Decorative films including on a substrate film sequentially a flexible resin layer and an independent dot-patterned hardcoat layer, and has an elongation percentage of 10% or greater is described. These decorative films may have scratch resistance and elongation properties.

Provided is a white laminated polyester film that has blocking resistance when water adheres and has excellent adhesion to UV ink. A white laminated polyester film comprising a polyester resin layer and a coating layer on at least one surface of the polyester film substrate, the coating layer being formed by curing a composition containing a urethane resin with a polycarbonate structure and a branched structure, a crosslinking agent, and a polyester resin. The crosslinking agent is preferably a compound containing three or more blocked isocyanate groups.

Provided herein are methods for the preparation of perfusable scaffolds for cell culture. These methods can comprise providing a bioink composition and a fugitive ink composition; chaotic printing the bioink composition and the fugitive ink composition to generate a microstructured precursor comprising a plurality of lamellar structures formed from the bioink composition; curing the bioink composition to form a cured scaffold precursor; and removing the fugitive ink from the cured scaffold precursor, thereby forming the perfusable scaffold. Also provided are scaffolds prepared by these methods as well as modular bioreactors incorporating these scaffolds.

Provided is an ink for inkjet printing having high environmental safety, well satisfying characteristics required for a printing ink for a commercial inkjet printer such as high image quality performance, high coating performance, high-speed printability, and substrate versatility in a well-balanced manner, and having good pigment dispersion stability. The ultraviolet-curable water-based inkjet-printing ink contains at least an ultraviolet curable oligomer and a colorant. The ultraviolet-curable oligomer includes a structural unit derived from a polyisocyanate compound (A), a structural unit derived from a compound (B′) shown below, and a structural unit derived from a compound (C′) shown below. Compound (B′): a compound having two or more polymerizable unsaturated bonds and capable of bonding with the polyisocyanate compound (A) Compound (C′): a water-soluble compound capable of bonding with the polyisocyanate compound (A).

Provided is an ink for inkjet printing having high environmental safety, well satisfying characteristics required for a printing ink for a commercial inkjet printer such as high image quality performance, high coating performance, high-speed printability, and substrate versatility in a well-balanced manner, and having good pigment dispersion stability. The ultraviolet-curable water-based inkjet-printing ink contains at least an ultraviolet curable oligomer and a colorant. The ultraviolet-curable oligomer includes a structural unit derived from a polyisocyanate compound (A), a structural unit derived from a compound (B′) shown below, and a structural unit derived from a compound (C′) shown below. Compound (B′): a compound having two or more polymerizable unsaturated bonds and capable of bonding with the polyisocyanate compound (A) Compound (C′): a water-soluble compound capable of bonding with the polyisocyanate compound (A).

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

A UV-curable composition for coating or printing on a substrate and/or a substrate surface includes at least one monofunctional acrylate monomer/methacrylate monomer having a substituted or unsubstituted monocycloaliphatic hydrocarbon radical, at least one vinyl monomer having a substituted or unsubstituted heterocyclic radical, where the heterocyclic radical has at least one ring-forming nitrogen atom, at least one monofunctional acrylate monomer/methacrylate monomer having a substituted or unsubstituted bicyclic, nonaromatic hydrocarbon radical and at least one photoinitiator, wherein the UV-curable composition is free of at least one monofunctional acrylate monomer/methacrylate monomer having a substituted or unsubstituted heterocyclic, nonaromatic radical.

A UV-curable composition for coating or printing on a substrate and/or a substrate surface includes at least one monofunctional acrylate monomer/methacrylate monomer having a substituted or unsubstituted monocycloaliphatic hydrocarbon radical, at least one vinyl monomer having a substituted or unsubstituted heterocyclic radical, where the heterocyclic radical has at least one ring-forming nitrogen atom, at least one monofunctional acrylate monomer/methacrylate monomer having a substituted or unsubstituted bicyclic, nonaromatic hydrocarbon radical and at least one photoinitiator, wherein the UV-curable composition is free of at least one monofunctional acrylate monomer/methacrylate monomer having a substituted or unsubstituted heterocyclic, nonaromatic radical.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.