The present application discloses a method of forming a hydrogel-coated substrate, wherein the hydrogel has antifouling and antimicrobial properties. The method comprises applying an aqueous pre-hydrogel solution to a substrate, polymerizing the aqueous pre-hydrogel solution, thereby forming a coated substrate having a conformal hydrogel coating and a non-conformal hydrogel coating, contacting the coated substrate with a swelling agent, and removing the non-conformal hydrogel coating from the coated substrate, thereby leaving the conformal hydrogel coating on the substrate to form the hydrogel-coated substrate. The aqueous pre-hydrogel solution comprises a monomer with antimicrobial activity, a monomer with antifouling activity, and either a polymer, oligomer, or macromer which, when polymerized together, form a hydrogel. Also disclosed is a coated substrate and a hydrogel coating.

The present invention belongs to the technical field of marine anti-fouling materials, and discloses a self-polishing zwitterionic anti-fouling resin having a main chain degradability and the preparation therefor and the use thereof. The self-polishing zwitterionic anti-fouling resin is formed by copolymerizing the following three monomers (in the total mass of the monomers): 1% to 80% of an olefinic reactive monomer, 1% to 80% of a cycloketene acetal monomer, and 1% to 80% of a betaine type precursor. The anti-fouling resin has a main chain degradability and a side chain hydrolyzability, and the transition of a coating from being hydrophobic to being hydrophilic is achieved by the hydrolysis of a surface to produce a super-hydrophilic zwitterionic surface, in order to further enhance the anti-fouling ability of the system. The material not only overcomes the disadvantages of poor mechanical properties and poor solubility in an organic solvent of a zwitterionic material, but can also effectively control the long-term stable release of an anti-fouling agent, so as to achieve a synergistic anti-fouling effect of the anti-fouling agent and an anti-protein. The method of the present invention is simple, has a relatively low cost, and is suitable for industrial production. The material is used in the field of marine anti-fouling coatings.

A modified conductive structure includes a conductive substrate and a polymer film disposed over a surface of the polymer film. A chemical bond exists between the polymer film and the conductive substrate, and the polymer film includes repeating units as shown below:

##STR00001##

wherein A is an antifouling molecule group; B is a sulfur-containing group or a nitrogen-containing group; R is a single bond or a first linking group; C is -L-E, wherein L is a second linking group, E is an enzyme unit; x and z are each independently 0 or an integer from 1 to 10000, and y is an integer from 1 to 10000; o is 0 or an integer from 1 to 50, and when o is an integer from 1 to 50, m and n are each independently 0 or an integer from 1 to 50.

Provided is a surface-protective coating composition capable of forming a surface-protective coating film in which the occurrence of cracks is suppressed during the formation of the coating film, while using a polymer having marine biodegradability. Also provided are: a surface-protective coating film formed from the surface-protective coating composition; a substrate with a surface-protective coating film, which is coated with the surface-protective coating film, and a method of producing the same; and a surface protection method using the surface-protective coating film. The surface-protective coating composition according to the present invention contains a polycaprolactone-based polymer (A) and a zinc oxide (B), wherein the polycaprolactone-based polymer (A) has an acid value of 5 mgKOH/g or more and 200 mgKOH/g or less, and a structural unit derived from caprolactone in the polycaprolactone-based polymer (A) has a content of 50% by mass or more and 99.5% by mass or less.

The present invention provides an antifouling coating formed from a water-based coating composition comprising 0.1% by mass to 10% by mass of ultrafine silica particles having an average particle size equal to or less than 25 nm, 5% by mass to 50% by mass, relative to the ultrafine silica particles, of a zirconium compound which is at least one selected from zirconium chloride and zirconyl chloride, and 30% by mass to 99.5% by mass of water. In accordance with the present invention, it is possible to provide an antifouling coating that can maintain the antifouling performance and hydrophilicity and prevent corrosion of fins even under an environment with a large amount of contaminating substances, such as metal particles, in the air.

Curable heat-expanding debondable coating compositions for use as a pre-coating or surface preparation in conjunction with adhesive composition. The debondable coating compositions include heat-expandable microspheres which are designed to expand in a specified temperature range, thereby debonding the coating compositions from a substrate. Adhesive compositions are overlaid on the debonding coating and are subsequently debonded from the substrate along with the debondable coating composition.

A composition for an antifogging coating includes isosorbide epoxy represented by Formula 1 below, a hardener, a hardening accelerator, and a silane coupling agent, ##STR00001## wherein n is 0.2 to 7.

The present invention provides a composition for substrate surface modification and a method using the same, and the composition for substrate surface modification is composed of a compound of the general formula structure shown in formula 1:

##STR00001##

wherein n.sub.1 is an integer of 1 to 6, and R is a zwitterionic group. The composition for substrate surface modification uses water as a medium to perform modifying reaction over a substrate surface, and at the same time has biological modification characteristics, and abilities of immobilizing biomolecules and anti-biofouling.

The invention relates to a hull of a vessel having characteristic surface properties, allowing an increase in surface runoff while benefiting from an inherent anti-fouling property and an original aesthetic appearance. Furthermore, the invention allows the incorporation of said outer composite envelope into the structure of the hull, thereby preventing delamination problems and inherently providing a vessel hull with the above-mentioned properties.

A method of forming a hydrophobic and oleophobic surface. The method including spin coating an F-POSS with 3,3-dichloro-1,1,1,2,2,-pentafluoropropane/1,3-dichloro-1,1,2,2,3-pentafluoropropane onto an inert surface. The F-POSS has a structure: ##STR00001## Each R.sub.f represents a nonreactive, fluorinated organic group, R.sub.1 represents a first monovalent organic group comprising at least two carbon atoms, and R.sub.2 represents hydrogen or a second monovalent organic group comprising at least two carbon atoms. The F-POSS with 3,3-dichloro-1,1,1,2,2,-pentafluoropropane/1,3-dichloro-1,1,2,2,3-pentafluoropropane are then dried on the inert surface.