A sheet containing a carbon fiber and a fluororesin layer disposed around a carbon monofilament constituting the carbon fiber. A fluororesin constituting the fluororesin layer is polyvinylidene fluoride. Further, the sheet has a tensile strength of 400 MPa or higher. Also disclosed is a laminate including a first layer and a second layer that is disposed on the first layer and that includes the sheet; a pipe including the laminate; a riser tube including the pipe and a flowline including the pipe.

The present invention relates to a porous membrane including a polymer including a polyvinylidene fluoride-based resin as a main component, and a branched polyvinylidene fluoride-based resin as the polyvinylidene fluoride-based resin, in which the polymer has a value of a of 0.32 to 0.41 and a value of b of 0.18 to 0.42, each of which is determined by approximation according to the formula 1 below from a radius of gyration <S.sup.2>.sup.1/2 and an absolute molecular weight M.sub.w of the polymer which are measured by GPC-MALS (gel permeation chromatograph equipped with a multi-angle light scattering detector). <S.sup.2>.sup.1/2=bM.sub.w.sup.a (Formula 1)

A material comprising a fine fiber pulp is provided. The fine fiber pulp has a plurality of fine fibers have an average diameter of less than 1 micron and an average length of less than 1 millimeter. In embodiments, the fine fibers formed of a polymer. The material can be created according to a method in which the fine fiber strands are formed from a polymer melt or a polymer solution, the fine fiber strands are cooled to a temperature of less than −25° C. to increase brittleness of the fine fibers, and the fine fiber strands are granulated into the fine fiber pulp.

The invention relates to a method for preparation of a polymer from monomers comprising polyvinylidene fluoride, trifluoroethylene and a third monomer, the method successively comprising: injection of all the monomers to react into a reactor; initiation of a polymerization of the monomers; a continuation step (a) of the polymerization of the monomers, during which a drop in pressure in the reactor is compensated.

A composite particle includes a discrete, hollow, ceramic spheroid and a fluoropolymer layer disposed thereon. The fluoropolymer is a homopolymer or copolymer of a perfluoroalkyl vinyl ether; a perfluoroalkoxy vinyl ether; at least one fluoroolefin independently represented by formula C(R).sub.2═CF—Rf, wherein Rf is fluorine or a perfluoroalkyl having from 1 to 8 carbon atoms and R is hydrogen, fluorine, or chlorine; or a combination thereof. Methods of making the composite particles, composite materials, and articles including them are also disclosed.

A polyvinylidene fluoride film composition and a polyvinylidene fluoride isolation film are provided. The polyvinylidene fluoride film composition includes a polyvinylidene fluoride, a polyetherimide, and a polyether-type nonionic surfactant. The weight ratio of the polyvinylidene fluoride to the polyetherimide is 1:1 to 19:1, and the content of the polyether-type nonionic surfactant is 0.1% to 10% by weight based on a total of 100% by weight of the polyvinylidene fluoride film composition.

Ion exchange membranes may comprise a polymeric microporous substrate and a cross-linked ion transferring polymeric layer on the substrate. The cross-linked ion transferring polymeric layer may comprise a polymerization product of at least a functional monomer and a low value r.sub.2/r.sub.s monomer. The ion exchange membranes may have an apparent permselectivity of at least about 95% and a resistivity of less than about 1.5 Ohm-cm.sup.2.

The present invention relates to new compositions for bipolar plates and processes for manufacturing said compositions. More particularly, the invention relates to a process for manufacturing a composition, comprising the following steps:—mixing a thermoplastic polymer in the molten state with a first conductive filler in order to obtain a conductive thermoplastic polymer,—grinding said conductive thermoplastic polymer in order to reduce it to powder;—mixing the conductive thermoplastic polymer powder with a second conductive filler.”

Highly energy efficient electrodialysis membranes having low operating costs and a novel process for their manufacture are described herein. The membranes are useful in the desalination of water and purification of waste water. They are effective in desalination of seawater due to their low electrical resistance and high permselectivity. These membranes are made by a novel process which results in membranes significantly thinner than prior art commercial electrodialysis membranes. The membranes are produced by polymerizing one or more monofunctional ionogenic monomers with at least one multifunctional monomer in the pores of a porous substrate.

Methods for forming a graft copolymer of a poly(vinylidene fluoride)-based polymer and at least one type of electrically conductive polymer, wherein the electrically conductive polymer is grafted on the poly(vinylidene fluoride)-based polymer are provided. The methods comprise a) irradiating a poly(vinylidene fluoride)-based polymer with a stream of electrically charged particles; b) forming a solution comprising the irradiated poly(vinylidene fluoride)-based polymer, an electrically conductive monomer and an acid in a suitable solvent; and c) adding an oxidant to the solution to form the graft copolymer. Graft copolymers of a poly(vinylidene fluoride)-based polymer and at least one type of electrically conductive polymer, wherein the electrically conductive polymer is grafted on the poly(vinylidene fluoride)-based polymer, nanocomposite materials comprising the graft copolymer, and multilayer capacitors comprising the nanocomposite material are also provided.