An oxidized zinc pigment has been developed that can be used in a waterborne coating. The zinc metal allows for improved stability in waterborne systems while retaining the level of activity required for an anticorrosive material. This pigment is oxidized enough to prevent corrosion and still be dispersed in the waterborne coating, while still allowing for cathodic and anodic corrosion protection in the coating once applied to a metal surface. This zinc pigment may also be used in a waterborne ink or coating system and also for coated metal articles.

An oxidized zinc pigment has been developed that can be used in a waterborne coating. The zinc metal allows for improved stability in waterborne systems while retaining the level of activity required for an anticorrosive material. This pigment is oxidized enough to prevent corrosion and still be dispersed in the waterborne coating, while still allowing for cathodic and anodic corrosion protection in the coating once applied to a metal surface. This zinc pigment may also be used in a waterborne ink or coating system and also for coated metal articles.

One aspect of this invention relates to hexagonal boron nitride (hBN) ionogel inks using exfoliated hBN nanoplatelets as the solid matrix. The hBN nanoplatelets are produced from bulk hBN powders by liquid-phase exfoliation, allowing printable hBN ionogel inks to be formulated following the addition of an imidazolium ionic liquid and ethyl lactate. The resulting inks are reliably printed with variable patterns and controllable thicknesses by aerosol jet printing, resulting in hBN ionogels that possess high room-temperature ionic conductivities and storage moduli of >3 mS cm-1 and >1 MPa, respectively. By integrating the hBN ionogel with printed semiconductors and electrical contacts, fully-printed thin-film transistors with operating voltages below 1 V are demonstrated on polyimide films. These devices exhibit desirable electrical performance and robust mechanical tolerance against repeated bending cycles, thus confirming the suitability of hBN ionogels for printed and flexible electronics.

One aspect of this invention relates to hexagonal boron nitride (hBN) ionogel inks using exfoliated hBN nanoplatelets as the solid matrix. The hBN nanoplatelets are produced from bulk hBN powders by liquid-phase exfoliation, allowing printable hBN ionogel inks to be formulated following the addition of an imidazolium ionic liquid and ethyl lactate. The resulting inks are reliably printed with variable patterns and controllable thicknesses by aerosol jet printing, resulting in hBN ionogels that possess high room-temperature ionic conductivities and storage moduli of >3 mS cm-1 and >1 MPa, respectively. By integrating the hBN ionogel with printed semiconductors and electrical contacts, fully-printed thin-film transistors with operating voltages below 1 V are demonstrated on polyimide films. These devices exhibit desirable electrical performance and robust mechanical tolerance against repeated bending cycles, thus confirming the suitability of hBN ionogels for printed and flexible electronics.

The present disclosure describes ink compositions having a polyurethane binder that can be used for textile printing. In one example, an ink composition can include water, an organic co-solvent, a colorant, and a polyurethane binder. The polyurethane binder can include pre-polymer segments that include polymerized monomers of a diisocyanate, a graft diol, a polymeric diol, and an acid-containing diol. The graft diol can include thioglycerol having a polymer sidechain replacing a hydrogen atom on a sulfur atom of the thioglycerol. The polymer sidechain can include a polymerized monomer of an acrylate ester, a methacrylate ester, a styrene, or a combination thereof. The polyurethane binder can also include chain extenders connecting the pre-polymer segments. The chain extenders can include a polymerized sulfonate-containing diamine.

The present disclosure describes ink compositions having a polyurethane binder that can be used for textile printing. In one example, an ink composition can include water, an organic co-solvent, a colorant, and a polyurethane binder. The polyurethane binder can include pre-polymer segments that include polymerized monomers of a diisocyanate, a graft diol, a polymeric diol, and an acid-containing diol. The graft diol can include thioglycerol having a polymer sidechain replacing a hydrogen atom on a sulfur atom of the thioglycerol. The polymer sidechain can include a polymerized monomer of an acrylate ester, a methacrylate ester, a styrene, or a combination thereof. The polyurethane binder can also include chain extenders connecting the pre-polymer segments. The chain extenders can include a polymerized sulfonate-containing diamine.

Provided is an image recording method including a step of preparing an ink containing water and a white pigment, and a step of jetting the ink from an ink jet head in a liquid droplet amount of 1.0 pL or greater to apply the ink onto a base material, in which in a case where an ink jetting surface of the ink jet head is immersed in the ink in a vertically standing state for 2 seconds, the jetting surface is pulled up from the ink in the state, and the jetting surface is allowed to stand in the state for 1 minute, a ratio of an area of a region to which the ink is adhered to an area of the jetting surface is 40% by area or less.

Provided is an image recording method including a step of preparing an ink containing water and a white pigment, and a step of jetting the ink from an ink jet head in a liquid droplet amount of 1.0 pL or greater to apply the ink onto a base material, in which in a case where an ink jetting surface of the ink jet head is immersed in the ink in a vertically standing state for 2 seconds, the jetting surface is pulled up from the ink in the state, and the jetting surface is allowed to stand in the state for 1 minute, a ratio of an area of a region to which the ink is adhered to an area of the jetting surface is 40% by area or less.

A liquid ejecting apparatus, a liquid ejecting method and an ink are provided, so as to appropriately increase the strength of ink after fixing. The liquid ejecting apparatus is configured to eject an ink by an inkjet method, and includes an inkjet head configured to eject the ink. The inkjet head has a nozzle configured to eject the ink. The ink includes a resin particle having a size capable of passing through the nozzle. The resin particle contains a fibrous substance. The fibrous substance is, for example, fibers of cellulose.

A liquid ejecting apparatus, a liquid ejecting method and an ink are provided, so as to appropriately increase the strength of ink after fixing. The liquid ejecting apparatus is configured to eject an ink by an inkjet method, and includes an inkjet head configured to eject the ink. The inkjet head has a nozzle configured to eject the ink. The ink includes a resin particle having a size capable of passing through the nozzle. The resin particle contains a fibrous substance. The fibrous substance is, for example, fibers of cellulose.