A water-dispersed electrodeposition solution (11) for forming an insulating film includes: polymer particles; an organic solvent; a basic compound; and water. The polymer particles are made of: any one of; or both of polyamide-imide and polyester-imide, main chains thereof being free of an anionic group, a number-based median diameter D.sub.50 of the polymer particles is 0.05 m to 0.5 m, and polymer particles having a particle size within 30% to +30% of the number-based median diameter D.sub.50 are 50% or more of all of the polymer particles on a number basis.

The invention provides a method of improving the corrosion resistance of a metal substrate. The method comprises: (a) electrophoretically depositing on the substrate a curable electrodepositable coating composition to form a coating over at least a portion of the substrate, and (b) heating the substrate to a temperature and for a time sufficient to cure the coating on the substrate. The electrodepositable coating composition comprises a resinous phase dispersed in an aqueous medium, the resinous phase comprising: (1) an ungelled active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (2) an at least partially blocked polyisocyanate curing agent; and (3) a pigment component comprising an inorganic, platelike pigment having an average equivalent spherical diameter of at least 0.2 microns. The electrodepositable coating composition demonstrates a pigment-to-binder ratio of at least 0.5. The coating composition contains less than 8 percent by weight of a grind vehicle.

The invention provides a method of improving the corrosion resistance of a metal substrate. The method comprises: (a) electrophoretically depositing on the substrate a curable electrodepositable coating composition to form a coating over at least a portion of the substrate, and (b) heating the substrate to a temperature and for a time sufficient to cure the coating on the substrate. The electrodepositable coating composition comprises a resinous phase dispersed in an aqueous medium, the resinous phase comprising: (1) an ungelled active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (2) an at least partially blocked polyisocyanate curing agent; and (3) a pigment component comprising an inorganic, platelike pigment having an average equivalent spherical diameter of at least 0.2 microns. The electrodepositable coating composition demonstrates a pigment-to-binder ratio of at least 0.5. The coating composition contains less than 8 percent by weight of a grind vehicle.

A challenge of the present invention is to provide a water-based coating composition capable of providing a design superior in depth feeling in the formation of a multilayer coating film having a so-called color clear coating film. The present invention relates to a water-based coating composition comprising a coating film-forming resin (i) and a coloring pigment dispersion (ii), wherein the coating film-forming resin (i) comprises: an acrylic resin emulsion (A) having an average particle diameter of 100 nm or less in an amount of 10 to 60% by mass in terms of the resin solid content of the coating film-forming resin (i),a water-soluble acrylic resin (B) in an amount of 5 to 40% by mass in terms of the resin solid content of the coating film-forming resin (i), and a melamine resin (C) in an amount of 20 to 40% by mass in terms of the resin solid content of the coating film-forming resin (i); and the coloring pigment dispersion (ii) comprises a coloring pigment (D) having a 90%-volume particle diameter (D90) of 100 nm or less.

Self-healing polymers used to fabricate electrical devices or to coat electrical devices that have a metal or polymer substrate. The self-healing polymers can be made from modified polymers including polyurethanes, polyureas, polyamides and polyesters and, optionally, cross-linking agents and one or more catalysts. The self-healing polymers can be used to make cable ties, tape, conduit fittings and explosion-proof sealant materials.

The invention provides a method of improving the corrosion resistance of a metal substrate. The method comprises: (a) electrophoretically depositing on the substrate a curable electrodepositable coating composition to form a coating over at least a portion of the substrate, and (b) heating the substrate to a temperature and for a time sufficient to cure the coating on the substrate. The electrodepositable coating composition comprises a resinous phase dispersed in an aqueous medium, the resinous phase comprising: (1) an ungelled active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (2) an at least partially blocked polyisocyanate curing agent; and (3) a pigment component comprising an inorganic, platelike pigment having an average equivalent spherical diameter of at least 0.2 microns. The electrodepositable coating composition demonstrates a pigment-to-binder ratio of at least 0.5. The coating composition contains less than 8 percent by weight of a grind vehicle.

The invention provides a method of improving the corrosion resistance of a metal substrate. The method comprises: (a) electrophoretically depositing on the substrate a curable electrodepositable coating composition to form a coating over at least a portion of the substrate, and (b) heating the substrate to a temperature and for a time sufficient to cure the coating on the substrate. The electrodepositable coating composition comprises a resinous phase dispersed in an aqueous medium, the resinous phase comprising: (1) an ungelled active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (2) an at least partially blocked polyisocyanate curing agent; and (3) a pigment component comprising an inorganic, platelike pigment having an average equivalent spherical diameter of at least 0.2 microns. The electrodepositable coating composition demonstrates a pigment-to-binder ratio of at least 0.5. The coating composition contains less than 8 percent by weight of a grind vehicle.

The invention provides an electrodepositable coating composition comprising a resinous phase dispersed in an aqueous medium, said resinous phase comprising: (1) an ungelled active hydrogen-containing, cationic salt group-containing resin; (2) an at least partially blocked polyisocyanate curing agent; and (3) a pigment component, wherein the pigment component comprises an inorganic, platelike pigment present in the resinous phase, wherein the electrodepositable coating composition contains less than 8 percent by weight of a grind vehicle, based on the total weight of solids in the electrodepositable coating composition. The invention also provides methods of improving the corrosion resistance of a metal substrate and coated substrates.

The invention relates to a method for grafting an organic film onto an electrically conductive or semiconductive surface by electro-reduction of a solution, wherein the solution comprises one diazonium salt and one monomer bearing at least one chain polymerizable functional group. During the electrolyzing process, at least one protocole consisting of an electrical polarization of the surface by applying a variable potential over at least a range of values which are more cathodic that the reduction or peak potential of all diazonium salts in said solution is applied. The invention also relates to an electrically conducting or semiconducting surface obtained by implementing this method.

The invention further relates to electrolytic compositions.

A fast drying, heavy metal-free, high performance coating composition with outstanding UV resistance, and excellent corrosion resistance coupled with fast dry and long pot life. This coating can be applied over DTM, such as blasted cold rolled steel, or treated cold rolled steel, aluminum and treated aluminum. High corrosion resistance without sacrificing gloss or UV resistance achieved by selecting proper pigments and proper pigment design and packing by advantageously utilizing differing pigment morphologies (sizes and shape).