Foamed reactor made thermoplastic polyolefins (rTPOs), and articles made therefrom, are described. The compositions have an rTPO combined with a foaming agent. The foaming agent can be a physical blowing agent and/or a chemical foaming agent, and may include optional nucleating agents. Some compositions utilize a masterbatch having one or more chemical foaming agents to foam the rTPOs. The rTPOs have a large melt flow rate range and flexural modulus range that translate into a broad scope of potential applications and foamed architecture. This allows the combination of rTPOs and foaming agents to be fine-tuned for selected foaming application.

A fiber-reinforced polymer composition that comprises a polymer matrix that contains a propylene polymer is provided. The polymer matrix constitutes from about 30 wt. % to about 80 wt. % of the composition, and a plurality of long reinforcing fibers that are distributed within the polymer matrix. The fibers constitute from about 20 wt. % to about 70 wt. % of the composition. The polymer composition exhibits a spiral flow length of about 450 millimeters or more as determined in accordance with ASTM D3123-09, and after aging at a temperature of 150° C. for 1,000 hours, a Charpy unnotched impact strength greater than about 15 kJ/m.sup.2 as determined at a temperature of 23° C. in accordance with ISO Test No. 179-1:2010.

The present invention is directed to a polypropylene composition (C) comprising a heterophasic propylene copolymer and an inorganic filler, the use of said polypropylene composition (C) for the production of a foamed article and a foamed article obtained from said polypropylene composition (C).

Films made from metallocene-catalyzed polyethylene polymers, optionally, with other polymers, are disclosed.

Disclosed is a fiber-reinforced polypropylene-based resin composition including a propylene-based polymer (A) and reinforcing fibers (B), in which when a content of at least one olefin-derived structural unit selected from ethylene and an -olefin having 4 to 8 carbon atoms in the propylene-based polymer (A) is designated as E (% by mass) (the sum of the propylene-based polymer (A) and the reinforcing fibers (B) is designated as 100% by mass), and a mesopentad fraction of the propylene-based polymer (A) as measured by .sup.13C-NMR is designated as M (%), the following Expression (1) and Expression (2) are satisfied, the fiber-reinforced polypropylene-based resin composition being a resin composition with which a molded product having excellent thermal and mechanical characteristics and having an excellent external appearance of the molded product surface (particularly, external appearance of a grained surface) can be produced.
85M99(1)
74M12E90(2)

Presented herein are materials, methods, and systems for the improved 3D printing improved 3D printing of materials that include polypropylene. In some embodiments, the present disclosure provides a composite comprising a polymer matrix and a plurality of fibers for improved 3D printing. For example, the polymer matrix may have a composition that includes a polymer blend of polypropylene (PP) and polyethylene (PE) (e.g., high density polyethylene (HDPE), low density polyethylene (LDPE), linear low-density polyethylene (LLDPE)), impact modified polypropylene copolymer and/or polypropylene random copolymer with a plurality of fibers. In some embodiments, the plurality of fibers comprises cellulosic nanofibers (e.g., natural cellulosic nanofibers, e.g., cellulose nanofibrils). In some embodiments, filaments are prepared from the composites by melt compounding the polymer matrix (e.g., PP copolymers and/or PP/PE pellets) with a plurality of fibers and extruding the mixture.

The present invention is related to a composition with about 80 wt % to about 95 wt % of a polymer blend, wherein the polymer blend comprises (a) about 3 wt % to about 25 wt % of a first propylene-based elastomer based on the polymer blend, and (b) about 75 wt % to about 97 wt % of a second propylene-based elastomer based on the polymer blend; and about 5 wt % to about 20 wt % of an ethylene-based polymer; wherein the first propylene-based elastomer and the second propylene-based elastomer each comprise the following: propylene and from about 2 to about 25 wt % units derived from one or more C.sub.2 or C.sub.4-C.sub.12 alpha-olefins; triad tacticity greater than about 90% and a heat of fusion less than about 75 J; and wherein the first propylene-based elastomer is different from the second propylene-based elastomer.

A composition suitable for a film having a 1% secant flexural modulus (MD or TD) of at least 55,000 psi and a dart drop impact of at least 500 g is provided. The composition comprises a broad molecular weight distribution polypropylene with at least 50 mol % propylene and having: a molecular weight distribution (Mw/Mn) greater than 6, a branching index (gvis) of at least 0.95, and a melt strength of at least 2 cN; and a polyethylene with at least 70 mol % ethylene and having: a density of from 0.910 to 0.923 g/cm.sup.3, a melt index (I.sub.2) of from 0.1 to 1.2 g/10 min, a melt index ratio (I.sub.21/I.sub.2) of from 20 to 35, a weight average molecular weight (M.sub.w) of from 150,000 to 400,000 g/mol, and an orthogonal comonomer distribution and/or at least a first peak and at least a second peak in a comonomer distribution analysis.

In an embodiment, a heat-seal film includes 10-90 wt % of a first polymer component and 10-90 wt % of a second polymer component, based on a total weight of the first polymer component and the second polymer component, wherein: the first polymer component includes propylene, and optionally, up to 18 wt % of a C.sub.2 and/or a C.sub.4-C.sub.20 -olefin based on a total weight of the first polymer component; and the second polymer component includes 91-99.9 wt % of propylene and 0.1-9 wt % of ethylene based on a total weight of the second polymer component, the second copolymer component having a melt flow rate of 2-60 g/10 min. In another embodiment, a multi-layer film structure includes a heat-seal layer including a heat-seal film described herein; and an unoriented, an uniaxially oriented, or a biaxially oriented base layer including polypropylene homopolymer, a polypropylene random copolymer, or a combination thereof.

An elastomeric article is provided that includes a composition having a silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm.sup.3. The elastomeric article can exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70 C.). The silane-crosslinked polyolefin elastomer can include a first polyolefin having a density less than 0.86 g/cm.sup.3, a second polyolefin having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, and a condensation catalyst.