The present disclosure belongs to the technical field of coatings, and in particular relates to a graphene-modified silicon-titanium nano-polymer slurry, and a preparation method and use thereof. When the graphene-modified silicon-titanium nano-polymer slurry provided by the present disclosure is added to a polymer coating, the high resistance of graphene to gas and liquid permeation and the silicon-titanium graphene network structure can significantly increase the resistance of a formed coating layer to medium permeation; due to the corrosion resistance of graphene, titanium, and silicon nanoparticles, a formed coating layer has very high stability, is not easy to react with various media such as an acid, an alkali, and a salt, is not easily consumed to form pores, and is not easy to react with corrosive media to generate soluble salts or cathodic loose and expanded products, which ensures the long-term stability of a composition and a structure of the coating layer.

A method for continuously preparing graphene powder directly dispersed in an organic system, including: mixing an aqueous graphene oxide dispersion, an emulsifier and an oil-soluble monomer followed by pH adjustment and dispersing to obtain a pre-emulsified dispersion; subjecting the pre-emulsified dispersion to an emulsion polymerization reaction in the presence of an initiator; introducing a reducing agent to reduce graphene oxide; and subjecting the reaction mixture after emulsion polymerization to spray drying to obtain the graphene powder. Equipment used in the preparation method is also provided herein.

The invention described herein provides a dry graphene powder composition comprising pristine graphene flakes, wherein the pristine graphene flakes are non-covalently functionalised with polymeric amphiphilic molecules and wherein the dry graphene powder composition is capable of forming a stable homogeneous dispersion in aqueous or alcoholic media, in the absence of free dispersants or stabilizers, as well as methods for producing same, and the use thereof in graphene inks, for 2D and 3D printing, for production of flexible circuits, electrodes, electrocatalysts, for fabrication of nanocomposites and for wet-spinning of pristine graphene fibers.

A method for forming a golf ball with a graphene core disclosed herein. The method includes mixing a graphene masterbatch material with a polybutadiene material to form a core mixture, wherein the graphene masterbatch material comprises graphene in an amount from 0.1 to 80.0 weight percent of the graphene masterbatch material mixed with a carrier polymer in an amount from 99.9 to 20 weight percent of the graphene masterbatch material.

A method for forming a golf ball with a graphene core disclosed herein. The method includes mixing a graphene masterbatch material with a polybutadiene material to form a core mixture, wherein the graphene masterbatch material comprises graphene in an amount from 0.1 to 80.0 weight percent of the graphene masterbatch material mixed with a carrier polymer in an amount from 99.9 to 20 weight percent of the graphene masterbatch material.

A composite material includes a combination including a thermoplastic resin mixed with a polypropylene-graft-maleic anhydride (PPgMA), and a plurality of carbon particles mixed in the combination. The plurality of carbon particles may include a first region having a relatively low concentration of carbon particles, and a second region having a relatively high concentration of carbon particles, at least some of the plurality of carbon particles having exposed carbon surfaces with carbon atoms bonded to molecular sites on adjacent PPgMA molecules and oxidized with one or more oxygen-containing groups. In some aspects, composite material further includes between 80 wt. % and 90 wt. % of the thermoplastic resin, between 0.5 wt. % and 15 wt. % of the PPgMA, and between 0.1 wt. % to 7 wt. % of carbon particles. The composite material may also include a plurality of pores, formed in the combination, and configured to be infiltrated by the PPgMA.

A composite material includes a combination including a thermoplastic resin mixed with a polypropylene-graft-maleic anhydride (PPgMA), and a plurality of carbon particles mixed in the combination. The plurality of carbon particles may include a first region having a relatively low concentration of carbon particles, and a second region having a relatively high concentration of carbon particles, at least some of the plurality of carbon particles having exposed carbon surfaces with carbon atoms bonded to molecular sites on adjacent PPgMA molecules and oxidized with one or more oxygen-containing groups. In some aspects, composite material further includes between 80 wt. % and 90 wt. % of the thermoplastic resin, between 0.5 wt. % and 15 wt. % of the PPgMA, and between 0.1 wt. % to 7 wt. % of carbon particles. The composite material may also include a plurality of pores, formed in the combination, and configured to be infiltrated by the PPgMA.

In various aspects, the processes disclosed herein may include the steps of inducing an electric field about a non-conductive substrate, and depositing functionalized nanoparticles upon the non-conductive substrate by contacting a nanoparticle dispersion with the non-conductive substrate, the nanoparticle dispersion comprising functionalized nanoparticles having an electrical charge, the electric field drawing the functionalized nanoparticles to the non-conductive substrate. In various aspects, the related composition of matter disclosed herein comprise functionalized nanoparticles bonded to a surface of a non-conductive fiber, the surface of the non-conductive fiber comprising a sizing adhered to the surface of the non-conductive fiber. This Abstract is presented to meet requirements of 37 C.F.R. §1.72(b) only. This Abstract is not intended to identify key elements of the processes, and related apparatus and compositions of matter disclosed herein or to delineate the scope thereof.

Body protection devices, particularly protective helmets are provided, which comprise a shell of plastic material or of fiber-reinforced plastic material, wherein the shell comprises an outer coating layer formed of a polyacrylic or polyepoxide polymeric matrix including graphene fillers. Processes for the production of body protection devices are also provided.

The present disclosure provides advantageous sheet stabilized emulsion based inks, and improved methods for fabricating and using such inks. More particularly, the present disclosure provides improved methods for fabricating conductive inks derived from water-in-oil emulsions stabilized by sheets exfoliated from layered materials (e.g., substantially pristine and non-oxidized graphite or hexagonal boron nitride), and related methods of use. A layered material (e.g., substantially pristine and non-oxidized graphite or hexagonal boron nitride) can be exfoliated into individual sheets, and these sheets can be utilized to stabilize water-in-oil emulsions. In certain embodiments, by utilizing long chain alkanes (e.g., hexadecane), one can advantageously fabricate emulsions with high viscosity and stability. In this form, the emulsions can be used as inks, thereby advantageously providing an inexpensive route to printing electrically conducting and/or insulating lines and shapes.