The invention relates to fluoropolymer filament for use in 3-D printing, and 3-D printed fluoropolymer articles having low warpage, excellent chemical resistance, excellent water resistance, flame resistance, and good mechanical integrity. Additionally, the articles of the invention have good shelf life without the need for special packaging. In particular, the invention relates to filament, 3-D printed polyvinylidene fluoride (PVDF) articles, and in particular material extrusion 3-D printing. The articles may be formed from PVDF homopolymers, copolymers, such as KYNAR resins from Arkema, as well as polymer blends with appropriately defined low shear melt viscosity. The PVDF may optionally be a filled PVDF formulation. The physical properties of the 3-D printed articles can be maximized and warpage minimized by optimizing processing parameters.

A thermally conductive sheet includes a resin that is liquid under normal temperature and pressure, a resin that is solid under normal temperature and pressure, and a particulate carbon material, and the thermal resistance of the thermally conductive sheet under a pressure of 0.05 MPa is at most 0.30 C./W. In the thermally conductive sheet, the resin that is solid under normal temperature and pressure is preferably a thermoplastic fluororesin that is solid under normal temperature and pressure, and the resin that is liquid under normal temperature and pressure is preferably a thermoplastic fluororesin that is liquid under normal temperature and pressure.

Disclosed are fluorinated vinyl polymer resin compositions, and prepregs and laminate materials containing the same. The fluorinated vinyl polymer resin composition includes a fluorine-substituted vinyl polymer resin and a functional polymer, where the fluorine-substituted vinyl polymer resin has the chemical structure:

##STR00001## where the maximum particle size is less than about 100 microns, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, and R.sub.4 includes a fluorine atom, and where n is greater than about 100. The fluorinated vinyl polymer resin composition can be incorporated in prepreg and laminate materials.

Disclosed are fluorinated vinyl polymer resin compositions, and prepregs and laminate materials containing the same. The fluorinated vinyl polymer resin composition includes a fluorine-substituted vinyl polymer resin and a functional polymer, where the fluorine-substituted vinyl polymer resin has the chemical structure:

##STR00001## where the maximum particle size is less than about 100 microns, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, and R.sub.4 includes a fluorine atom, and where n is greater than about 100. The fluorinated vinyl polymer resin composition can be incorporated in prepreg and laminate materials.

The invention provides a novel composition capable of providing a film or coat exhibiting excellent adhesiveness to a water-impermeable sheet and to an EVA encapsulant layer even without corona discharge treatment. The composition of the invention contains a fluorine-containing polymer and a polyol compound having a hydroxyl value of 10 to 300. The polyol compound is contained in an amount of not less than 0.1 mass % but less than 100 mass % relative to the fluorine-containing polymer.

The invention provides a novel composition capable of providing a film or coat exhibiting excellent adhesiveness to a water-impermeable sheet and to an EVA encapsulant layer even without corona discharge treatment. The composition of the invention contains a fluorine-containing polymer and a polyol compound having a hydroxyl value of 10 to 300. The polyol compound is contained in an amount of not less than 0.1 mass % but less than 100 mass % relative to the fluorine-containing polymer.

The invention provides a novel composition capable of providing a film or coat exhibiting excellent adhesiveness to a water-impermeable sheet and to an EVA encapsulant layer even without corona discharge treatment. The composition of the invention contains a fluorine-containing polymer and a polyol compound having a hydroxyl value of 10 to 300. The polyol compound is contained in an amount of not less than 0.1 mass % but less than 100 mass % relative to the fluorine-containing polymer.

The present invention relates to high thermal resistance synthetic rubber and a compound for a wheel balance weight using the same. In some aspects, the high specific gravity compound for the wheel balance weight has excellent curve adhesive strength and is capable of being cut and used as needed. Provided herein is a method of forming a high thermal resistance elastic body synthetic rubber. The method includes blending acrylic rubber and fluoro rubber. A wheel balance weight having a high specific gravity elastic body can be formed by using the high thermal resistance synthetic rubber described herein as a base polymer and a metal powder.

The present invention relates to high thermal resistance synthetic rubber and a compound for a wheel balance weight using the same. In some aspects, the high specific gravity compound for the wheel balance weight has excellent curve adhesive strength and is capable of being cut and used as needed. Provided herein is a method of forming a high thermal resistance elastic body synthetic rubber. The method includes blending acrylic rubber and fluoro rubber. A wheel balance weight having a high specific gravity elastic body can be formed by using the high thermal resistance synthetic rubber described herein as a base polymer and a metal powder.

The present invention relates to high thermal resistance synthetic rubber and a compound for a wheel balance weight using the same. In some aspects, the high specific gravity compound for the wheel balance weight has excellent curve adhesive strength and is capable of being cut and used as needed. Provided herein is a method of forming a high thermal resistance elastic body synthetic rubber. The method includes blending acrylic rubber and fluoro rubber. A wheel balance weight having a high specific gravity elastic body can be formed by using the high thermal resistance synthetic rubber described herein as a base polymer and a metal powder.