The invention relates to a noncrosslinked gelled carbonaceous composition and a pyrolyzed composition respectively forming an aqueous polymer gel and the pyrolysate thereof in the form of porous carbon. The invention also relates to the production method thereof, to a porous carbon electrode formed by the pyrolyzed composition, and to a supercapacitor containing said electrodes. The gelled, noncrosslinked composition (G2) is based on a resin created at least partly from polyhydroxybenzene(s) R and formaldehyde(s) F and comprises at least one hydrosoluble cationic polyelectrolyte P. According to the invention, the composition forms a rheofluidifying physical gel. A pyrolyzed carbonaceous composition according to the invention, consisting of a carbon monolith, is the product of coating, crosslinking, drying and pyrolysis of the non-crosslinked gelled composition, the carbon monolith being predominantly microporous and able to form a supercapacitor electrode having a thickness of less than 1 mm.

A method for producing a composite material, includes: immersing a carbon fiber bundle, including continuous carbon fibers, in a dispersion in which carbon nanotubes are dispersed in water, alcohol, or organic solvent; applying a tensile force to the carbon fibers, which are linearly arranged, using flat rollers; moving the carbon fibers linearly, under the tensile force by the flat rollers, at a constant depth inside the dispersion at a traveling speed of 1 to 20 m/min, such that the carbon nanotubes in the dispersion are adhered to respective surfaces of the carbon fibers; and applying a sizing agent to cover at least a part of the respective surfaces.

Provided is a gelled carbon-based composition forming an organic polymeric monolithic gel capable of forming a porous carbon monolith by pyrolysis, a use thereof and a process for preparing this composition. A composition according to the invention is based on a resin derived at least partly from polyhydroxybenzene(s) R and formaldehyde(s) F, has a thermal conductivity of less than or equal to 40 mW.Math.m.sup.1.Math.K.sup.1, and includes at least one water-soluble cationic polyelectrolyte P. A process for preparing this composition comprises: a) polymerization, in an aqueous solvent, of the polyhydroxybenzene(s) and formaldehyde(s), in the presence of at least one cationic polyelectrolyte dissolved in this solvent and of a catalyst, in order to obtain a solution based on the resin, b) gelling of the solution in order to obtain a gel, and c) drying in order to obtain the organic polymeric monolithic gel.

The invention relates to a gelled carbon-based composition forming an organic polymeric monolithic gel which is suitable for forming an aerogel by drying, to uses and to a process for preparing this carbon-based composition. The invention applies especially to the production of such gels having a very low density and a very low heat conductivity, a very high specific surface area and a satisfactory compression strength, for their use as thermal superinsulators or as carbon-based electrode precursors of supercondensers. A composition according to the invention comprises a resin at least partly derived from polyhydroxybenzenes H and from formaldehyde(s) F, said polyhydroxybenzenes comprising at least one unsubstituted polyhydroxybenzene R and at least one polyhydroxybenzene substituted with one or two alkyl groups. This composition is such that said polyhydroxybenzenes comprise several said unsubstituted polyhydroxybenzenes R and R and in that the composition comprises a water-soluble cationic polyelectrolyte P.

The present invention relates to a flexible composite organic aerogel (1) comprising: a textile reinforcement (5), an organic aerogel (3) placed within said textile reinforcement (3),
said organic aerogel (3) being based on a resin resulting at least in part from polyhydroxybenzene(s) R and formaldehyde(s) F,
said organic aerogel (3) being a polymeric organic gel comprising at least one water-soluble cationic polyelectrolyte,
or said organic aerogel (3) being a pyrolysate of said gel in the form of a porous carbon monolith comprising the product of the pyrolysis of said at least one water-soluble cationic polyelectrolyte P,
said organic aerogel (3) exhibiting a specific thermal conductivity of between 10 and 40 mW.Math.m.sup.1.Math.K.sup.1 at atmospheric pressure.

A sliding contact surface-forming material includes a reinforcing base impregnated with a resol-type phenolic resin having polytetrafluoroethylene resin dispersed therein. The reinforcing base is composed of a woven fabric formed by using, respectively as the warp and the weft, a ply yarn which is formed by paralleling at least two strands of a single twist yarn spun from fluorine-containing resin fiber and a single twist yarn spun from polyphenylene sulfide fiber, and by twisting them in the direction opposite to the direction in which the single twist yarns were spun. Also, a multi-layered sliding contact component having the overall shape of a flat plate or a circular cylinder includes the sliding contact surface-forming material so as to configure at least the sliding-contact surface thereof.

A sliding contact surface-forming material with improved friction-proof and wear-proof characteristics under dry friction conditions such as in the open air, while keeping the low swelling, friction-proof, and wear-proof characteristics under moist atmosphere typically under water unchanged, wherein the sliding contact surface-forming material includes a reinforcing base impregnated with a resol-type phenolic resin having polytetrafluoroethylene resin dispersed therein, the reinforcing base being composed of a woven fabric formed by using, respectively as the warp and the weft, a ply yarn which is formed by paralleling at least two strands of a single twist yarn spun from fluorine-containing resin fiber and a single twist yarn spun from polyphenylene sulfide fiber, and by twisting them in the direction opposite to the direction in which the single twist yarns were spun.

A fiber-reinforced aerogel is disclosed. The aerogel can include a porous organic polymer matrix and fibers included in the porous organic polymer matrix. The aerogel can include a thermal conductivity of less than or equal to 60 mWIm.Math.K at a temperature of 20? C., at least a bimodal pore size distribution with a first mode of pores having an average pore size of less than or equal to 50 nanometers (nm) and a second mode of pores having an average pore size of greater than 50 nm, and a planar shape having a thickness of 5 millimeters (mm) or less and is capable of being rolled up into a roll, wherein the fibers form a woven fiber matrix.

An ultra-thin film of a thermosetting resin, such as a phenolic resin, can be produced by a method that includes introducing a solution containing an aldehyde-based compound and a compound (A) capable of undergoing addition condensation with an aldehyde-based compound into an electrochemical cell, which includes a working electrode and a counter electrode, and applying a positive potential to the working electrode to form a thin film on the working electrode.

The present invention relates to a vacuum insulation board (1) comprising: a hermetically closed covering (3) in which the pressure is lower than atmospheric pressure, a core material (5) made of organic aerogel placed inside said covering (3),
said organic aerogel being based on a resin resulting at least in part from polyhydroxybenzene(s) R and formaldehyde(s) F,
said organic aerogel being a polymeric monolithic organic gel comprising at least one water-soluble cationic polyelectrolyte,
or said organic aerogel being a pyrolysate of said gel in the form of a porous carbon monolith comprising the product of the pyrolysis of said at least one water-soluble cationic polyelectrolyte P,
said organic aerogel exhibiting a specific thermal conductivity of between 10 and 40 mW.Math.m.sup.1.Math.K.sup.1 at atmospheric pressure.