A film having a dielectric dissipation factor at a frequency of 1 kHz and 160° C. of 0.02% or lower and a dielectric breakdown strength at 160° C. of 400 V/μm or higher. Also disclosed is a film including at least one fluoropolymer selected from a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer, the fluoropolymer having a crystallinity of 65% or higher.

Disclosed are a superhydrophobic and self-cleaning radiative cooling film and a preparation method thereof. The preparation method includes the following steps: 1) dissolving P (VDF.sub.x-HFP.sub.y) and PDMS in a composite polar solvent to obtain a translucent composite polymer solution of P (VDF.sub.x-HFP.sub.y)/PDMS; 2) adding a non-solvent dropwise to the obtained solution to allow for a phase separation of P (VDF.sub.x-HFP.sub.y)/PDMS to form a sol; 3) casting the sol; drying the cast sol to obtain a film are porous inside with micro/nano rough structures of low surface-energy on the surface. The preparation method of the present invention is simple, and can be used for large-scale production.

Disclosed are a superhydrophobic and self-cleaning radiative cooling film and a preparation method thereof. The preparation method includes the following steps: 1) dissolving P (VDF.sub.x-HFP.sub.y) and PDMS in a composite polar solvent to obtain a translucent composite polymer solution of P (VDF.sub.x-HFP.sub.y)/PDMS; 2) adding a non-solvent dropwise to the obtained solution to allow for a phase separation of P (VDF.sub.x-HFP.sub.y)/PDMS to form a sol; 3) casting the sol; drying the cast sol to obtain a film are porous inside with micro/nano rough structures of low surface-energy on the surface. The preparation method of the present invention is simple, and can be used for large-scale production.

A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.

A polyphenylene sulfide resin composition is obtained by mixing a polyphenylene sulfide resin (a), a fluororesin (b) and an organosilane compound (c). When a resin phase-separated structure of a molded product formed from the polyphenylene sulfide resin composition is observed by an electron microscope, the component (a) forms a continuous phase, the component (b) forms a primary dispersed phase having a number-average dispersion diameter of not greater than 1 m, and a secondary dispersed phase of the component (a) is included in the primary dispersed phase of the component (b).

Provided is a highly stable non-aqueous dispersion even without surfactants. The present invention relates to a non-aqueous dispersion including a fluoropolymer and a non-aqueous solvent, the fluoropolymer in the non-aqueous dispersion having an average dispersed particle size of smaller than 1.0 m, the fluoropolymer being present in an amount of 5 to 45% by mass, the non-aqueous solvent having a surface tension of 30 mN/m or lower, the non-aqueous dispersion containing a surfactant in an amount of less than 0.1% by mass relative to the fluoropolymer.

A film having a dielectric dissipation factor at a frequency of 1 kHz and 160 C. of 0.02% or lower and a dielectric breakdown strength at 160 C. of 400 V/m or higher. Also disclosed is a film including at least one fluoropolymer selected from a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer, the fluoropolymer having a crystallinity of 65% or higher.

Light transparent fluoropolymer composition having less than 2 percent haze, comprising at least one of alkali metal (e.g., lithium, sodium, and potassium) cation, alkali metal (e.g., lithium, sodium, and potassium) and a corresponding anion (e.g., CO.sub.3,OH, OOCCH.sub.3), alkaline earth metal cation (e.g., calcium, magnesium, strontium, and barium), or alkaline earth metal cation (e.g., calcium, magnesium, strontium, and barium) and a corresponding anion (e.g., CO.sub.3,OH, OOCCH.sub.3), wherein the light transparent fluoropolymer has at least 90% visible light transmission. Exemplary uses of light transparent fluoropolymer compositions described herein include as films (e.g., solar reflective films, solar transparent frontside photovoltaic films, commercial graphic overlay film, commercial graphic film, and tubing (e.g., transparent tubing for medical)).

In one aspect, a foamable composition is disclosed, which comprises a base polymer, talc and a citrate compound blended with the base polymer. In some embodiments, the concentration of the talc in the composition is in a range of about 0.05% to about 25% by weight, e.g., in a range of about 2% to about 20%, or in a range of about 3% to about 15%, or in a range of about 5% to about 10%. Further, the concentration of the citrate compound in the composition can be, for example, in a range of about 0.05% to about 3% by weight, or in a range of about 0.02% to about 0.9% by weight, or in a range of about 0.03% to about 0.8% by weight, or in a range of about 0.04% to about 0.7% by weight, or in a range of about 0.05% to about 0.6% by weight.

A method for preparing a pyroelectric polymer film based on a combined process of solution casting and uniaxial stretching is disclosed. The pyroelectric polymer film is firstly prepared by solution casting, afterwards, the casted film is subjected to uniaxial stretching when the film is in a semi-cured state (wet film). Thus a larger stretching ratio (>10) at a lower temperature (even at room temperature) is realized. Without undergoing a further poling process, the as-stretched film does have a fairly, good pyroelectric performance. Moreover, the surface of the stretched film is smoother and has fewer surface defects.