A coating composition including the following five components 1) to 5): 1) a fluorine-containing multifunctional (meth)acrylate; 2) a binder component that is free of fluorine and reacts with the 1) component; 3) metal oxide nanoparticles each including an organic group on a surface thereof; 4) a solvent having a total (P+H) of 8 MPa.sup.1/2 or more, the total (P+H) being a total of a polar term SP and a hydrogen bond term SH in Hansen solubility parameters; and 5) a reaction initiator.

According to the present invention, there are provided a film forming composition, which contains a polymer having a repeating unit represented by General Formula (I) and a curable compound, an optical film having a film formed of the composition, a hardcoat film, a polarizing plate, and a method for manufacturing a hydrophilized hardcoat film. In General Formula (I),

##STR00001##

R.sup.1 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, L represents an ester bond, an ether bond, a phenylene group, or an amide bond, R.sup.2 and R.sup.4 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, or a halogenated alkyl group having 1 to 20 carbon atoms, and R.sup.3 represents a hydrogen atom or a substituent.

##STR00002##

Provided is a barrier film, comprising a base layer and an inorganic layer including a first region and a second region, which have different elemental contents (atomic %) of Si, N, and O from each other as measured by XPS, and having a compactness expressed through an etching rate of 0.17 nm/s in the thickness direction for an Ar ion etching condition to etch Ta.sub.2O.sub.5 at a rate of 0.09 nm/s, wherein the second region has a higher elemental content of N than that of the first region, and the second region has a thickness of 10% or more relative to the total thickness of the inorganic layer. The barrier film has excellent barrier properties and optical properties and can be used for electronic products which are sensitive to moisture and the like.

Additive manufacturing processes featuring consolidation of thermoplastic particulates may form printed objects in a range of shapes. Inorganic nanoparticles disposed upon the outer surface of the thermoplastic particulates may improve flow performance of the thermoplastic particulates during additive manufacturing, but may be undesirable to incorporate in some printed objects. Polymer nanoparticles may be substituted for inorganic nanoparticles in some instances to address this difficulty and provide other advantages. Particulate compositions suitable for additive manufacturing may comprise: a plurality of thermoplastic particulates comprising a thermoplastic polymer and a plurality of polymer nanoparticles disposed upon an outer surface of the thermoplastic particulates, the polymer nanoparticles comprising a crosslinked fluorinated polymer.

To provide a method for producing a liquid repellent molded product, whereby it is possible to uniformly apply, on the surface of a resin molded product, a liquid repellent composition containing an aqueous liquid having a compound having a perfluoroalkyl group with at most 6 carbon atoms dissolved or dispersed in an aqueous medium, and to obtain a liquid repellent molded product having excellent liquid repellency. The method for producing a liquid repellent molded product, comprises applying a liquid repellent composition comprising a fluorinated copolymer having structural units based on a monomer having a C.sub.4-6 perfluoroalkyl group, water and a C.sub.1-4 alcohol, to a resin molded product, and is characterized in that the content of the alcohol is from 70 to 99.9 mass % based on 100 mass % of the liquid repellent composition, and the application amount of the liquid repellent composition to the resin molded product is from 0.001 to 0.2 g/m.sup.2 as the amount of fluorine atoms.

Compositions, devices, and methods are disclosed for the covalent modification of polymer surfaces with graft copolymers having a blend of side chains. The halogenated acrylic and polyalkylene glycol acrylic side chains of the graft copolymer provide the polymer surface with high hydrophobicity, as well as increased resistance to biofouling with proteinaceous material. The polymer surfaces can be particularly useful in microfluidic devices and methods that involve the contacting of the covalently modified polymer surfaces with emulsions of aqueous droplets containing biological macromolecules within an oil carrier phase.

A fluorine-containing copolymer includes: a repeating unit represented by General Formula (I) and a repeating unit represented by General Formula (II), a composition containing the fluorine-containing copolymer, an optical film having a layer formed of the composition, a hardcoat film, a polarizing plate, and a touch panel display, and a method for producing a fluorine-containing copolymer.

##STR00001##

R.sup.1, R.sup.10, and R.sup.3 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R.sup.2 represents an alkyl group having 1 to 20 carbon atoms in which at least one carbon atom has a fluorine atom as a substituent, and L represents a divalent linking group constituted of at least one group selected from the group consisting of O, (CO)O, O(CO), divalent chain-like groups, and divalent aliphatic cyclic groups.

A gas barrier film including a polymer base, an undercoat layer that contains, as the main component, an acrylic resin having at least one side chain selected from the group consisting of the side chains (I) to (III) mentioned below, and an inorganic layer, wherein the undercoat layer and the inorganic layer are arranged in this order on at least one surface of the polymer base in such a manner that the undercoat layer and the inorganic layer are in contact with each other: (I) a side chain having an acrylic polymer skeleton; (II) a side chain having a dimethylsiloxane skeleton; and (III) a side chain having a skeleton containing a fluorine atom.

An underfill material enabling voidless packaging and excellent solder bonding properties, and a method for manufacturing a semiconductor device using the same are provided. An underfill material, including an epoxy resin, an acid anhydride, an acrylic resin, and an organic peroxide, the minimum melt viscosity being between 1000 Pa*s and 2000 Pa*s, and gradient of melt viscosity between 10 C. higher than the minimum melt viscosity attainment temperature and a temperature 10 C. higher being between 900 Pa*s/ C. and 3100 Pa*s/ C., is applied to a semiconductor chip having a solder-tipped electrode formed thereon, and the semiconductor chip is mounted onto a circuit substrate having a counter electrode opposing the solder-tipped electrode, and the semiconductor chip and the circuit substrate are thermocompressed under bonding conditions of raising the temperature from a first temperature to a second temperature at a predetermined rate.

The present invention provides a porous polytetrafluoroethylene membrane having a surface coated with a liquid-repellent agent. In this porous polytetrafluoroethylene membrane, the liquid-repellent agent is a polymer obtained by polymerization of monomers consisting essentially of CH.sub.2CHCOOCH.sub.2CH.sub.2C.sub.6F.sub.13. This porous polytetrafluoroethylene membrane is suitable for use as a gas-permeable membrane that allows passage of gases but prevents entry of liquids and/or dust, specifically as a waterproof sound-transmitting membrane, a waterproof gas-permeable membrane, or a dustproof gas-permeable membrane.