Patent classifications
C08L101/08
CROSSLINKABLE FLAME-RETARDANT COATING COMPOSITION
The invention is directed to a crosslinkable flame-retardant coating composition comprising the following components: a) a dendritic polymer having hydroxyl groups, wherein the dendritic polymer has a hydroxyl number in the range of 80 to 800, b) a polyol having at least 3 hydroxyl groups, c) an ammonium polyphosphate compound, d) a base coat polymer selected from a polycarbamate resin or a polymer bearing carboxyl groups, and e) a crosslinker for crosslinking the base coat polymer selected from a compound having two or more aldehyde groups, acetals or hemiacetals of the aldehydes, or a polycarbodiimide.
Such a cross-linkable flame-retardant coating composition improves the overall appearance of the cross-linked base coating on a substrate and also imparts improved flame-retardancy.
Aqueous Dispersion, Production Method Therefor, Coating Composition, and Coating Film
An aqueous dispersion including a polymer having a 2-oxazoline group; and a surfactant, the surfactant containing a sulfuric acid ester compound represented by the following Chemical Formula (S):
R.sup.1—O—(R.sup.2O)nSO.sub.3X (S)
wherein R.sup.1 represents an aliphatic hydrocarbon group having 8 to 20 carbon atoms; R.sup.2 represents an alkylene group having 2 to 4 carbon atoms; n represents 2 to 15; and X represents a monovalent cation.
Aqueous Dispersion, Production Method Therefor, Coating Composition, and Coating Film
An aqueous dispersion including a polymer having a 2-oxazoline group; and a surfactant, the surfactant containing a sulfuric acid ester compound represented by the following Chemical Formula (S):
R.sup.1—O—(R.sup.2O)nSO.sub.3X (S)
wherein R.sup.1 represents an aliphatic hydrocarbon group having 8 to 20 carbon atoms; R.sup.2 represents an alkylene group having 2 to 4 carbon atoms; n represents 2 to 15; and X represents a monovalent cation.
FIBROUS CELLULOSE COMPOSITE RESIN AND PRODUCTION METHOD THEREFOR
A fibrous cellulose composite resin excellent in strength, and a method for producing the same. The fibrous cellulose composite resin includes microfiber cellulose, a resin, and an acid-modified resin, wherein the microfiber cellulose has hydroxyl groups, which are substituted with carbamate groups, and has been washed and defibrated into an average fiber width of 0.1 μm or larger, in which the amount of the byproduct is 10% or less per 100 parts by mass of a carbamate-modified cellulose. The production method includes heat-treating a cellulose raw material and urea to obtain a carbamate-modified cellulose, washing the carbamate-modified cellulose, defibrating the carbamate-modified cellulose to obtain a dispersion of carbamate-modified microfiber cellulose having an average fiber width of 0.1 μm or larger, mixing the dispersion and an acid-modified resin to obtain a material containing carbamate-modified microfiber cellulose, and kneading the material with a resin to obtain a composite resin.
FIBROUS CELLULOSE COMPOSITE RESIN AND PRODUCTION METHOD THEREFOR
A fibrous cellulose composite resin excellent in strength, and a method for producing the same. The fibrous cellulose composite resin includes microfiber cellulose, a resin, and an acid-modified resin, wherein the microfiber cellulose has hydroxyl groups, which are substituted with carbamate groups, and has been washed and defibrated into an average fiber width of 0.1 μm or larger, in which the amount of the byproduct is 10% or less per 100 parts by mass of a carbamate-modified cellulose. The production method includes heat-treating a cellulose raw material and urea to obtain a carbamate-modified cellulose, washing the carbamate-modified cellulose, defibrating the carbamate-modified cellulose to obtain a dispersion of carbamate-modified microfiber cellulose having an average fiber width of 0.1 μm or larger, mixing the dispersion and an acid-modified resin to obtain a material containing carbamate-modified microfiber cellulose, and kneading the material with a resin to obtain a composite resin.
Polycarbodiimide composition, method for producing a polycarbodiimide composition, water-dispersed composition, solution composition, resin composition, and cured resin
The polycarbodiimide composition is a reaction product of polyisocyanate having a primary isocyanate group with alcohol, wherein the alcohol contains at least one oxyethylene-containing alcohol containing an oxyethylene group, and at least one oxyethylene-noncontaining alcohol containing no oxyethylene group, the at least one oxyethylene-noncontaining alcohol has a solubility parameter of 11.20 (cal/cm.sup.3).sup.1/2 or less.
Polycarbodiimide composition, method for producing a polycarbodiimide composition, water-dispersed composition, solution composition, resin composition, and cured resin
The polycarbodiimide composition is a reaction product of polyisocyanate having a primary isocyanate group with alcohol, wherein the alcohol contains at least one oxyethylene-containing alcohol containing an oxyethylene group, and at least one oxyethylene-noncontaining alcohol containing no oxyethylene group, the at least one oxyethylene-noncontaining alcohol has a solubility parameter of 11.20 (cal/cm.sup.3).sup.1/2 or less.
Process for the preparation of dry chlorinated polyvinyl chloride
The present disclosure provides an effective and efficient process for the preparation of a dry chlorinated polyvinyl chloride (CPVC), comprising introducing chlorine gas into slurry of polyvinyl chloride in water to obtain a reaction mixture; irradiating the reaction mixture to obtain a product mixture comprising CPVC and water solution including unreacted chlorine gas and hydrogen chloride; filtering the product mixture to obtain a first mass; adding water to the first mass for extracting unreacted chlorine gas and hydrogen chloride to obtain an aqueous suspension, and filtering the aqueous suspension to obtain a second mass; passing nitrogen through the second mass to extract residual water solution to leave behind a third mass; and agitating the third mass in a high-speed mixer together with a neutralizing agent, and optionally with a stabilizer and a processing additive to obtain dry thermally stable CPVC with thermal stability in the range of 1000 seconds to 1500 seconds.
Process for the preparation of dry chlorinated polyvinyl chloride
The present disclosure provides an effective and efficient process for the preparation of a dry chlorinated polyvinyl chloride (CPVC), comprising introducing chlorine gas into slurry of polyvinyl chloride in water to obtain a reaction mixture; irradiating the reaction mixture to obtain a product mixture comprising CPVC and water solution including unreacted chlorine gas and hydrogen chloride; filtering the product mixture to obtain a first mass; adding water to the first mass for extracting unreacted chlorine gas and hydrogen chloride to obtain an aqueous suspension, and filtering the aqueous suspension to obtain a second mass; passing nitrogen through the second mass to extract residual water solution to leave behind a third mass; and agitating the third mass in a high-speed mixer together with a neutralizing agent, and optionally with a stabilizer and a processing additive to obtain dry thermally stable CPVC with thermal stability in the range of 1000 seconds to 1500 seconds.
METHOD FOR PREPARING TOPOLOGICAL ELASTOMERS WITH HIGHLY BRANCHED STRUCTURES, LOW MODULUS AND HIGH ELASTICITY
A fabrication method and application of topological elastomers with highly branched structures, low modulus and high elasticity. The topological elastomers comprise dendritic macromolecules. The fabrication method includes direct crosslinking, post-crosslinking, grafting, and copolymerization. The performance of the elastomer can be easily tuned via changing the topology of the polymer network. The breakthrough of this invention lies in that these topological elastomers with highly branched structures are having low modulus and high elasticity, which would expand its application in the field of elastomer. Notably, the variety of topological elastomers, the versatility of curing chemistries, the availability of a wide variety of monomers, and the various polymerization methods are enabling the fabrication of topological elastomers with feasibility and efficiency.