The present invention relates to a technique for providing a quinacridone solid solution pigment, by which a quinacridone solid solution pigment that allows a colored product to have high chroma and a properly yellowish hue, and suitably, that has a controlled particle diameter and has the above-described, desired hue can be obtained. The present invention provides a method for producing a quinacridone solid solution pigment, wherein a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid are subjected to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution such that water is contained in a solid solution having a mass ratio of unsubstituted quinacridone to a 2,9-dialkylquinacridone of 85:15 to 60:40; the water-containing crude quinacridone solid solution obtained above is dried in a drying step, thereby obtaining a powdery, crude quinacridone solid solution having a water content of less than 1%; and the powdery, crude quinacridone solid solution is heated in a liquid medium that does not dissolve the crude quinacridone solid solution in a pigmentation step, and the present invention also provides a pigment dispersion liquid and an inkjet ink each containing the obtained quinacridone solid solution pigment.

Disclosed herein are compositions (e.g., pigment dispersions or ink compositions such as inkjet ink compositions) comprising at least one quinacridone magenta pigment and at least one synergist selected from compounds (A) and (B) having the following structures, wherein each n is an integer independently ranging from 1 to 4, and R.sub.1-R.sub.3 are each independently selected from H, CH.sub.3, Cl, and F,

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The present disclosure is drawn to aqueous pigment dispersions. In one example, an aqueous pigment dispersion can include from 40 wt % to 90 wt % water, from 2 wt % to 30 wt % organic co-solvent, from 7.5 wt % to 30 wt % quinacridone pigment, from 0.5 wt % to 3.5 wt % styrene-acrylic dispersant, and from 0.5 wt % to 3.5 wt % hydrophilic polyurethane dispersant having an acid number from 20 to 100. The styrene-acrylic dispersant and the hydrophilic polyurethane dispersant can be present at a weight ratio from 1:5 to 5:1.

There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters. Specifically, a method for producing a quinacridone solid solution pigment, the method including a crude quinacridone solid solution production step of subjecting a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution containing a solid solution of an unsubstituted quinacridone and a 2,9-dialkylquinacridone, the solid solution containing water, a drying step of drying the water-containing crude quinacridone solid solution to reduce the water content to less than 1% and obtain a powdery, crude quinacridone solid solution, and a pigmentation step of heating the powdery, crude quinacridone solid solution in a liquid medium that cannot dissolve the crude quinacridone solid solution.

Provided is a quinacridone pigment composition for coloring plastics, particularly engineering plastics. The quinacridone pigment composition has high transparency and high color strength and also has high heat resistance, so that discoloration during molding of a resin (a color change of a molded plate) is very small. Also provided are a masterbatch and a resin molded product that contain the pigment composition. The pigment composition for coloring resins contains a quinacridone pigment and a pigment that absorbs fluorescence in a wavelength range of 500 to 600 nm. The inventors have found that, when the pigment composition is used as a colorant of a resin molded product subjected to a high-temperature thermal history, the change in color, i.e., the discoloration, of the resin molded product obtained is very small. Thus, the present invention has been completed.

A quinacridone solid solution pigment that allows a colored product to have high chroma and a properly yellowish hue and has a controlled particle diameter, and a method for producing the quinacridone solid solution pigment. In the method, a water-containing crude quinacridone solid solution is produced by a co-cyclization reaction of a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid in polyphosphoric acid, then the resulting water-containing crude quinacridone solid solution having a mass ratio of unsubstituted quinacridone to a 2,9-dialkylquinacridone of 85:15 to 60:40 is dried, thereby obtaining a powdery, crude quinacridone solid solution having a water content of less than 1%. Then, the resulting powdery, crude quinacridone solid solution is heated in a liquid medium that does not dissolve the crude quinacridone solid solution. Also, a pigment dispersion liquid and an inkjet ink each containing the obtained quinacridone solid solution pigment are provided.

Provided is a quinacridone pigment composition for coloring plastics, particularly engineering plastics. The quinacridone pigment composition has high transparency and high color strength and also has high heat resistance, so that discoloration during molding of a resin (a color change of a molded plate) is very small. Also provided are a masterbatch and a resin molded product that contain the pigment composition. The pigment composition for coloring resins contains a quinacridone pigment and a pigment that absorbs fluorescence in a wavelength range of 500 to 600 nm. The inventors have found that, when the pigment composition is used as a colorant of a resin molded product subjected to a high-temperature thermal history, the change in color, i.e., the discoloration, of the resin molded product obtained is very small. Thus, the present invention has been completed.

Provided are a quinacridone pigment having a low content of a primary aromatic amine, a method for producing the same, and also a gravure and flexo ink, a colorant for plastic, a paint, a lithographic ink, a toner, or an ink-jet ink using the pigment. The quinacridone pigment having a low primary aromatic amine content is provided by washing a quinacridone pigment with at least one solvent selected from water and an organic solvent, or by adding an oxidizing agent to a pigment slurry including a quinacridone pigment and at least one solvent selected from water and an organic solvent to oxidatively decompose the aromatic amine.

A highly efficient method is provided for producing a water-based ink for ink jet recording with which the number of coarse particles in a water-based pigment dispersion liquid is significantly reduced, dispersed particles are made finer, the dispersion stability is improved, the storage stability is improved, and high discharge stability is achieved when a water-based ink for ink jet recording is produced. Particularly, provided is a method for producing a water-based pigment dispersion liquid, the method including kneading a mixture containing a quinacridone type pigment (a), a styrene-acrylic acid type copolymer (c), a basic compound (d), and a polyoxyalkylene glycol or its derivative (e) to prepare a pigment dispersion that is solid at room temperature and mixing a aqueous medium and the pigment dispersion to decrease the viscosity and liquefy the pigment dispersion.

An inkjet ink includes a quinacridone pigment, a pigment dispersion resin, and a water-soluble organic solvent. The pigment dispersion resin includes an adsorbed resin adsorbed on the quinacridone pigment and an unadsorbed resin that is not adsorbed on the quinacridone pigment. A ratio of the unadsorbed resin to the pigment dispersion resin is 40 mass % or less. The water-soluble organic solvent includes a predetermined water-soluble organic solvent having an octanol/water partition coefficient Log P of 0.00 or more. A content ratio of the predetermined water-soluble organic solvent with respect to a mass of the inkjet ink is 15 mass % or more and 40 mass % or less. A sulfur concentration in a supernatant liquid obtained by centrifuging the inkjet ink at 1,050,000 G for 3 hours is 0.5 ppm or more and 2.0 ppm or less.