Anti-corrosion metal pretreatment compositions comprising a Group IVB metal, a Group IB metal and polyamidoamine polymers; replenisher compositions for the metal pretreatment compositions; methods of making the metal pretreatment compositions; methods of forming an anti-corrosion Group IVB oxide coating on at least one metal substrate surface by contacting the surface with the metal pretreatment composition; and coated metal substrates having anti-corrosion coatings deposited on the metal substrates from chrome VI free, anti-corrosion metal pretreatment compositions having enhanced corrosion resistance of the Group IVB metal oxide coatings and adhesion of the anti-corrosion and primer coating layers to metal substrates.

Provided is a surface treatment solution composition comprising: 30 to 51 wt % of a trivalent chromium compound comprising chromium phosphate (A) and chromium nitrate (B) and having a content ratio of A/(A+B) that satisfies 0.3 to 0.6; 5 to 15 wt % of silane coupling agent; 0.2 to 3 wt % of vanadium-based anti-corrosive rust inhibitor; 3 to 12 wt % of colloidal silica; 0.5 to 5 wt % of polysiloxane copolymer; and 14 to 61.3 wt % of water, a hot dip galvanized steel sheet surface-treated using same, and a manufacturing method thereof. The hot dip galvanized steel sheet treated with the surface treatment solution composition containing trivalent chromium has an excellent corrosion resistance, blackening resistance, pipe-forming oil reactivity, and alkali resistance.

Self-fusing silicone tapes contain neutral corrosion inhibitors therein such as salts of acids. Such tapes provide protection in an acid gas environment as well as under thermal insulation. The same also allows inspection of protected structure without removing the protection apparatus.

Coating compositions for coating an oilfield operational component, and related methods, may include in some aspects a coating composition having a trifunctional silane, a silanol, and a filler. The coating composition may be applied to a surface of the oilfield operational component that is configured to be exposed to a fluid. The coating composition may be applied to at least partially cover or coat the surface. The coating composition may be configured to chemically bond with a cured primer composition that includes an epoxy.

An electrical assembly includes a metallic component having a bottom portion that is buried in the earth, a top portion that is above the earth, and an outer surface. A water-impermeable electrically-conductive covering is applied to the outer surface at the bottom portion and is in electrical contact with the earth. The covering includes a water-impermeable polymeric matrix that protects the metallic component from corrosion, and a particulate carbonaceous material that is dispersed in the polymeric matrix and that allows for the metallic component to be electrically grounded.

A method for preparing a vinyl-modified fluorocarbon resin comprises mixing a fluorine-containing vinyl monomer, an initiator, and a tetrafluoroethylene monomer in a gas phase to carry out an addition reaction so as to obtain the vinyl-modified fluorocarbon resin. The fluorine-containing vinyl monomer is grafted onto tetrafluoroethylene, resulting in a vinyl-modified fluorocarbon resin which is highly resistant to strong acids and bases as well as weathering. The corrosion resistant coating prepared by using the resin as a base resin also has high resistances to strong acids and bases as well as weathering.

A method for producing a glass-like protective layer on an optionally pre-coated metal or glass substrate. The method comprises: (a) mixing one or more defined silicon compounds with NaOH and KOH, (b) adding water to the mixture obtained in (a) to hydrolyze the silicon compound(s), (c) adding at least one defined compound of formula MY.sub.m,
where M is Pb, Ti, Zr, Al or B, to the hydrolyzed mixture obtained in (b), wherein the molar ratio M/Si is from 0.01/1 to 0.04/1, to obtain a coating sol, (d) applying the coating sol obtained in (c) to the substrate, and (e) thermal densification of the coating sol applied in d) at a temperature of from 300° C. to 500° C. to form the glass-like protective layer.

Embodiments described herein relate generally to large scale synthesis of thinned graphite and in particular, few layers of graphene sheets and graphene-graphite composites. In some embodiments, a method for producing thinned crystalline graphite from precursor crystalline graphite using wet ball milling processes is disclosed herein. The method includes transferring crystalline graphite into a ball milling vessel that includes a grinding media. A first and a second solvent are transferred into the ball milling vessel and the ball milling vessel is rotated to cause the shearing of layers of the crystalline graphite to produce thinned crystalline graphite.

A corrosion inhibiting additive and methods of making the corrosion inhibiting additive are described. The corrosion inhibiting additive comprises a metal appended deactivated aromatic compound. The method includes reacting a metal salt with a deactivated aromatic compound to form a metal appended dichloro-diphenyl sulfone. Corrosion inhibiting coating compositions including the metal appended deactivated aromatic compound are also described.

The present invention is directed to provide a corrosion-resistant coating composition that is capable of forming a coating film with superior moisture resistance and a superior corrosion-resistant property for a long period, particularly over a long period even under acidic environmental conditions, further with superior storage stability.

The corrosion-resistant coating composition of the present invention comprises a coating film-forming resin (A), a crosslinking agent (B), and a magnesium hydroxide (C), wherein the oil absorption of the magnesium hydroxide (C) is 70 g/100 g or less and wherein the BET specific surface area is 4.0 m.sup.2/g or less.