Provided are processes of applying a decorative imaging to a substrate that includes providing a stamp pad comprising a child and environmentally friendly disperse dye composition, inking a stamp with the disperse dye composition, optionally transferring the disperse dye composition from the stamp to an intermediate ink receptive surface using the rubber stamp to thereby place an image on an intermediate ink receptive surface, and transferring the image to a dye receptive object by application of sufficient heat and pressure. The disperse dye compositions provided herein are safe, environmentally friendly, and able to be used in stamp pad imaging processes.

A coalescing agent for three-dimensional (3D) printing includes a co-solvent, a surfactant having a hydrophilic lipophilic balance (HLB) value that is less than 10, a carbon black pigment, a polymeric dispersant, and a balance of water. The co-solvent is present in an amount ranging from about 15 wt % to about 30 wt % of a total wt % of the coalescing agent. The surfactant is present in an amount ranging from about 0.5 wt % to about 1.4 wt % of the total wt % of the coalescing agent. The carbon black pigment is present in an amount ranging from about 3.0 wt % to about 6.0 wt % of the total wt % of the coalescing agent. The polymeric dispersant has a weight average molecular weight ranging from about 12,000 to about 20,000.

A coalescing agent for three-dimensional (3D) printing includes a co-solvent, a surfactant having a hydrophilic lipophilic balance (HLB) value that is less than 10, a carbon black pigment, a polymeric dispersant, and a balance of water. The co-solvent is present in an amount ranging from about 15 wt % to about 30 wt % of a total wt % of the coalescing agent. The surfactant is present in an amount ranging from about 0.5 wt % to about 1.4 wt % of the total wt % of the coalescing agent. The carbon black pigment is present in an amount ranging from about 3.0 wt % to about 6.0 wt % of the total wt % of the coalescing agent. The polymeric dispersant has a weight average molecular weight ranging from about 12,000 to about 20,000.

The present disclosure relates to the use of occluding fluids, such as a high-density fluid (a “z-fluid”) or a low-density fluid (an “a-fluid”), to displace resin within a vat during 3D printing. Further, an a-fluid may act as a protective boundary for a 3D printing resin wherein the a-fluid sits on top of the printing resin. Another embodiment of the disclosure provides a process of assessing which regions of a computer-aided design (CAD) model take advantage of a buoying force supplied by the occluding fluid, such that fewer support structures are needed for printing a final CAD model compared to printing the CAD model without the occluding fluid.

The present disclosure relates to the use of occluding fluids, such as a high-density fluid (a “z-fluid”) or a low-density fluid (an “a-fluid”), to displace resin within a vat during 3D printing. Further, an a-fluid may act as a protective boundary for a 3D printing resin wherein the a-fluid sits on top of the printing resin. Another embodiment of the disclosure provides a process of assessing which regions of a computer-aided design (CAD) model take advantage of a buoying force supplied by the occluding fluid, such that fewer support structures are needed for printing a final CAD model compared to printing the CAD model without the occluding fluid.

A low temperature sinterable copper nanoparticle or nanowire, comprising gold, zinc, nickel, tin, or aluminum as an alloying metal, and a capping agent. The nanoparticles or nanowires may be deposited on porous or fibrous substrates, the capping agent desorbed, and sintered at low temperature to form conductive traces or sensing elements. The nanoparticles or nanowires may be deposited by aerosol jet, inkjet or dispenser printers, for example.

A low temperature sinterable copper nanoparticle or nanowire, comprising gold, zinc, nickel, tin, or aluminum as an alloying metal, and a capping agent. The nanoparticles or nanowires may be deposited on porous or fibrous substrates, the capping agent desorbed, and sintered at low temperature to form conductive traces or sensing elements. The nanoparticles or nanowires may be deposited by aerosol jet, inkjet or dispenser printers, for example.

An ink is provided which can prevent the deformation and degradation of resin products by printed items, and is also suitable for inkjet printing. The oil-based inkjet ink contains a colorant and a fatty acid ester-based solvent represented by general formula (1) shown below and having 12 to 23 carbon atoms in one molecule. ##STR00001##
(In general formula (1), each of R.sup.1 and R.sup.2 independently represents an alkyl group, and at least one of the alkyl groups of R.sup.1 and R.sup.2 is a branched alkyl group having a side chain of at least 4 carbon atoms.).

An ink is provided which can prevent the deformation and degradation of resin products by printed items, and is also suitable for inkjet printing. The oil-based inkjet ink contains a colorant and a fatty acid ester-based solvent represented by general formula (1) shown below and having 12 to 23 carbon atoms in one molecule. ##STR00001##
(In general formula (1), each of R.sup.1 and R.sup.2 independently represents an alkyl group, and at least one of the alkyl groups of R.sup.1 and R.sup.2 is a branched alkyl group having a side chain of at least 4 carbon atoms.).

An ink including a pigment, water, and a resin is provided. An image formed with the ink on a print medium has a tack force of 6 gf or greater but 13 gf or less when measured at a probe temperature of 100 degrees C., where the image is a solid image formed at a resolution of 1,200 dpi, subsequently irradiated with light of 395 nm for 0.6 seconds, and left to stand at normal temperatures and normal humidities for 30 seconds.