Described herein are heat resistant inks and coating compositions that, when coated on a substrate, impart the feel of paper. The inks and coating compositions do not degrade when exposed to temperatures of 120° C. or greater.

The present disclosure is drawn to three-dimensional printing kits, methods of making magnetic three-dimensional printed articles, and systems for three-dimensional printing. In one example, a three-dimensional printing kit can include a powder bed material, a fusing agent, and a magnetic agent. The powder bed material can include polymer particles. The fusing agent can include water and a non-magnetic radiation absorber. The non-magnetic radiation absorber can absorb radiation energy and convert the radiation energy to heat. The magnetic agent can include a dispersion of magnetic nanoparticles.

The present disclosure is drawn to a base paper substrate that is cellulose-based and an ink-receiving layer on the base paper substrate. The ink-receiving layer, for example, includes a metal salt, inorganic particulates, a polymeric binder, and an emulsifier including a hydroxylated saturated hydrocarbon block including from 6 to 24 carbon atoms and a hydroxyl group and further includes a polyalkylene oxide block including form 10 to 35 polyalkylene oxide units selected from polyethylene oxide, polypropylene oxide, or a combination thereof.

The present disclosure is drawn to a base paper substrate that is cellulose-based and an ink-receiving layer on the base paper substrate. The ink-receiving layer, for example, includes a metal salt, inorganic particulates, a polymeric binder, and an emulsifier including a hydroxylated saturated hydrocarbon block including from 6 to 24 carbon atoms and a hydroxyl group and further includes a polyalkylene oxide block including form 10 to 35 polyalkylene oxide units selected from polyethylene oxide, polypropylene oxide, or a combination thereof.

A 3D printing kit can include a powder bed material comprising from about 80 wt % to 100 wt % polymer particles, a fusing agent to selectively apply to the powder bed material, and a hardener to selectively apply to the powder bed material. The polymeric particles can include a polyalkylene backbone with both ethylene and propylene polymerized monomeric units with from 2 mol % to 15 mol % of the polymerized monomeric units include a grafted side chain having an epoxide moiety. The fusing agent can include water and a radiation absorber that absorbs electromagnetic energy and converts the electromagnetic energy to heat. The hardener can be present in the fusing agent or can be included in a hardening agent that is separate from the fusing agent.

A 3D printing kit can include a powder bed material comprising from about 80 wt % to 100 wt % polymer particles, a fusing agent to selectively apply to the powder bed material, and a hardener to selectively apply to the powder bed material. The polymeric particles can include a polyalkylene backbone with both ethylene and propylene polymerized monomeric units with from 2 mol % to 15 mol % of the polymerized monomeric units include a grafted side chain having an epoxide moiety. The fusing agent can include water and a radiation absorber that absorbs electromagnetic energy and converts the electromagnetic energy to heat. The hardener can be present in the fusing agent or can be included in a hardening agent that is separate from the fusing agent.

The present disclosure describes methods of printing, textile printing systems, and printers. In one example, a method of printing can include jetting an ink composition onto a substrate, the ink composition including an evaporable solvent, a colorant, and a non-curable polymeric binder. The ink composition on the substrate can be exposed to electromagnetic radiation having a wavelength from 350 nm to 420 nm. The exposure of the ink composition can begin from 0 ms to 600 ms after jetting the ink composition. The electromagnetic radiation can heat the ink composition to evaporate a portion of the evaporable solvent from the ink composition within 5 ms to 500 ms after the beginning of the exposure.

The present disclosure describes methods of printing, textile printing systems, and printers. In one example, a method of printing can include jetting an ink composition onto a substrate, the ink composition including an evaporable solvent, a colorant, and a non-curable polymeric binder. The ink composition on the substrate can be exposed to electromagnetic radiation having a wavelength from 350 nm to 420 nm. The exposure of the ink composition can begin from 0 ms to 600 ms after jetting the ink composition. The electromagnetic radiation can heat the ink composition to evaporate a portion of the evaporable solvent from the ink composition within 5 ms to 500 ms after the beginning of the exposure.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.