The present disclosure provides a photo-curable elastic ink composition for three-dimensional printing and the preparation method. The ink composition includes approximately 10%-75% of a soft monomer, approximately 10%-75% of a hard monomer, approximately 5%-20% of a cross-linking agent, approximately 5%-20% of a non-reactive soft resin, approximately 0.5%-10% of a photo-initiator, approximately 0%-0.5% of a colorant, and approximately 0.05%-8% of an auxiliary agent. The soft monomer is capable of generating a homopolymer with a glass transition temperature lower than about 25° C. The hard monomer is capable of generating a homopolymer with a glass transition temperature of about 25° C. or higher. The non-reactive soft resin is a resin without containing any radiation curable group in the molecular structure and having a glass transition temperature less than 0° C.

A method for producing a recorded matter includes a first ejection step of ejecting a first ink, which is a radiation-curable ink jet composition, and adhering the first ink to a recording medium, a first irradiation step of irradiating radiation to the first ink adhered to the recording medium to obtain a cured coating film of the first ink, a second ejection step of ejecting a second ink, which is a radiation-curable ink jet composition, and adhering the second ink with a plurality of dot sizes to the cured coating film of the first ink so that the duty is less than 100%, a second irradiation step of irradiating radiation to the second ink adhered to the recording medium to cure the second ink, obtaining a recorded matter, and a lamination step of laminating, in the recorded matter, a recording surface to which the first ink and the second ink have been adhered, and a non-recording surface to which the first ink and the second ink have not been adhered, so that both surfaces face each other.

A method for producing a recorded matter includes a first ejection step of ejecting a first ink, which is a radiation-curable ink jet composition, and adhering the first ink to a recording medium, a first irradiation step of irradiating radiation to the first ink adhered to the recording medium to obtain a cured coating film of the first ink, a second ejection step of ejecting a second ink, which is a radiation-curable ink jet composition, and adhering the second ink with a plurality of dot sizes to the cured coating film of the first ink so that the duty is less than 100%, a second irradiation step of irradiating radiation to the second ink adhered to the recording medium to cure the second ink, obtaining a recorded matter, and a lamination step of laminating, in the recorded matter, a recording surface to which the first ink and the second ink have been adhered, and a non-recording surface to which the first ink and the second ink have not been adhered, so that both surfaces face each other.

Provided is an ultraviolet curable silicone composition capable of being ejected via inkjet ejection. The composition of the invention is an ultraviolet curable silicone composition comprising: (A) an organopolysiloxane represented by the following general formula (1) ##STR00001##
wherein each R.sup.1 independently represents a group selected from a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms, an acryloyl group, a methacryloyl group, an alkyl acrylate group and an alkyl methacrylate group, while the component (A) has per molecule at least two groups selected from an acryloyl group, a methacryloyl group, an alkyl acrylate group and an alkyl methacrylate group; n represents a number satisfying 10≤n≤1,000; (B) a monofunctional (meth)acrylate compound having no siloxane structure; and/or (C) a multifunctional (meth)acrylate compound having no siloxane structure; and (D) a photopolymerization initiator.

Provided is an ultraviolet curable silicone composition capable of being ejected via inkjet ejection. The composition of the invention is an ultraviolet curable silicone composition comprising: (A) an organopolysiloxane represented by the following general formula (1) ##STR00001##
wherein each R.sup.1 independently represents a group selected from a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms, an acryloyl group, a methacryloyl group, an alkyl acrylate group and an alkyl methacrylate group, while the component (A) has per molecule at least two groups selected from an acryloyl group, a methacryloyl group, an alkyl acrylate group and an alkyl methacrylate group; n represents a number satisfying 10≤n≤1,000; (B) a monofunctional (meth)acrylate compound having no siloxane structure; and/or (C) a multifunctional (meth)acrylate compound having no siloxane structure; and (D) a photopolymerization initiator.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.

In one aspect, inks for use with a three-dimensional printing system are described herein. In some embodiments, an ink described herein comprises a thiol monomer component and an ene monomer component. Moreover, in some cases, an ink described herein further comprises an additional (meth)acrylate monomer component differing from the ene monomer component. In some such cases, the additional (meth)acrylate monomer component can be polymerized separately from the thiol and ene monomers of the ink.

In one aspect, inks for use with a three-dimensional printing system are described herein. In some embodiments, an ink described herein comprises a thiol monomer component and an ene monomer component. Moreover, in some cases, an ink described herein further comprises an additional (meth)acrylate monomer component differing from the ene monomer component. In some such cases, the additional (meth)acrylate monomer component can be polymerized separately from the thiol and ene monomers of the ink.

Provided is a curable resin composition including (A) a (meth)acrylic compound having a number-average molecular weight of 5,000 or less and represented by the formula (1) (R.sub.1 is a hydrogen atom, etc., L.sub.1 and L.sub.2 each represent an alkylene group, etc., L.sub.3 represents a divalent linking group having an ether structure, etc. and Q.sub.1 to Q.sub.3 each represent a divalent linking group —O—, etc.), (B) a (meth)acrylic organosiloxane compound having a number-average molecular weight of 1,000 or less and represented by the following formula (2) (R.sub.3 represents a hydrogen atom, etc., R.sub.4 represents an alkyl group, etc., L.sub.4 represents a single bond, etc., Q.sub.4 represents a single bond, etc., and m stands for an average number of repeating constituting units) and (C) a curing agent. A (meth)acrylic compound (A):(meth)acrylic organosiloxane compound (B) mass ratio is 40:60 to 85:15. ##STR00001##