C08J2423/24

Wax composition comprising linear hydrocarbons, branched hydrocarbons and oxidized hydrocarbons, aqueous dispersion thereof, method to produce such wax composition and dispersion and use thereof as Carnauba wax replacement
11965097 · 2024-04-23 · ·

The invention relates to a wax composition comprising linear hydrocarbons, branched hydrocarbons and oxidized hydrocarbons, wherein the composition is characterized by a congealing point from 68? C. to 110? C., an acid number in the range of 3 to 30 mg KOH/g, a saponification number of 20 to 90 mg KOH/g and a needle penetration at 25? C. of below 15 1/10 mm. The invention further relates to an aqueous dispersion comprising the wax composition and a method of manufacture of both the wax composition and the dispersion. The wax composition can be used to fully or partially substitute Carnauba wax or Candelilla wax.

DILUTION INDEX

This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Y.sub.d) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X.sub.d) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 25 and a CDBI.sub.50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Polyethylene compositions

A polyethylene composition including the product of the combination of at least one copolymer made from units derived from at least 85 wt % ethylene and a C.sub.3 to C.sub.10 -olefin and from 0.10 wt % to 10 wt % of a cyclic-diene terpolymer is provided.

DILUTION INDEX

This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Y.sub.d) greater than 0; total catalytic metal 3.0 ppm; 0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X.sub.d) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 25 and a CDBI.sub.50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Caps and closures

This disclosure relates to caps and closures manufactured from an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Y.sub.d) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X.sub.d) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 20 dg/minute, a density from about 0.948 to about 0.968 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 25 and a CDBI.sub.50 from about 54% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Ethylene interpolymer films

This disclosure relates to multilayer films having improved caulkability. These multilayer films have at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Y.sub.d) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X.sub.d) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 25 and a CDBI.sub.50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Rotomolded articles

This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Y.sub.d) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X.sub.d) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 25 and a CDBI.sub.50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Dilution index

This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Y.sub.d) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X.sub.d) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 25 and a CDBI.sub.50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Rotomolded articles

This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product and an ethylene polymer, where the ethylene interpolymer product has a Dilution Index (Y.sub.d) greater than 0 and improved Environmental Stress Crack Resistance (ESCR). The ethylene interpolymer product has a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 6 and a CDBI.sub.50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Films produced from ethylene interpolymer products

This disclosure relates to films comprising at least one layer of an ethylene interpolymer product. The ethylene interpolymer product comprises a first ethylene interpolymer, a second ethylene interpolymer and optionally a third ethylene interpolymer; wherein the ethylene interpolymer product has ?0.03 terminal vinyl unsaturations per 100 carbon atoms and ?3 parts per million (ppm) of a total catalytic metal; and optionally a Dilution Index, Y.sub.d, greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.4 to about 10 dg/minute, a density from about 0.900 to about 0.940 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 12 and a CDBI.sub.50 from about 20% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.