A heteroaryl-thio-substituted pyrone compound that is a heteroaryl-thio-substituted pyrone or a heteroaryl-thio-substituted coumarin. In various embodiments, the heteroaryl-thio-substituted pyrone compound or a reaction product thereof is a metal corrosion inhibitor.

A composition for application to a metal substrate comprises a metal cation, an azole compound and an aqueous carrier. A composition for coating a substrate comprises a carrier comprising an epoxy carrier, a urethane carrier, or a fluorinated urethane carrier, and an azole compound. A coated substrate includes the composition for application to a metal substrate and a coating on the composition. A method of fabricating a coated substrate comprises applying the composition to a substrate, allowing the composition to dry to form a conversion coating, and applying a coating on the conversion coating.

A surface protection composition contains (a) a phosphorus compound represented by formula (1), ##STR00001## wherein R.sup.1 represents a hydrogen atom, R.sup.2 represents a hydrocarbon group having 4 to 30 carbon atoms, and R.sup.3 represents a hydrogen atom or a hydrocarbon group having 4 to 30 carbon atoms, (b-1) a metal-containing compound or (b-2) an amine compound, (c) a (meth)acrylate having a hydrocarbon chain having 4 or more carbon atoms, (d-1) an acylphosphine oxide photopolymerization initiator and (d-2) an ?-aminoacetophenone photopolymerization initiator, wherein the composition has the compound (d-1) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition, compound (d-2) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition and a total amount of the compound (d-I) and (d-2) is less than 5.0 mass % with respect to the total amount of the composition.

A method of preventing formation of rust on a metal surface is provided. The method may include applying a polyamine onto the metal surface and applying a compound of formula (I) or salt thereof onto the metal surface. The compositions and methods disclosed herein may be used to inhibit corrosion of a metal surface in contact with an aqueous system. ##STR00001##

Coating composition and respective process for applying same to metal substrates. The present invention pertains to the field of coatings, more specifically to an anti-corrosion coating composition comprised of at least three layers to provide protection against galvanic corrosion. The coating (5) is configured by at least three distinct layers (2, 3, 4) applied to the same metallic component. The base layer (2) consists of an organometallic dispersion containing zinc and aluminum alloys or a zinc or zinc alloy base applied electrolytically to the metal surface (1). An aqueous intermediate layer (3) is applied over the base layer (2) containing silicon oxide nanoparticles of up to 50 nanometers. An outer layer (4) rich in aluminum dispersed in organic solvents or water and binding elements is also affixed to intermediate layer (3). The present invention further discloses a process for applying the coating (5) and the use thereof in fastening elements that are in direct contact with aluminum components that are much larger than said fastening elements, in order to prevent galvanic corrosion.

The invention pertains to a method for providing a metallicor concrete surface of a chemical installation with a coating, which comprises the steps of:providing a two-pack coating composition wherein the first pack comprises an epoxy resin and the second pack comprises an amine curing agent for the epoxy resin, the coating composition further comprising an organoboron compound of the formula (I), wherein X is anorganic group having 1 to 24 carbon atoms and is linked to the boron atom via a carbon-boron bond, and wherein Y is an at least divalent organic group having 2 to 16 carbon atoms, combining the first pack and the second pack to form a coating composition,applying the coating composition to the surface of a chemical installation to form a coating layer, andallowing the coating layer to cure at a temperature in the range of 10 to 50 C. A chemical installation provided with a lining of a cured coating composition as specified above, and a suitable coating composition, are also claimed. It has been found that the coating composition as specified herein has a wide application spectrum, and a high chemical resistance.

##STR00001##

The invention pertains to a method for providing a metallic or concrete surface of a chemical installation with a coating, which comprises the steps ofproviding a two-pack coating composition wherein the first pack comprises an epoxy resin and the second pack comprises an amine curing agent for the epoxy resin, the coating composition further comprising an organoboron compound of the formula BX1X2X3, wherein X1, X2, and X3 are independently selected from Y1 and OY2, wherein Y1 is independently selected from monovalent C1-C12 alkyl groups and monovalent C6-C12 aryl groups, and Y2 is independently selected from monovalent C1-C12 alkyl groups and monovalent C6-C12 aryl groups, and wherein at least one of X1, X2, and X3 is an OY2 group,combining the first pack and the second pack to form a coating composition,applying the coating composition to the surface of a chemical installation to form a coating layer, andallowing the coating layer to cure at a temperature in the range of 0 to 50 C. A chemical installation provided with a lining of a cured coating composition as specified above, and a suitable coating composition, are also claimed. It has been found that the coating composition as specified herein has a wide application spectrum, and a high chemical resistance.

A method of forming anti-rust or anti-bacterial film includes mixing a predetermined liquid and a film-forming composition which contains a tannic acid derivative in which hydrogen atoms in at least 10% of hydroxyl groups of tannic acid are substituted by a chain hydrocarbon group having 10 to 16 carbon atoms, and removing the liquid.

Hydrotetrazine compounds having antioxidant properties and uses thereof are described herein. These compounds may be dihydrotetrazines, tetrahydrotetrazines, or hexahydrotetrazines that can be utilized as antioxidants for use in thermoplastics, thermosets and elastomers; free radical inhibitors to stabilize reactive chemicals, such as monomers against free radical polymerizations; and as anticorrosion agents in coatings to protect against metal oxidation. The hydrogenated tetrazines can donate hydrogen atom equivalents to terminate radical chain reactions. These compounds can change colors to signal when oxidation has occurred, and can be further recycled by reduction reactions.

Method for preparation of 5-alkylsalicylaldoximes with formula 1, where R is a C6-C16 alkyl group, consisting in that into a water-alcohol solvent system, p-alkylphenol, sodium hydroxide, chloroform and hydroxylamine are introduced, while in relation to the alkylphenol used, sodium hydroxide and chloroform are used in amounts from the stoichiometric amount to a 100% excess, and hydroxylamine is used in amounts from the stoichiometric amount to a 60% excess, and the reaction is carried out at a temperature of 60-75? C. for 1.5-4 h, and then, at a temperature of 20-30? C., the post-reaction mixture is acidified till the pH of the aqueous phase <7.0 is obtained, and next, an alcohol-water azeotrope is distilled off with an admixture of unreacted chloroform, the residue is mixed with a neutral C5-C10 hydrocarbon solvent, the layers are separated, and the solvent is distilled off from the organic phase.