New selenated thiourea hybrid compounds are described herein, as well as the use of such selenated thiourea hybrid compounds in inhibiting corrosion of a steel material. Also described are methods for forming the new selenated thiourea hybrid compounds as well as anti-corrosion coatings containing the selenated thiourea hybrid compounds.

The disclosure relates to a coating composition comprising: a) a resin system comprising an organic film-forming resin and optionally a curing agent reactive with the organic film-forming resin, b) a lithium salt with a solubility in water in the range from 0.01 to 120 g/L at 20 C., selected from the group consisting of lithium carbonate, lithium phosphate, lithium bicarbonate, lithium tetraborate, and lithium oxalate, in an amount of at least 1.3 wt. % of lithium based on solid weight of the resin system, and c) a zinc salt of 2,5-dimercapto-1,3,4-thiadiazole (DMTD). The zinc salt of DMTD was shown to have a synergistic effect on the reinforcement of barrier properties of a protective layer that is formed in a coating defect due to the presence of the lithium salt in the coating composition.

The disclosure relates to a coating composition comprising a resin system comprising an organic film-forming resin and optionally a curing agent reactive with the organic film-forming resin, a lithium salt with a solubility in water in the range from 0.01 to 120 g/L at 20 C., selected from the group consisting of lithium carbonate, lithium phosphate, lithium bicarbonate, lithium tetraborate, and lithium oxalate, and a zinc salt of 2,5-dimercapto-1,3,4-thiadiazole (DMTD), wherein the zinc salt of DMTD is present as solid particles, the surface of which is at least partially covered by a layer of a film-formed polymer. The zinc salt of DMTD was shown to have a synergistic effect on reinforcement of barrier properties of a protective layer that is formed in a coating defect due to the presence of the lithium salt. In addition, the coating composition has an improved pot life.

Described herein is a composition including at least one polyurethane polymer. Also described herein are a method of using the composition including at least one polyurethane polymer for metal pre-treatment and a process for metal pre-treatment.

Aspects described herein generally relate to a sol-gel that is the reaction product of an organosilane, a metal alkoxide, an acid, and a thio-lanthanide salt having a solubility of about 1 gram or greater per gram of sol-gel at 23 C. The thio-lanthanide salt includes a cation and a thio-ligand. The cation can be lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, cobalt, calcium, strontium, barium, and zirconium. In another aspect, a component, such as a vehicle component, includes a metal substrate and a sol-gel disposed on the metal substrate. Methods can include forming a sol-gel by mixing a metal alkoxide and an acid to form a first mixture; mixing with the first mixture an organosilane to form a second mixture; and mixing with the second mixture a lanthanide salt to form a third mixture.

Compositions are described for protecting a metal surface against corrosion. The composition includes a corrosion-inhibiting particle. The corrosion inhibiting particle may be usable in an epoxy resin-based coating or an olefin resin-based coating. The particle may include a core and a protectant. The core may include a water soluble corrosion inhibitor. The protectant may be disposed on at least a portion of a surface of the core and may be covalently or ionically bonded to a thiol group of the corrosion inhibitor. The protectant may be configured to reduce reaction between the core and the epoxy resin or the olefin resin. Methods of making the compositions are also disclosed.

Corrosion inhibition systems, including coated substrates, coating materials and corrosion inhibition compounds, and methods of making the same are disclosed. These systems and methods include corrosion inhibition compounds that are responsive to corrosion at a surface, releasing active inhibitor groups upon a corrosion stimulus. The active inhibitor groups are selected to block corrosion at the surface by inhibiting oxidation reactions, reduction reactions and/or by forming a passivation layer. Corrosion inhibition compounds may be linear polymers that include the inhibitor groups linked together with labile linkages that are disulfide or metal-sulfide bonds.

Disclosed are petrolatum-like compositions that include metathesized unsaturated polyol esters. Also disclosed are emulsions that include metathesized unsaturated polyol esters. The petrolatum-like compositions may be used as substitutes for petroleum-based petrolatum. The emulsions may be water-in-oil or oil-in-water emulsions and may be suitable for a variety of end uses.

A coated steel sheet comprises: a steel sheet; a primer coating film which is arranged on the steel sheet and comprises an anti-corrosive pigment and an aggregate composed of primary particles; and a top coating film which is arranged on the primer coating film. The anti-corrosive pigment comprises at least one compound selected from the group consisting of a bivalent tin salt, a trivalent vanadium salt, a tetravalent vanadium salt, a tetravalent molybdenum salt, an oxycarboxylic acid salt, an ascorbic acid, a phosphorous acid salt and a hypophosphorous acid salt.

A process for coating a metallic surface of a metallic substrate comprising applying, an organic, anionically, cationically or radically curable anticorrosive composition, to the metallic surface, wherein said anticorrosive composition is a dispersion or solution containing at least two components that are at least partially anionically, cationically or radically curable, wherein at least one monofunctional monomer or monofunctional oligomer is present, a photoinitiator, and first organic corrosion inhibitor.