Patent classifications
C08L61/24
AMINO RESIN PERFORMANCE WITH SULFONATED LIGNIN
A resin system and methods of making resin system wherein lignosulfonate is added to urea-formaldehyde and melamine-urea-formaldehyde adhesives. Lignosulfonate is added to the resins which improves the performance characteristics of the adhesive while reducing environmental impact by consuming byproducts from other industrial processes. The resin system includes a urea-formaldehyde (UF) resin or melamine-urea-formaldehyde (MUF), prepared in at least two stages wherein the UF resin or MUF resin has a molar ratio (MR) of total moles formaldehyde to total moles urea plus, if present, the one or more melamine compounds of from about 0.25:1 to about 2.50:1, and wherein one or more lignosulfonate compounds are included in an amount of from about 0.1-30 wt. %, based on a total weight of the resin system, and wherein the resin system has a buffer capacity of 2-400 mL of 0.1 N HCl by the ATV Method for a period of time of at least about 20 days at 25° C.
AMINO RESIN PERFORMANCE WITH SULFONATED LIGNIN
A resin system and methods of making resin system wherein lignosulfonate is added to urea-formaldehyde and melamine-urea-formaldehyde adhesives. Lignosulfonate is added to the resins which improves the performance characteristics of the adhesive while reducing environmental impact by consuming byproducts from other industrial processes. The resin system includes a urea-formaldehyde (UF) resin or melamine-urea-formaldehyde (MUF), prepared in at least two stages wherein the UF resin or MUF resin has a molar ratio (MR) of total moles formaldehyde to total moles urea plus, if present, the one or more melamine compounds of from about 0.25:1 to about 2.50:1, and wherein one or more lignosulfonate compounds are included in an amount of from about 0.1-30 wt. %, based on a total weight of the resin system, and wherein the resin system has a buffer capacity of 2-400 mL of 0.1 N HCl by the ATV Method for a period of time of at least about 20 days at 25° C.
ARTICLES MADE FROM LIPOPHILIC-RICH CELLULOSIC MATERIAL AND METHODS THEREFOR
The invention relates to systems and techniques for manufacturing articles containing cellulosic material, a tackifier, and a binder, and related processes of making and using the cellulosic articles. In particularly exemplary embodiments, the manufactured articles are door skins, sometimes known as door facings, and doors made from the door skins. The article contains a lipophilic cellulosic material, a tackifier, and a binder.
ARTICLES MADE FROM LIPOPHILIC-RICH CELLULOSIC MATERIAL AND METHODS THEREFOR
The invention relates to systems and techniques for manufacturing articles containing cellulosic material, a tackifier, and a binder, and related processes of making and using the cellulosic articles. In particularly exemplary embodiments, the manufactured articles are door skins, sometimes known as door facings, and doors made from the door skins. The article contains a lipophilic cellulosic material, a tackifier, and a binder.
Articles made from lipophilic-rich cellulosic material and methods therefor
The invention relates to systems and techniques for manufacturing articles containing cellulosic material, a tackifier, and a binder, and related processes of making and using the cellulosic articles. In particularly exemplary embodiments, the manufactured articles are door skins, sometimes known as door facings, and doors made from the door skins. The article contains a lipophilic cellulosic material, a tackifier, and a binder.
Articles made from lipophilic-rich cellulosic material and methods therefor
The invention relates to systems and techniques for manufacturing articles containing cellulosic material, a tackifier, and a binder, and related processes of making and using the cellulosic articles. In particularly exemplary embodiments, the manufactured articles are door skins, sometimes known as door facings, and doors made from the door skins. The article contains a lipophilic cellulosic material, a tackifier, and a binder.
