New selenated thiourea hybrid compounds are described herein, as well as the use of such selenated thiourea hybrid compounds in inhibiting corrosion of a steel material. Also described are methods for forming the new selenated thiourea hybrid compounds as well as anti-corrosion coatings containing the selenated thiourea hybrid compounds.

A titanium dioxide micro-nanocontainers, corrosion-resistant waterborne epoxy coatings and preparation method thereof, including preparation steps as follows: TiO.sub.2 micro-nano spheres are synthesized by applying hydrothermal method; a polyaniline layer doped with molybdate ions is deposited on the surface of TiO.sub.2 micro-nano spheres by adopting the method of in-situ chemical polymerization, TiO.sub.2/PANI-MoO.sub.4.sup.2? micro-nano-spheres are obtained, then, polydopamine is encapsulated on the surface of TiO.sub.2/PANI-MoO.sub.4.sup.2? micro-nano spheres to obtain titanium dioxide micro-nanocontainers; next, antirust filler, defoamer, dispersant and thickener are added into waterborne epoxy emulsion, then titanium dioxide micro-nanocontainers are added in the waterborne epoxy emulsion for dispersing and grinding, filtering and encapsulating to obtain component A; the waterborne epoxy curing agent and deionized water are mixed in proportion to obtain component B; component A is stirred, then it is mixed with the component B in proportion, corrosion-resistant waterborne epoxy coatings is obtained. According to the invention, the titanium dioxide micro-nanocontainers is synthesized and added into the coating as an additive, which can not only improve the compatibility between the filler and the emulsion, but greatly improves the long-term corrosion resistance of the coating by prolonging the release time of the corrosion inhibitors.

Provided is a humic acid-based coating suspension comprising humic acid, particles of an anti-corrosive pigment or sacrificial metal, and a binder resin dissolved or dispersed in a liquid medium, wherein the humic acid has a weight fraction from 0.1% to 50% based on the total coating suspension weight excluding the liquid medium. Also provided is an object or structure coated at least in part with such a coating.

The present invention generally relates to methods and compounds for preventing metal corrosion. More specifically, the method comprises contacting a hydrocarbon-containing liquid with a composition in an effective amount to prevent metal corrosion.

The present invention discloses methods for producing a covalently attached antioxidant coating using a multi-step coating process consisting of (1) exposing the substrate surface to plasma polymerization to produce a surface containing functional groups; (2) contacting the surface containing functional groups with crosslinking agents to produce a reactive surface; (3) contacting the reactive surface with a solution of one or more antioxidant compounds or a solution of one or more antioxidant-containing polymers. Alternatively, the third step is replaced by (3) contacting the reactive surface with a solution of one or more polymers to produce a polymer coated surface and (4) covalently attaching one or more antioxidant compounds to the polymer coated surface.

An alkoxysilane is contacted with water and an inorganic acid to form a first composition. A zirconium alkoxide is contacted with an organic acid to form a second composition. One or more alkoxysilanes and an organic acid are contacted with a mixture of the first and second compositions to form a sol-gel composition, to which a photoinitiator is added. The sol-gel composition has a ratio of a number of moles of silicon to a number of moles of zirconium (n.sub.Si/n.sub.Zr) ranging from about 2 to about 10. The sol-gel composition is applied on a substrate (e.g., an aluminum alloy substrate) multiple times to form multiple sol-gel layers, and at least one of the sol-gel layers is cured by UV radiation. The multiple sol-gel layers are then thermally cured.

A corrosion inhibiting composition includes a first plurality of carriers and a second plurality of carriers. The first plurality of carriers has a first carrier body which encapsulates a film-forming compound. The second plurality of carriers has a second carrier body encapsulates a corrosion inhibitor. Each of the first and second carrier bodies is formed of a degradable material. Coatings and methods for inhibiting corrosion on a metal substrate are also described herein.

Provided are a 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating and a preparation method thereof, the raw materials of which comprising, by mass ratio: 2-mercaptobenzothiazole modified graphene oxide 5-20; a matrix resin 30-70; a leveling agent 0.5-1.0; a defoamant 0.5-1.0; a dispersant 0.5-1.0; a film-forming additive 0.5-1.0; a diluent 20-35. The method for the 2-mercaptobenzothiazole modified graphene oxide comprises first reacting graphene oxide with cyanuric chloride, then reacting with 2-mercaptobenzothiazole.

A corrosion inhibiting composition includes a first plurality of carriers and a second plurality of carriers. The first plurality of carriers has a first carrier body which encapsulates a film-forming compound. The second plurality of carriers has a second carrier body encapsulates a corrosion inhibitor. Each of the first and second carrier bodies is formed of a degradable material. Coatings and methods for inhibiting corrosion on a metal substrate are also described herein.

A corrosion inhibiting additive and methods of making the corrosion inhibiting additive are described. The corrosion inhibiting additive comprises a metal appended deactivated aromatic compound. The method includes reacting a metal salt with a deactivated aromatic compound to form a metal appended dichloro-diphenyl sulfone. Corrosion inhibiting coating compositions including the metal appended deactivated aromatic compound are also described.