Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerizable therewith to said dispersion; and polymerizing vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.

The present invention includes a polymer composition of at least one vinylidene chloride/alkyl acrylate polymer having from about 3.4 to about 6.7 percent mole percent of mer units derived from at least one alkyl acrylate monomer polymerized with the vinylidene chloride and comprising a plasticizer and having at least one of the following compositional characteristics (1) and (2): (1) at least one low molecular weight vinyl chloride polymer having a molecular weight of at most about 70,000 Daltons in an amount sufficient to increase affinity for at least one ink; and (2) at least one methacrylic polymer in an amount sufficient to increase the affinity for at least one ink. Surfaces comprising such a composition and articles having such surfaces are surprisingly printable and are aspects of the invention as is printing thereon.

A method of manufacturing a coextruded and/or laminated and biaxially oriented composite film and a resulting multilayered film which has improved processability and/or improved recyclability. For this purpose, the method and multilayered film provides a novel combination of the density of various layer components of the composite film and certain manufacturing parameters such as the stretching factors, relaxation factors, relaxation temperatures, and residual stretching factors.

A polymer blend including a vinylidene chloride interpolymer; an ethylene-acrylate interpolymer; and optionally one or more additives selected from the group consisting of stabilizers, plasticizers, and processing aids is provided. Also provided is an extruded film and a packaging or container which includes the film.

A roof laminate (10) includes a roof membrane (12, 100, 200, 300) and a protective sheet (14, 114, 214, 314) removably affixed thereto. The surface (20) of the roof membrane (12, 100, 200, 300) can be protected from dirt, scratches and scrapes by a protective sheet (14, 114, 214, 314) which also provides other beneficial attributes that aid an installer. The membrane (12, 100, 200) and the sheet (14, 114, 214) are heat laminated together in the absence of adhesive and tackifiers. Alternatively, the membrane (12, 300) and the sheet (14, 314) are surface treated and then brought into contact with one another in the absence of adhesive and tackifiers. The sheet (14, 114, 214, 314)) may be single layer or include at least a first layer (30) directly secured to a second layer (32). The first layer (30) provides at least one of UV protection, anti-slip, and anti-glare to the roof laminate (10) and so aids the installer in at least one of those respects. The second layer (32) is removably affixed to the roof membrane (12, 100, 200, 300).

Provided is a polyamide film which is a stretched film including a polyamide resin composition containing 1 to 10% by mass of a polyester thermoplastic elastomer, wherein the polyamide film satisfies all of the following conditions (A) to (C): (A) elastic moduli in MD and TD of the film are each 1.0 to 2.3 GPa; (B) a ratio between the elastic moduli in MD and TD of the film (MD/TD) is 0.9 to 1.5; and (C) a haze of the film is 7% or less.

The packaged 3-dimensional modeling powder material, including 3-dimensional modeling powder material including plural types of particles, and a storage container configured to contain the modeling powder material in an inside of the storage container in a pressured state.

Provided is a process for preparing a PVDC additive blend in which an additive is blended with PVDC under high shear blending to produce a highly uniform blend in which the additive is homogeneously distributed throughout the PVDC. It has been found that performing high shear blending in multiple successive stages in which the concentration of the additive in the blend is reduced in each successive stage helps in prove the uniformity of the PVDC additive blend. For example, the high shear blending may be carried out in 2 to 6 stages, and in particular, from 2 to 4 stages. Also provided is a PVDC additive blend having a uniform blend of PVDC and an additive, such as a blend of a PVDC copolymer of vinylidene chloride and methyl acrylate and a fluorescing agent, such as 2,2′(2,5-thiophenylendiyl)bis(5-tert-butylbenzoxazole).

A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of β-keto esters, β-keto amides, β-diketones, cyanoacetic esters, malonates, nitroalkanes, β-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.

A method of forming a polymeric vacuum insulation board is provided, the polymeric vacuum insulation board including a plurality of evacuated, closed-cell pores therein. In one embodiment, the method includes intermixing a polymer with zeolite particles that contain water and extruding the resulting composition under high pressure. During extrusion, water in the zeolite particles evaporates and creates a porous, closed-cell microstructure within a polymer matrix. As the polymer matrix cools and solidifies, water vapor is reabsorbed by the zeolite, which at least partially evacuates the closed-cell pores. In another embodiment, the method includes intermixing a polymer with expandable graphite particles and extruding the resulting composition under high pressure. During extrusion, the expandable graphite particles define evacuated voids. The polymer binder can be selected to include low gas permeance, for example ethylene vinyl alcohol (EvOH) or polyvinylidene chloride (PVDC). In some applications, the polymer can be blended with nano-clays or other additives to further decrease the gas permeance of the vacuum insulation board.