PREPARATION OF UREA-FORMALDEHYDE/POLY(BUTYLENE SUCCINATE) AND ITS TERNARY BIODEGRADABLE POLYMER NANO SLOW/CONTROLLED RELEASE MATERIALS BY REACTIVE EXTRUSION
The invention relates to the field of preparing biodegradable polymer slow/controlled release composite, in particular to a biodegradable polymer slow/controlled release binary composite urea-formaldehyde/poly(butylene succinate) and a biodegradable polymer slow/controlled release ternary nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate. The following steps are included: uniformly mixing two components poly(butylene succinate) and methylol-urea or three components poly(butylene succinate), methylol-urea and potassium dihydrogen phosphate, and then extruding the resulting mixture by an extruder, and the biodegradable polymer slow/controlled release composite urea-formaldehyde/poly(butylene succinate) containing nutrient N and the biodegradable polymer slow/controlled release nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate containing nutrients of N, P and K are obtained respectively. As one of the raw materials, methylol-urea, the precursor of urea-formaldehyde, can react by way of melt polycondensation to form urea-formaldehyde macromolecular chains with different polymerization degrees at high temperature in the extruder, which are dispersed among the PBS macromolecular chains, thereby obtaining the composite UF/PBS of the present invention; and the hindering effect of the molecular segments of urea-formaldehyde and poly(butylene succinate) and the hydrogen bond interaction between the components result in that potassium dihydrogen phosphate crystals dissolved in the water produced by the polycondensation reaction are restricted to nanoscale during their precipitation process, so as to prepare nanocomposite UF/PBS/MKP. The prepared composites all have excellent mechanical properties, and can be directly used as a biodegradable polymer slow/controlled release fertilizer, or as a matrix polymer to prepare other types of slow release fertilizers, and the formulae with high PBS contents can also replace PBS to prepare other agricultural implements, such as agricultural films, nursery pots and vegetation nets.
PREPARATION OF UREA-FORMALDEHYDE/POLY(BUTYLENE SUCCINATE) AND ITS TERNARY BIODEGRADABLE POLYMER NANO SLOW/CONTROLLED RELEASE MATERIALS BY REACTIVE EXTRUSION
The invention relates to the field of preparing biodegradable polymer slow/controlled release composite, in particular to a biodegradable polymer slow/controlled release binary composite urea-formaldehyde/poly(butylene succinate) and a biodegradable polymer slow/controlled release ternary nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate. The following steps are included: uniformly mixing two components poly(butylene succinate) and methylol-urea or three components poly(butylene succinate), methylol-urea and potassium dihydrogen phosphate, and then extruding the resulting mixture by an extruder, and the biodegradable polymer slow/controlled release composite urea-formaldehyde/poly(butylene succinate) containing nutrient N and the biodegradable polymer slow/controlled release nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate containing nutrients of N, P and K are obtained respectively. As one of the raw materials, methylol-urea, the precursor of urea-formaldehyde, can react by way of melt polycondensation to form urea-formaldehyde macromolecular chains with different polymerization degrees at high temperature in the extruder, which are dispersed among the PBS macromolecular chains, thereby obtaining the composite UF/PBS of the present invention; and the hindering effect of the molecular segments of urea-formaldehyde and poly(butylene succinate) and the hydrogen bond interaction between the components result in that potassium dihydrogen phosphate crystals dissolved in the water produced by the polycondensation reaction are restricted to nanoscale during their precipitation process, so as to prepare nanocomposite UF/PBS/MKP. The prepared composites all have excellent mechanical properties, and can be directly used as a biodegradable polymer slow/controlled release fertilizer, or as a matrix polymer to prepare other types of slow release fertilizers, and the formulae with high PBS contents can also replace PBS to prepare other agricultural implements, such as agricultural films, nursery pots and vegetation nets.
Method for quick hot-press forming of laminated wood
The present invention discloses a method for quick hot-press forming of laminated wood. The method includes: drying a machined small wood material to a moisture content of 5-8 wt %; gluing the dried small wood material, and assembling and laying the dried small wood material to be a square material or a sheet material, where an adhesive for the gluing is a water-soluble adhesive having a solid content of 45-60 wt %; clamping the square material or the sheet material through a three-dimensional metal clamp; sending the clamped square material or sheet material together with the clamp into a microwave heating machine for microwave heating to obtain a formed laminated wood, where the time from the gluing to the entry into the microwave heating machine is controlled to not exceed 15 min. According to the present invention, a glued part that needs to be heated can be heated quickly, precisely and effectively, the gluing strength and production efficiency of the laminated wood can be significantly improved, and the cost of production energy consumption is reduced.
Method for quick hot-press forming of laminated wood
The present invention discloses a method for quick hot-press forming of laminated wood. The method includes: drying a machined small wood material to a moisture content of 5-8 wt %; gluing the dried small wood material, and assembling and laying the dried small wood material to be a square material or a sheet material, where an adhesive for the gluing is a water-soluble adhesive having a solid content of 45-60 wt %; clamping the square material or the sheet material through a three-dimensional metal clamp; sending the clamped square material or sheet material together with the clamp into a microwave heating machine for microwave heating to obtain a formed laminated wood, where the time from the gluing to the entry into the microwave heating machine is controlled to not exceed 15 min. According to the present invention, a glued part that needs to be heated can be heated quickly, precisely and effectively, the gluing strength and production efficiency of the laminated wood can be significantly improved, and the cost of production energy consumption is reduced.