A multilayer coating film includes a lustrous layer containing a luster material and a colored layer containing a reddish coloring agent, and having translucency. Regarding a Y value of an XYZ colorimetric system calibrated with a standard white plate, when a light incident angle is 45, Y(5) represents a Y value of reflected light measured at a light receiving angle of 5, and Y(15) represents a Y value of reflected light measured at a light receiving angle of 15, the lustrous layer satisfies the following: Y(5) is 30 or more to 700 or less; Y(15)=kY(5) (where k is a coefficient); and k is 0.01 or more to 0.3 or less. The concentration of the reddish coloring agent in the colored layer is 1 mass % or more to 17 mass % or less.

A powder coating composition comprising: (a) a first acrylic powder resin having a hydroxyl value of at least about 180; (b) a second acrylic powder resin having a hydroxyl value between about 45 and about 80; (c) a crosslinker reactive with the hydroxyl functional acrylic resins; and (d) an acicular filler.

Coating material (237) for generating a coating layer by non-impact printing wherein the coating layer represents an image and wherein a resolution of the image is at least 100 DPI, the coating material comprising a curable resin; wherein the coating material (237) exhibits a minimum viscosity when being heated from room temperature with a heating rate of 5 Kelvin per minute up to a temperature where curing of the coating material occurs, wherein the minimum viscosity is in a range between 3 Pascal seconds to 20000 Pascal seconds, in particular in a range between 50 Pascal seconds and 10000 Pascal seconds and further in particular in a range between 250 Pascal seconds and 7000 Pascal seconds; and wherein a pill flow length is below 350 mm at a potential curing temperature which may be used to cure the coating material.

A developer comprises: at least one carrier; and, in an amount of 10 wt-% or less, a coating material (237), in particular for generating a coating layer by non-impact printing, the coating material being provided in the form of particles and comprising: a curable resin preferably an at least partially thermal curable resin and even more in particular curable by a crosslinking agent able to react with functional groups of the resin, the resin comprising in particular an amorphous resin portion; wherein an average diameter of the particles is in a range between 1 m and 25 m; and wherein the particles have an average sphericity larger than 0.7, in particular larger than 0.8, in particular a sphericity larger than 0.9; wherein, if the coating material is heated from room temperature with a heating rate of 5 K per minute, the coating material upon heating reduces its viscosity down to a minimum viscosity and increases its viscosity upon further increase of the temperature; wherein the minimum viscosity is in a range between 3 Pascal seconds and 20000 Pascal seconds.

There are very few violet or pink colored commercial pigments that display high heat stability, resistance to acidic conditions, or good lightfastness. This technology results in pigments that fall into the above color space, but display improved chemical and weathering stability. The pigments based of this technology have the molar ratio (A.sub.2O).sub.x(BO).sub.y(C.sub.2O.sub.5).sub.z(DO.sub.3).sub.w(EO.sub.2).sub.v, where 2x+y+2z+w+v100. Where A is Li or Li with one or more of Cu, Na, or K, where B is Co or Co with one or more of Ca, Cu, Fe, Mg, Mn, Ni, Sn, or Zn, where C is Nb, Sb, or combination thereof, where D is Mo, W or combination thereof, where E is Sn, Ti, Zr, or combination thereof. The above formulation may be modified with a dopant addition of Al, B, Ba, Bi, Ca, Ce, Cr, La, P, Pr, Si, Sr, Ta, V, or Y where the dopant concentration represents 5 atomic % or less of the total number of moles of components A+B+C+D+E.

The invention provides a powder coating material capable of forming a film excellent in metallic hue, concealing property and weather resistance. The powder coating material comprises the following fluororesin (A), the following resin (B) and the following pigment (C) as constituents thereof, wherein the content of the pigment (C) is from 0.7 to 23 mass %; Fluororesin (A): a fluororesin having a fluorine content of at least 10 mass %; Resin (B): a resin having a SP value larger than that of the fluororesin (A), and the difference between the SP value thereof and the SP value of the fluororesin (A) is at least 0.4 (J/cm.sup.3).sup.1/2; Pigment (C): a pigment which is a metallic pigment covered with a covering material, and the SP value of the covering material exceeds the SP value of the fluororesin (A) and less than the SP value of the resin (B).

The present invention relates to a particularly effective protective coating for metallic objects, the coating method, and the special applications thereof. The particularly high protective effect is achieved by the adaptation of the inorganic fraction and the organic polymer fraction of the coating to the specific surface of the object. Further adjustments of the coating can be used for further optimization, for example of the protection properties or other product properties.

Coating material (237) being processable by non-impact printing to form at least a part of a coating layer (206) representing an image; the coating material (237) comprising an amorphous resin portion and being curable; the coating material (237) being configured for being applied with a thickness of at least 15 m; wherein preferably the coating material (237) is configured for being applied with a thickness of at least 20 in particular with a thickness of at least 30 further in particular with a thickness of at least 40 m; the coating material comprising one or more of the following: (i) a polyester resin comprising at least one incorporated acid monomer and wherein at least 10 weight percent of the at least one incorporated acid monomer is isophthalic acid; (ii) a polyester resin containing 1 to 100 w-% of cycloaliphatic glycol compounds with respect to the total weight of the glycol compounds of the polyester resin component, in particular 2,2,4,4-tetraalkylcyclobutane-1,3-diol and/or 2,2,4,4-tetramethyl-1,3-cyclobutanediol; (iii) an acrylic resin; (iv) a fluorine containing polymer, in particular a hydroxyl functional fluorine polymer; (v) a polyurethane resin.

A pigment pellet preparation, comprises one or more effect pigment and one or more thermosetting resin. The effect pigment is dispersed in the thermosetting resin. The thermosetting resin has 3 or more reactive terminal groups and has an acid number from about 10 to about 50 mg KOH/g resin. The preparation comprises from about 70% to about 90% by weight of one or more effect pigment and from about 5% to about 35% by weight of one or more thermosetting resin. The pigment and thermosetting resin comprise about 95% or more of the preparation. The pellets have a diameter of about 0.5 mm to about 5 mm and a length of about 1 mm to about 5 cm.

The invention is targeted mainly at a polymer powder suitable for 3D printing by sintering, comprising: (a) a polymer composition comprising at least one thermoplastic elastomer; (b) a pigment composition comprising at least one pigment exhibiting an absorbance of the light with a wavelength of 1000 nm, as measured according to the standard ASTM E1790, of less than 50%; and also, if appropriate, (c) one or more fillers or reinforcements; and (d) one or more additional additives.

The invention is also targeted at a process for the preparation of said powder and also at the use of said powder for 3D printing by sintering. Finally, it is targeted at the use of a pigment exhibiting an absorbance of the light with a wavelength of 1000 nm, as measured according to the standard ASTM E1790, of less than 50% to improve the definition and/or the mechanical properties of the articles printed by a process of 3D printing by sintering of a thermoplastic elastomer powder.