After there is prepared a conductive paste which contains fine copper particles having an average particle diameter of 1 to 100 nm, each of the fine copper particles being coated with an azole compound, such as benzotriazole, coarse copper particles having an average particle diameter of 0.3 to 20 μm, at least one of a polyvinylpyrrolidone (PVP) resin and a polyvinyl butyral (PVB) resin, a chlorine compound, and a glycol solvent, such as ethylene glycol, the total amount of the fine copper particles and the coarse copper particles being 50 to 90% by weight, and the weight ratio of the fine copper particles to the coarse copper particles being in the range of from 1:9 to 5:5, the conductive paste thus prepared is applied on a substrate by screen printing to be preliminary-fired by vacuum drying, and then, fired with light irradiation by irradiating with light having a wavelength of 200 to 800 nm at a pulse period of 500 to 2000 μs and a pulse voltage of 1600 to 3800 V to form a conductive film on the substrate.

After there is prepared a conductive paste which contains fine copper particles having an average particle diameter of 1 to 100 nm, each of the fine copper particles being coated with an azole compound, such as benzotriazole, coarse copper particles having an average particle diameter of 0.3 to 20 μm, at least one of a polyvinylpyrrolidone (PVP) resin and a polyvinyl butyral (PVB) resin, a chlorine compound, and a glycol solvent, such as ethylene glycol, the total amount of the fine copper particles and the coarse copper particles being 50 to 90% by weight, and the weight ratio of the fine copper particles to the coarse copper particles being in the range of from 1:9 to 5:5, the conductive paste thus prepared is applied on a substrate by screen printing to be preliminary-fired by vacuum drying, and then, fired with light irradiation by irradiating with light having a wavelength of 200 to 800 nm at a pulse period of 500 to 2000 μs and a pulse voltage of 1600 to 3800 V to form a conductive film on the substrate.

The present invention relates to a coating of the surface of an electrical household appliance comprising a decoration (a) comprising a pigmentary compound B1VO4 having a ΔE* in the coating greater than or equal to 11 between ambient temperature and 150° C., ΔE* being defined by the formula CIE1976 in the CIELAB colour space: Formula (I): L1*, a1* and b1* characterising the values L*a*b* of said compound at ambient temperature; L2*, a2* and b2* characterising the values L*a*b* of said compound at 150° C.

The present invention relates to a coating of the surface of an electrical household appliance comprising a decoration (a) comprising a pigmentary compound B1VO4 having a ΔE* in the coating greater than or equal to 11 between ambient temperature and 150° C., ΔE* being defined by the formula CIE1976 in the CIELAB colour space: Formula (I): L1*, a1* and b1* characterising the values L*a*b* of said compound at ambient temperature; L2*, a2* and b2* characterising the values L*a*b* of said compound at 150° C.

Provided are a conductive composition for thin film printing and a method for forming a thin film conductive pattern, which can easily performing thin film printing, and can capable of improve conductivity by thermal sintering at a comparatively low temperature of 300° C. or less or by photo irradiation. A conductive composition comprises metal particles, a binder resin, and a solvent, the content of an organic compound in the solvent being 5 to 98% by mass, the organic compound comprising a hydrocarbon group having a bridged cyclic structure and a hydroxyl group, the content of metal particles being 15 to 60% by mass, the metal particles containing 20% by mass or more of flat metal particles, the content of the binder resin being 0.5 to 10 parts by mass relative to 100 parts by mass of the metal particles, and the viscosity at 25° C. being 1.0×10.sup.3 to 2×10.sup.5 mPa.Math.s. The composition is printed in a pattern having any selected shape on a substrate, by screen printing, and the pattern is subjected to thermal sintering at a temperature of 300° C. or less and/or subjecting the pattern to pulsed light irradiation.

An alcohol-based composition may contain an acryl-modified polyolefin resin and exhibit a good adhesion even at a high solid content, suppress an increase in viscosity, and have good stability such as dispersibility and sustainable stability. A dispersion composition may contain at least a modified polyolefin resin dispersed in a dispersing medium containing an alcohol solvent and an aliphatic hydrocarbon solvent. The modified polyolefin resin may be modified with a (meth)acrylic acid component containing at least a (meth)acrylic ester of formula (I) and a (meth)acrylic ester of formula (II). The total content of the structure derived from the (meth)acrylic acid component in the dispersion composition is 3% to 94% by weight, relative to 100% by weight as a total amount of the modified polyolefin resin and (meth)acrylic acid component polymer, and a solid fraction in the dispersion composition is 30% to 80% by weight.

An alcohol-based composition may contain an acryl-modified polyolefin resin and exhibit a good adhesion even at a high solid content, suppress an increase in viscosity, and have good stability such as dispersibility and sustainable stability. A dispersion composition may contain at least a modified polyolefin resin dispersed in a dispersing medium containing an alcohol solvent and an aliphatic hydrocarbon solvent. The modified polyolefin resin may be modified with a (meth)acrylic acid component containing at least a (meth)acrylic ester of formula (I) and a (meth)acrylic ester of formula (II). The total content of the structure derived from the (meth)acrylic acid component in the dispersion composition is 3% to 94% by weight, relative to 100% by weight as a total amount of the modified polyolefin resin and (meth)acrylic acid component polymer, and a solid fraction in the dispersion composition is 30% to 80% by weight.

A water-based ink includes: a dye; water; an acidic preservative; and at least one of a surfactant and a penetrant. The acidic preservative preferably includes at least one selected from the group consisting of a polyvalent unsaturated fatty acid, a polyvalent unsaturated fatty acid salt, dehydroacetic acid, and a dehydroacetate. A content of the acidic preservative in the water-based ink is preferably 0.3% by mass to 6.0% by mass relative to a total mass of the water-based ink. The surfactant preferably includes an acetylene-based surfactant. The penetrant preferably includes at least one selected from the group consisting of an alkylene diol and a glycol ether compound.

A water-based ink includes: a dye; water; an acidic preservative; and at least one of a surfactant and a penetrant. The acidic preservative preferably includes at least one selected from the group consisting of a polyvalent unsaturated fatty acid, a polyvalent unsaturated fatty acid salt, dehydroacetic acid, and a dehydroacetate. A content of the acidic preservative in the water-based ink is preferably 0.3% by mass to 6.0% by mass relative to a total mass of the water-based ink. The surfactant preferably includes an acetylene-based surfactant. The penetrant preferably includes at least one selected from the group consisting of an alkylene diol and a glycol ether compound.

A device including an electrically conducting track arranged on a support includes a step of supply of the support, and a step of formation of the electrically conducting track on the support including a step of supply of a solution intended to be deposited on the support, a step of deposition of the solution by printing on the support. The step of supply of the solution is such that the solution supplied includes a mixture of a solvent, of a set of metal particles and of a metallic material having a melting point below that of the metal particles of the set of metal particles, and the method includes a step of melting of the metallic material which results in the formation of a solder of metallic material between metal particles of the set of metal particles.