The present disclosure is directed to an ultra-high solids emulsion comprising a plurality of multiphase polymer particles, in which the multiphase particles comprises an acrylic-based copolymer derived from monomers comprising an alkyl methacrylate; an alkyl acrylate; a hydroxyalkyl acrylate; at least one or more acids; a vinyl aromatic compound; and a vinyl ester or vinyl lactam, a copolymerizable surfactant, at least one or more alkylphenol ethoxylate (APE) free nonionic surfactants, and at least one or more APE free anionic surfactants in aqueous medium in the presence of an initiator and a buffer. Additionally, methods for preparing such ultra-high solids emulsion and applications of such emulsion in coatings and adhesives are disclosed.

The present invention relates to a dispersant having a tertiary or quaternary amine anchoring group and a solubilizing polymer selected from C.sub.8-50 fatty acid; a C.sub.8-50 ak(en)yl substituted succinic acid, anhydride or partial ester; a dimer or trimer fatty acid; and/or polymers from repeating units of polyesters, polyethers, polyacrylate, polyamides, polyurethanes or mixtures of said repeating units in a random or blocky copolymer. The dispersants are an improvement in that the alkylene connecting group between the tertiary or quaternized amine and the solubilizing polymer lacks abstractable hydrogen atoms at the geminal carbon atom from the nitrogen of the tertiary or quaternized amine over the prior art. The dispersants are useful as dispersants with improved thermal stability and low amounts yellow color after aging at elevated temperatures.

Copolymers comprising recurring units of a phenyl glycidyl ether and alkylene oxides are disclosed. Some of the copolymers comprise a di- or polyfunctional nucleophilic initiator and recurring units of the phenyl glycidyl ether and an alkylene oxide. The di- or polyfunctional nucleophilic initiator is an alcohol, phenol, amine, thiol, thiophenol, sulfinic acid, or deprotonated species thereof. Other copolymers comprise a monofunctional nucleophilic initiator selected from thiols, thiophenols, aralkylated phenols, sulfinic acids, secondary amines, C.sub.10-C.sub.20 terpene alcohols, and deprotonated species thereof. Pigments dispersions comprising the copolymers are also disclosed. The copolymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the copolymers are also disclosed.

The present application provides a method of preparing lithium-friendly colloid paint. The method comprises functionalizing a carbon nanotube material to obtain a plurality of carbon nanotubes with functional groups; dispersing the of carbon nanotube material with functional groups in a solution containing nitrogen molecules to from the dispersion liquid to obtain a carbon nanotube precursor; heat-treating the carbon nanotube precursors to obtain a plurality of nitrogen-doped carbon nanotubes; dispersing the plurality of nitrogen-doped carbon nanotubes in an organic solvent, and adding a dispersant obtain a nitrogen-doped carbon nanotube solution precursor; and providing a polymer material colloid and a lithium salt, and uniformly mixing the nitrogen-doped carbon nanotube solution precursor, the lithium salt and the polymer material colloid.

A water-based acrylic latex paint has a dispersant-over-pigment (DOP) ratio between 0.5 and 1.5 to form a coating in which the pigment has a low concentration and is highly dispersed throughout to absorb in the visible band to produce a color (e.g., black) and is transmissive in the NIR and SWIR bands. The variables that determine absorption in the visible band and transmission in the NIR and SWIR bands include the DOP ratio, a pigment weight percentage between 1-2% in the paint and a coating thickness between 2 and 4 mil. To control the viscosity, the dispersing agent is suitably an acrylate-based block co-polymer, of molecular weight above 2,000 grams per mole, that includes an amine-functional block to anchor onto the pigment.

Disclosed is a transparent self-assembling polymer clay nanocomposite coating that is useful in food, drink and electronic packaging as a gas barrier and on textiles and clothing as a flame retardant coating. The coating includes two main components a water dispersible polymer and a sheet like nanoparticle. The coatings may be applied to any substrate. The coatings are applied sequentially with polymer being applied first followed by the nanoparticles. This sequence results in the self-assembly of a highly ordered nanocomposite film that exhibits high barrier properties and flame retardancy. The desired level of gas barrier or flame retardancy desired can be adjusted by the number of bilayers applied.

A resin-coated metal powder according to the present invention is obtained by covering at least a part of the surface of a metal powder with a hydrolyzable resin that has an average composition of general formula (1) and a number average molecular weight of from 500 to 100,000; and this resin-coated metal powder exhibits sufficient dispersibility in an aqueous solution, while being stable for a relatively long period of time even in the coexistence of water in an aqueous coating material.

##STR00001##

(In the formula, R.sup.1 represents a linear or branched monovalent hydrocarbon group having from 1 to 10 carbon atoms, said group optionally having a specific substituent such as a hydroxyalkyl group; each of R.sup.3, R.sup.4 and R.sup.5 independently represents a linear or branched monovalent hydrocarbon group having from 1 to 10 carbon atoms; each of R.sup.2 and R.sup.6 independently represents a hydrogen atom or a linear or branched monovalent hydrocarbon group having from 1 to 10 carbon atoms; and a and b represent numbers that satisfy 0a<1, 0<b1 and (a+b)=1.)

A dispersion includes a plurality of polymer particles, a plurality of inorganic particles, or a combination thereof dispersed in an aqueous solution, wherein the polymer particles, the inorganic particles, or the combination thereof are substantially insoluble in the aqueous solution. At least a portion of the surface of each particle includes one or more functional surfactants disposed on the surface of the particle. The functional surfactants include a C.sub.18-32 alkyl group; and at least one functional group that is a sulfonate group, a phosphate group, a ureido group, an acetoacetoxy group, a carboxylate group, a C.sub.1-12 fluorocarbon group, a zwitterionic group, a polyether group, a sugar group, a quaternary ammonium group, or a combination thereof. The dispersions can be useful in the preparation of coatings.

An aqueous silicone dispersion capable of forming an elastomer coating film when dried at a normal temperature, said aqueous silicone dispersion comprising: (A) a silicone elastomer which is an addition reaction product of an alkenyl group-containing organopolysiloxane (A-1) having 2 or more alkenyl groups per molecule, an organopolysiloxane (A-2) having 3 or more hydrosilyl groups per molecule and a linear diorganopolysiloxane (A-3) having hydrosilyl groups at both ends of the molecular chain; (B) an anionic surfactant; (C) a nonionic surfactant; (D) colloidal silica; and (E) water.

The present invention relates to a composition comprising: a) an aqueous dispersion of i) polymer particles functionalized with structural units of a phosphorus acid monomer; and ii) TiO.sub.2 particles; b) a sulfur acid functionalized dispersant; and c) a carboxylic acid functionalized dispersant. The composition of the present invention addresses a need in the art by providing a way to tune TiO.sub.2-binder composite formation efficiency with relative ease.