The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

Provided is a prepreg resin composition, containing: a urethane (meth)acrylate (A) that is a reaction product of polyisocyanate (a1), polyol (a2), and hydroxy alkyl (meth)acrylate (a3); a polymerization initiator (B); and a thermoplastic resin (C), as an essential component, in which the polyisocyanate (a1) is at least one polyisocyanate selected from 2,4′-diphenyl methane diisocyanate, 4,4′-diphenyl methane diisocyanate, a carbodiimide modified product of 4,4′-diphenyl methane diisocyanate, and polymethylene polyphenyl polyisocyanate. The prepreg resin composition of the invention is excellent in molding properties, and is capable of forming a molded article excellent in various physical properties such as flexibility, impact resistance, and heat resistance, and thus, can be preferably used in a prepreg and a molded article thereof.

Provided is a prepreg resin composition, containing: a urethane (meth)acrylate (A) that is a reaction product of polyisocyanate (a1), polyol (a2), and hydroxy alkyl (meth)acrylate (a3); a polymerization initiator (B); and a thermoplastic resin (C), as an essential component, in which the polyisocyanate (a1) is at least one polyisocyanate selected from 2,4′-diphenyl methane diisocyanate, 4,4′-diphenyl methane diisocyanate, a carbodiimide modified product of 4,4′-diphenyl methane diisocyanate, and polymethylene polyphenyl polyisocyanate. The prepreg resin composition of the invention is excellent in molding properties, and is capable of forming a molded article excellent in various physical properties such as flexibility, impact resistance, and heat resistance, and thus, can be preferably used in a prepreg and a molded article thereof.

The invention relates to a two-component adhesive based on hybrid urethane-acrylate epoxies comprising a core/shell rubber demonstrating good T-peel strength. The adhesives are suitable for use in industry, e.g., as adhesives for transportation industry applications.

The invention relates to a two-component adhesive based on hybrid urethane-acrylate epoxies comprising a core/shell rubber demonstrating good T-peel strength. The adhesives are suitable for use in industry, e.g., as adhesives for transportation industry applications.

An optical structure includes a multilayer relief that has a first surface having an uneven shape, and a reflection layer that is formed on the first surface and reflects visible light. The multilayer relief includes a first resin layer that contains a non-radiation curable resin as a main component and constitutes the first surface, and a second resin layer that contains a radiation curable resin as a main component and is adjacent to the first resin layer. The first resin layer has a thickness smaller than an unevenness difference of the uneven shape.

An optical structure includes a multilayer relief that has a first surface having an uneven shape, and a reflection layer that is formed on the first surface and reflects visible light. The multilayer relief includes a first resin layer that contains a non-radiation curable resin as a main component and constitutes the first surface, and a second resin layer that contains a radiation curable resin as a main component and is adjacent to the first resin layer. The first resin layer has a thickness smaller than an unevenness difference of the uneven shape.

The invention relates to thermosetting powder coating compositions as these are disclosed herein. The compositions comprise A) unsaturated resin(s) comprising ethylenic unsaturations selected from the group consisting of polyester resins, polyurethanes, epoxy resins, polyamides, polyesteramides, polycarbonates, polyureas and mixtures thereof; and B) curing agent(s) selected from the group consisting of certain vinyl urethanes, vinyl functionalized urethane resins and mixtures thereof; and C) thermal radical initiator(s) selected from the group consisting of organic peroxides, azo compounds, and mixtures thereof; and D) co-initiator(s) selected from the group consisting of certain onium compounds, sulpho-compounds, and mixtures thereof; and E) inhibitor(s) selected from the group consisting of phenolic compounds, stable radicals, catechols, phenothiazines, hydroquinones, benzoquinones and mixtures thereof. The invention further relates to a process for making said thermosetting powder coating compositions and processes for coating an article with said thermosetting powder coating compositions. The invention further relates to cured thermosetting powder coating compositions obtained by curing of the thermosetting powder coating compositions of the invention. The invention further relates to an article having coated thereon said thermosetting powder coating composition as well as to an article having coated and cured thereon said thermosetting powder coating composition. The invention further relates to the use of said thermosetting powder coating compositions, to the use of an article having coated thereon said thermosetting powder coating compositions and to the use of an article having coated and cured thereon said thermosetting powder coating compositions. The invention further relates to various uses of either the thermosetting powder coating compositions of the invention, or the cured thermosetting powder coating compositions of the invention or of articles having coated thereon the thermosetting powder coating composition of the invention, or of articles having coated and cured thereon the thermosetting powder coating composition of the invention. The invention further relates to a method for substantially lowering the T.sub.chalk-free as the latter is defined herein.

The invention relates to thermosetting powder coating compositions as these are disclosed herein. The compositions comprise A) unsaturated resin(s) comprising ethylenic unsaturations selected from the group consisting of polyester resins, polyurethanes, epoxy resins, polyamides, polyesteramides, polycarbonates, polyureas and mixtures thereof; and B) curing agent(s) selected from the group consisting of certain vinyl urethanes, vinyl functionalized urethane resins and mixtures thereof; and C) thermal radical initiator(s) selected from the group consisting of organic peroxides, azo compounds, and mixtures thereof; and D) co-initiator(s) selected from the group consisting of certain onium compounds, sulpho-compounds, and mixtures thereof; and E) inhibitor(s) selected from the group consisting of phenolic compounds, stable radicals, catechols, phenothiazines, hydroquinones, benzoquinones and mixtures thereof. The invention further relates to a process for making said thermosetting powder coating compositions and processes for coating an article with said thermosetting powder coating compositions. The invention further relates to cured thermosetting powder coating compositions obtained by curing of the thermosetting powder coating compositions of the invention. The invention further relates to an article having coated thereon said thermosetting powder coating composition as well as to an article having coated and cured thereon said thermosetting powder coating composition. The invention further relates to the use of said thermosetting powder coating compositions, to the use of an article having coated thereon said thermosetting powder coating compositions and to the use of an article having coated and cured thereon said thermosetting powder coating compositions. The invention further relates to various uses of either the thermosetting powder coating compositions of the invention, or the cured thermosetting powder coating compositions of the invention or of articles having coated thereon the thermosetting powder coating composition of the invention, or of articles having coated and cured thereon the thermosetting powder coating composition of the invention. The invention further relates to a method for substantially lowering the T.sub.chalk-free as the latter is defined herein.

The present invention provides a method for producing an optical film excellent in anti-fouling properties and scratch resistance as well as anti-reflection properties. The method includes the steps of: (1) applying a lower layer resin and an upper layer resin; (2) forming a resin layer having the uneven structure on a surface thereof by pressing a mold against the lower layer resin and the upper layer resin from the upper layer resin side in the state where the applied lower layer resin and upper layer resin are stacked; and (3) curing the resin layer, the lower layer resin containing at least one kind of first monomer that contains no fluorine atoms, the upper layer resin containing a fluorine-containing monomer and at least one kind of second monomer that contains no fluorine atoms, at least one of the first monomer and the second monomer containing a compatible monomer that is compatible with the fluorine-containing monomer and being dissolved in the lower layer resin and the upper layer resin.