Patent classifications
C09D7/67
Water-based UV coatings, preparation method therefor and application thereof
A water-based dual-cure coating comprising the following raw material components: 15-25 parts by weight of a water-based polycarbonate dispersion, 30-60 parts by weight of a water-based aliphatic polyurethane acrylate dispersion, 5-15 parts by weight of a UV reactive diluent, 1-4 parts by weight of a photoinitiator, 0.2-1 part by weight of an auxiliary agent, 3-8 parts by weight of a film coalescing aid, and 5-15 parts by weight of water. The coating is sprayed onto an automotive interior part and subsequently cured by baking at a temperature of 50-65? C. to form a film, proceeding UV curing; and proceeding thermal curing at temperature of 70-80? C.
COATING FILM AND COMPONENT PART
A coating film includes a water-repellent resin having a smooth surface and a contact angle of 70 degrees or more. The coating film has a plurality of protrusions formed by the water-repellent resin, and the plurality of protrusions are scattered in the coating film and each have an end portion with a convex surface formed by cutting out a continuous region accounting for 50% or more of a spherical surface. The spherical surfaces each have an average radius of curvature of 16 ?m or less. An average distance between each ones of the plurality of protrusions adjacent to each other is less than or equal to 30 times a radius of curvature.
COATING COMPOSITION
Provided is a coating composition comprising (a) a matrix mixture, comprising (i) one or more urethane multi(meth)acrylates (ii) one or more non-urethane multi(meth)acrylates (iii) optionally one or more mono(meth)acrylates (iv) one or more initiators; (b) zirconia,; and wherein the weight ratio of (a) to (b) is from 0.06:1 to 2.8:1, and wherein the amount of (a) plus the amount of (b) is 1% to 100% by weight based on the weight of said coating composition. Also provided is a coated article formed by a process comprising (A) applying a layer of the coating composition to a surface of a substrate, (B) removing said solvent from said layer of the coating composition, and (C) curing, or allowing to cure, said layer of the coating composition.
PHOTOCURABLE COATING COMPOSITION FOR FORMING LOW REFRACTIVE LAYER
The present invention relates to a photocurable coating composition for forming a low refractive layer, a method for preparing an antireflection film using the photocurable coating composition, and an anti-reflective film prepared by using the photocurable coating composition. According to the present invention, a low refractive layer is formed of a photocurable coating composition containing two or more types of photo-polymerizable compounds, a photoinitiator, surface-treated hollow inorganic nanoparticles, and surface-treated solid inorganic nanoparticles.
Pelletized Thermoplastic Pavement Marking Compositions Using Glass Dust Filler
A pelletized thermoplastic road marking material is provided in which glass dust rather than calcium carbonate is used as the filler. Such glass dust can account for up to 55 weight % of the final formulation. Glass dust is a readily available and inexpensive byproduct of glass manufacturing which otherwise has little or no commercial value. Use of the glass dust is effective if the thermoplastic composition is prepared in pelletized form and performs comparably to a thermoplastic composition having calcium carbonate filler, while producing a higher yield.
UV-STABLE AND SUPERHYDROPHOBIC WOOD SURFACE
The invention relates to a method for treatment of wood material. In a first treatment step comprises the provision of a solution comprising zinc oxide or titanium(IV) isopropoxide and immersion of the wood material into the solution. After drying of the wood material a second treatment step is following in case of the first solution comprising zinc oxide. The second treatment step comprises the provision of a solution comprising a zinc compound and immersion of the wood material from the first treatment step into the solution followed by drying of the wood material. In a second aspect the invention relates to a wood material characterized by the visibility of the natural appearance of the surface and at least one other property relating to UV resistance, weathering resistance, mechanical resistance or hydrophobic properties.
METHOD OF FORMING SILVER NANOPARTICLES USING CELLULOSIC POLYMERS
Articles can be prepared having silver layers or patterns using a non-aqueous silver precursor composition consisting essentially of: at least 1 weight % of one or more (a) cellulosic polymers, (b) at least 0.1 weight % of reducible silver ions, and (c) an organic solvent medium consisting of: (i) one or more hydroxylic organic solvents, and, optionally, (ii) a nitrile-containing or carbonate-containing aprotic solvent. This composition is subjected to a temperature of at least 20 C. for a time sufficient to convert at least 90 mol % of the (b) reducible silver ions to (d) silver nanoparticles having a mean particle size of at least 25 nm and up to and including 750 nm. Additional (ii) nitrile-containing or carbonate-containing aprotic solvent can be added, and (e) carbon black can be added sufficient to provide at least 5 weight % carbon black. The resulting silver nanoparticle-containing composition can be disposed onto a supporting surface of a substrate to form a silver nanoparticle-containing pattern, and any organic solvents can be removed. This pattern can also be electrolessly plated to form an electrically-conductive pattern.
SILVER-CONTAINING COMPOSITIONS CONTAINING CELLULOSIC POLYMERS
A non-aqueous silver precursor composition contains at least 1 weight % of one or more (a) polymers that are certain cellulosic polymers; (b) reducible silver ions; and(c) an organic solvent medium consisting of: (i) a hydroxylic organic solvent having an -hydrogen atom and a boiling point at atmospheric pressure of 100-500 C., and, optionally, (ii) a nitrile-containing aprotic solvent or a carbonate-containing aprotic solvent different from the (i) organic solvent, each having a boiling point at atmospheric pressure of 100-500 C. The (b) reducible silver ions are present in an amount of 0.1-400 weight %, based on the total weight of the one or more (a) polymers. This composition can be used to form silver nanoparticles under silver ion reducing conditions and then applied to various substrates to provide silver nanoparticle patterns.
SILVER-CONTAINING PRECURSOR AND PRODUCT ARTICLES CONTAINING CELLULOSIC POLYMERS
An article has a substrate and a pattern of a dry silver nanoparticle-containing composition comprising at least 20 weight % of one or more (a) polymers, that are cellulosic polymers; (d) silver nanoparticles having a mean particle size of 25-750 nm and present in an amount of 0.1-400 weight %, based on the total weight of the one or more (a) polymers; and (e) carbon black in an amount of 5-50 weight %, based on the total weight of the one or more (a) polymers. Such patterns can have multiple fine lines of any geometric arrangement. The article can have multiple patterns of this type, and each pattern can be electrolessly plated with a suitable metal such as copper to provide electrically-conductive product articles.
Metallic copper dispersion, process for producing the metallic copper dispersion, electrode, wiring pattern, and coating film formed using the metallic copper dispersion, decorative article and antimicrobial article with the coating film formed thereon, and processes for producing the decorative article and the antimicrobial article
A dispersion comprising at least metallic copper particles with gelatin provided on the surface thereof, a polymeric dispersant, and an organic solvent. The dispersion is produced by reducing copper oxide in an aqueous solvent in the presence of gelatin having an amine number and an acid number wherein the difference (amine numberacid number) is 0 or less, then subjecting the reaction solution to solid-liquid separation, and then mixing the resultant metallic copper particles with gelatin provided on the surface thereof and a polymeric dispersant having an amine number and an acid number wherein the difference (amine numberacid number) is 0 to 50, into an organic solvent. The dispersion maintains dispersion stability of the metallic copper particles for a long time, is suitable for inkjet printing and spray coating and can be used to make microelectrodes and circuit wiring patterns.