Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) in combination with toughening agents for fabricating the object. Systems suitable for performing these methods and kits containing modeling material formulations usable in the methods are also provided.

Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) in combination with toughening agents for fabricating the object. Systems suitable for performing these methods and kits containing modeling material formulations usable in the methods are also provided.

Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes, adhesives, for the making of gel coats, composites, molding compositions or 3D articles. Materials of the invention are in particular suitable as surface cure boosterin UV and UV LED applications.

Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes, adhesives, for the making of gel coats, composites, molding compositions or 3D articles. Materials of the invention are in particular suitable as surface cure boosterin UV and UV LED applications.

There are provided an image transfer sheet for leaving no air bubbles between an image layer and a transfer target object, a method for manufacturing the image transfer sheet and a method for transferring an image. An image transfer method, comprising the steps of: forming a glue layer by pressure-gluing a glued sheet, defined by a substrate and a glue layer provided on a lower surface of the substrate, onto an upper surface of a release paper, having many fine recesses, and subsequently peeling and removing the substrate and exposing the glue layer; printing ink on the exposed upper surface of the glue layer by a non-contact printer to thereby provide an image layer on part of the glue layer; affixing a transfer film on the glue layer provided with the image layer, wherein the transfer film is releasable from the image layer and easily adhesive to the glue layer, and causing the transfer film to contact with a lower surface of the transfer film onto the image layer where there is the image layer, and with the glue layer where there is no image layer; peeling and removing only the release paper from the image transfer sheet; pressure-gluing the lower surface of the glue layer of the image transfer sheet, with the release paper removed, onto a transfer target object; and peeling and removing the transfer film from the image transfer sheet pressure-glued to the transfer target object.

There are provided an image transfer sheet for leaving no air bubbles between an image layer and a transfer target object, a method for manufacturing the image transfer sheet and a method for transferring an image. An image transfer method, comprising the steps of: forming a glue layer by pressure-gluing a glued sheet, defined by a substrate and a glue layer provided on a lower surface of the substrate, onto an upper surface of a release paper, having many fine recesses, and subsequently peeling and removing the substrate and exposing the glue layer; printing ink on the exposed upper surface of the glue layer by a non-contact printer to thereby provide an image layer on part of the glue layer; affixing a transfer film on the glue layer provided with the image layer, wherein the transfer film is releasable from the image layer and easily adhesive to the glue layer, and causing the transfer film to contact with a lower surface of the transfer film onto the image layer where there is the image layer, and with the glue layer where there is no image layer; peeling and removing only the release paper from the image transfer sheet; pressure-gluing the lower surface of the glue layer of the image transfer sheet, with the release paper removed, onto a transfer target object; and peeling and removing the transfer film from the image transfer sheet pressure-glued to the transfer target object.

Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) in combination with toughening agents for fabricating the object. Systems suitable for performing these methods and kits containing modeling material formulations usable in the methods are also provided.

Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) in combination with toughening agents for fabricating the object. Systems suitable for performing these methods and kits containing modeling material formulations usable in the methods are also provided.

The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A): (A) whereby R.sub.1 is H; R.sub.2 and R.sub.4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R.sub.3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R.sub.2 and R.sub.3 (in case R.sub.2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R′ and R″ are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight from 600 to 20000 Daltons, wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.

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The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): whereby R′, R″ are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 840 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.

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