Antimicrobial polymer composite materials are disclosed that are suitable for making oral devices used in dental applications, such as denture bases. Acrylic resin composite materials comprising antimicrobial polymers and antimicrobial fillers provide reduction in common oral microorganisms after long-term aging, with reduced release rate of antimicrobial agents from the composite material. Antimicrobial polymers are prepared from compositions comprising acrylate and/or methacrylate monomers and polymerizable quaternary ammonium silicon-containing compounds.

Antimicrobial polymer composite materials are disclosed that are suitable for making oral devices used in dental applications, such as denture bases. Acrylic resin composite materials comprising antimicrobial polymers and antimicrobial fillers provide reduction in common oral microorganisms after long-term aging, with reduced release rate of antimicrobial agents from the composite material. Antimicrobial polymers are prepared from compositions comprising acrylate and/or methacrylate monomers and polymerizable quaternary ammonium silicon-containing compounds.

An electrostatic latent image developing toner includes toner base particles including a binding resin and a colorant. The binding resin is at least one of: a first polymer having a first structural unit represented by a general formula (1) below and a second polymer having a second structural unit represented by a general formula (2) below; and a copolymer having at least one of the first structural unit and the second structural unit.

##STR00001##

In the general formula (1), R.sub.1 represents a hydrogen atom or an alkoxy group having one to three carbon atoms.

##STR00002##

In the general formula (2), R.sub.2 represents a hydrogen atom or an alkyl group having one to three carbon atoms.

An electrostatic latent image developing toner includes toner base particles including a binding resin and a colorant. The binding resin is at least one of: a first polymer having a first structural unit represented by a general formula (1) below and a second polymer having a second structural unit represented by a general formula (2) below; and a copolymer having at least one of the first structural unit and the second structural unit.

##STR00001##

In the general formula (1), R.sub.1 represents a hydrogen atom or an alkoxy group having one to three carbon atoms.

##STR00002##

In the general formula (2), R.sub.2 represents a hydrogen atom or an alkyl group having one to three carbon atoms.

The invention relates to an acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, to an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, to acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and to a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

The invention relates to an acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, to an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, to acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and to a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

The photochromic composition contains one or more compounds represented by General Formula A, one or more compounds represented by General Formula B, and one or more compounds represented by General Formula C is provided. In General Formula A, R.sup.1 to R.sup.6, B.sup.1, and B.sup.2 each independently represent a hydrogen atom or a substituent. In General Formula B, R.sup.7 to R.sup.12, B.sup.3, and B.sup.4 each independently represent a hydrogen atom or a substituent, and R.sup.13 and R.sup.14 each independently represent an electron-donating group. In General Formula C, R.sup.15 to R.sup.20, B.sup.5, and B.sup.6 each independently represent a hydrogen atom or a substituent, and one of R.sup.21 and R.sup.22 represents a hydrogen atom and the other represents an electron-donating group.

##STR00001##

The photochromic composition contains one or more compounds represented by General Formula A, one or more compounds represented by General Formula B, and one or more compounds represented by General Formula C is provided. In General Formula A, R.sup.1 to R.sup.6, B.sup.1, and B.sup.2 each independently represent a hydrogen atom or a substituent. In General Formula B, R.sup.7 to R.sup.12, B.sup.3, and B.sup.4 each independently represent a hydrogen atom or a substituent, and R.sup.13 and R.sup.14 each independently represent an electron-donating group. In General Formula C, R.sup.15 to R.sup.20, B.sup.5, and B.sup.6 each independently represent a hydrogen atom or a substituent, and one of R.sup.21 and R.sup.22 represents a hydrogen atom and the other represents an electron-donating group.

##STR00001##

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.