A polysiloxazane compound including a repeating unit of the following general formula (1), and having a number average molecular weight of 500 to 100,000 as measured by gel permeation chromatography versus polystyrene standards,

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wherein R.sup.1 and R.sup.2 each independently represent a substituted or unsubstituted C.sub.1-C.sub.50 monovalent hydrocarbon group optionally containing a hetero atom, Xs each independently represent a methyl group, an oxygen atom, NHSiX.sub.2, or (NH).sub.(3-r)/2SiR.sup.1R.sup.2.sub.r (R.sup.1 and R.sup.2 have the same meaning as provided above), or Xs are joined to one another to represent an oxygen atom, n is an integer of 0 to 8, when the number of NHSiX.sub.2 is denoted by p, p satisfies 0p/(2n+4)0.5, r is an integer of 0, 1, or 2, and a and b are numbers satisfying 0<a1, 0b<1, and a+b=1.

The present disclosure is drawn to material sets for 3-dimensional printing, 3-dimensional printing systems, and 3-dimensional printed parts. A material set can include a powder bed material of composite particles including glass beads coated with polyamide-12 polymer. The composite particles can have an average particle size from 20 m to 200 m, and the polyamide-12 polymer can include greater than 80 meq/g carboxylic end groups and less than 40 meq/g amino end groups. The fusing agent can include an energy absorber capable of absorbing electromagnetic radiation to produce heat.

This application relates to elastomeric articles such as gloves, compositions for producing the articles and methods for their manufacture. The elastomeric articles contain particles for detectability of the articles (or portions thereof) by metal detectors and/or x-ray detectors. The articles may contain two different types of particlesone particle type is selected from magnetic particles, highly conductive particles or a combination, and the second particle type is particles containing one or more high atomic mass elements (with an atomic mass of at least 132). The particles may be coated by a corrosion inhibitor coating, or they may be uncoated. The compositions for producing the articles may contain a viscosity modifier.

A conductive polymer composite for adhesion to a flexible substrate contains a polymer adhesive containing a curable polymer and a curing agent; and a conductive filler containing a metal and a carbonaceous material dispersed in the polymer adhesive. The conductive polymer composite is suitable for application to not only the human body but also other objects having irregular surface. In addition, due to enhanced adhesive strength of the conductive polymer composite to the flexible substrate, the reduction in conductivity or conductivity breakdown caused by external stress can be prevented and flexibility and stretchability can be improved.

Magnetic material powder that can be detected by a metal detector and the like and tungsten powder that can be detected by an X-ray inspection device are dispersed in a polymer material of the molded article.

A radiation-curable slurry for additive manufacturing of 3D metal objects is provided, comprising: (a) 2-45 wt % of a polymerizable resin; (b) 0.001-10 wt % of one or more polymerization photoinitiators; and (c) 55-98 wt % of a mixture of metal-containing compounds, wherein the mixture of metal-containing compounds comprises, based on the weight of said mixture, 5-95 wt % of metal particles and 5-95 wt % of one or more metal precursors. An additive manufacturing method for producing a three-dimensional metal object using the slurry is provided, as well as three-dimensional metal objects obtainable by the method.

A melt-processable consumable material configured as a feedstock for use in an additive manufacturing system includes a polymeric matrix comprising one or more polyaryletherketones, wherein the polymeric matrix comprises between about 10 wt % and about 50 wt % of the total weight of the feedstock. The material includes radiation shielding particles dispersed within the polymer matrix wherein the radiation shielding particles comprise between about 50 wt % and less than 90 wt % of the total weight of the feedstock.

An embodiment includes a system comprising: an iodine containing thermoset open-cell shape memory polymer (SMP) foam that is x-ray visible; wherein (a) the SMP foam is configured to expand from a compressed secondary state to an expanded primary state in response to thermal stimulus, (b) the SMP foam is a poly(urethane-urea-amide). Other embodiments are described herein.

Certain embodiments are described that are directed to lead containing compositions including radiation absorption metals in combination with a polymeric material. In some aspects, a composition includes lead, optionally at least one additional heavy metal known to have shielding capability against ionizing radiation and at least one polymer, polymer blend or co-polymer. Sheets and articles including the compositions are also described.

Provided are X-ray and metal detectable thermoset composites and methods of detecting the same. The present X-ray and metal detectable thermoset composites may be formed into trays, sheets, or other substrates suitable for use in food or pharmaceutical processing or manufacturing.