C09C1/3081

Method for large scale fabrication of Janus/amphiphilic particles using polymer precipitation procedure

This invention provides a method for creating a large-scale of amphiphilic particles. The method includes: adding nanoparticles into a polycarbonate-based solution, adding a surfactant into the solution while performing ultra-sonication to generate polymer precipitation, creating at least one microsphere with the nanoparticles embedded onto it, subjecting the exposed hemisphere of the embedded nanoparticles to a further amphiphilic particles related modification, and dissolving the at least one microsphere in a polycarbonate-based solution in order to free said embedded nanoparticles from the at least one microsphere.

METHOD OF PREPARING HYDROPHOBIC SILICA AEROGEL AND HYDROPHOBIC SILICA AEROGEL PREPARED THEREBY
20170369326 · 2017-12-28 ·

The present invention relates to a method of preparing a high hydrophobic silica aerogel having a low tap density and a hydrophobic silica aerogel prepared thereby. The method of preparing a hydrophobic silica aerogel according to the present invention may have good productivity and economic efficiency, because preparation time is reduced by simultaneously performing surface modification and solvent substitution in a single step, and may control a degree of hydrophobicity of the prepared silica aerogel by controlling a surface modification reaction by including a step of adding ammonium hydroxide. Thus, a hydrophobic silica aerogel having excellent physical properties, such as tap density and specific surface area, as well as high hydrophobicity obtained by controlling the degree of hydrophobicity may be prepared.

MULTIFUNCTIONAL SUPERHYDROPHOBIC PARTICLES FOR CHEMICAL ADHESION AND BLOOMING
20170362257 · 2017-12-21 ·

Provided herein is a multifunctional particle and methods of forming the same. The multifunctional particle includes a surface of the particle; a first moiety coupled to the surface and having at least one substantially hydrophobic appendage; and a second moiety coupled to the surface and having at least one appendage comprising a reactive functional group and a substantially hydrophilic repeating unit, whereby the particle is substantially superhydrophobic as a result of the substantially hydrophobic appendage, chemically reactive as a result of the reactive functional group, and migratory to a surface of a substantially hydrophobic matrix in which the particle may be included as a result of the substantially hydrophilic repeating unit. Additionally, antimicrobial functional groups may be coupled to the surface.

SILICONE OIL-TREATED SILICA PARTICLES AND TONER FOR ELECTROPHOTOGRAPHY

A silicone oil-treated silica particle according to the present invention includes a silica particle body and silicone oil. The silica particle body has a BET specific surface area of 70 m.sup.2/g to 120 m.sup.2/g. The silica particle body has been surface-treated with the silicone oil. The amount of free silicone oil liberated from the surface of the silica particle body in the silicone oil accounts for 2.0 mass % to 5.0 mass % with respect to the silica particle body. A surface-treated styrene acrylic resin particle, in which 2 parts by mass of the silicone oil-treated silica particle has been added to 100 parts by mass of a styrene acrylic resin particle having a particle size median of 5 μm to 8 μm, has a degree of agglomeration of 18 % or less.

Surface treatment of particles and their use

The invention relates to polymer compositions containing inorganic or organic particles which either have been surface-treated before the production of the compositions or are dispersed by special polyether-modified siloxanes through the production of the compositions.

Natural amorphous silica filler products

Natural amorphous silica filler products featuring high brightness, low oil absorption, fine particle size, and low crystalline silica content are described. Methods for making, using, and measuring the properties of the natural amorphous silica filler products are also described. The natural amorphous silica filler products described herein may be useful in a variety of products including, but not limited to, polymers, sealants, paints, caulks, latex, architectural coatings, industrial coatings, pozzolan, glass catalysts, ceramic glazes, and anti-blocking applications.

Silica Fillers and Methods of Making Same
20170342273 · 2017-11-30 ·

An exemplary embodiment of the present invention provides a filler comprising a silica core, a first layer in communication with the core, and a second layer in communication with the first layer. The presence of the second layer can decrease the coefficient of thermal expansion, decrease the composite modulus, and increase the glass transition temperature of the modulus as compared to fillers without a second layer.

Method of glass fabric production including resin adhesion for printed circuit board formation

Embodiments generally relate to devices and methods for production of fibers and threads for use in electronic device manufacturing. Described here, fibers can be produced and manipulated using a dual-surfaced sizing material. The dual-surfaced sizing material has a surface which binds a fiber and a surface which binds a resin. Thus, the dual-surfaced sizing material can be left attached to the fibers without adversely affecting the resin binding in later production steps.

Fluorine-containing oligomer, nano-silica composite particles using the same, and methods for producing both

Disclosed is a fluorine-containing oligomer comprising a copolymer of a fluoroalkyl alcohol (meth)acrylic acid derivative represented by the general formula:
C.sub.nF.sub.2n+1(CH.sub.2CF.sub.2).sub.a(CF.sub.2CF.sub.2).sub.b(CH.sub.2CH.sub.2).sub.cOCOCR═CH.sub.2  [I]
wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, a is an integer of 1 to 4; b is an integer of 0 to 3; and c is an integer of 1 to 3; and a (meth)acrylic acid derivative represented by the general formula:
(CH.sub.2═CRCO).sub.mR′  [II]
wherein R is a hydrogen atom or a methyl group, m is 1, 2, or 3; and when m is 1, R′ is OH group, NH.sub.2 group that is unsubstituted or mono- or di-substituted with an alkyl group having 1 to 6 carbon atoms, or a monovalent group derived from an alkylene glycol or polyalkylene glycol group containing an alkylene group having 2 or 3 carbon atoms; when m is 2 or 3, R′ is a divalent or trivalent organic group derived from a diol or triol. The copolymerization reaction is performed using a hydrocarbon-based peroxide or azo compound polymerization initiator. Also disclosed are nano-silica composite particles formed as a condensate of the fluorine-containing oligomer and an alkoxysilane with nano-silica particles.

Silicone oil-treated fumed silica, manufacturing method and application thereof

A silicone oil-treated fumed silica and a method of producing the silicone oil-treated fumed silica are provided. The silicone oil-treated fumed silica, which has the following physical properties: A) the silicone oil-treated fumed silica has a degree of hydrophobicity of 68 vol % or more; B) the silicone oil-treated fumed silica has a silicone oil fixation rate of from 60 mass % to 95 mass %; and C) a composition obtained by adding 6 parts by mass of the silicone oil-treated fumed silica to 100 parts by mass of an amine composition containing trimethylolpropane polyoxypropylene triamine and 1,3-bis(aminomethyl)cyclohexane at a mass ratio of 95:5 has a viscosity of 4,000 mPa.Math.s or more after the composition is left to stand at 25° C. for 1 hour.