

CURABLE COMPOSITIONS COMPRISING UNSATURATED POLYOLEFINS

The present disclosure relates to unsaturated polyolefins and processes for preparing the same. The present disclosure further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking.

CURABLE COMPOSITIONS COMPRISING UNSATURATED POLYOLEFINS

Disclosed relates to unsaturated polyolefins and processes for preparing the same. Disclosed further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking.

CURABLE COMPOSITIONS COMPRISING UNSATURATED POLYOLEFINS

The present disclosure relates to unsaturated polyolefins and processes for preparing the same. The present disclosure further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking.