An adhesive sign suited to use in retail applications includes a substrate layer. An adhesive layer is disposed on the substrate layer. The adhesive layer defines an exposed region for attachment to an associated structure. The adhesive layer is derived from a photo-curable inkjet composition. An ink layer is disposed on the substrate layer. The ink layer includes an image. The ink layer is derived from a photo-curable inkjet composition. The adhesive layer and ink layer can be formed in the same inkjet printing process and cured in a common photo-curing station. A stack of the adhesive signs can be assembled without interleaving a release liner between each pair of signs.

An adhesive sign suited to use in retail applications includes a substrate layer. An adhesive layer is disposed on the substrate layer. The adhesive layer defines an exposed region for attachment to an associated structure. The adhesive layer is derived from a photo-curable inkjet composition. An ink layer is disposed on the substrate layer. The ink layer includes an image. The ink layer is derived from a photo-curable inkjet composition. The adhesive layer and ink layer can be formed in the same inkjet printing process and cured in a common photo-curing station. A stack of the adhesive signs can be assembled without interleaving a release liner between each pair of signs.

In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (D.sub.p), a critical energy (E.sub.c), and a print through depth (D.sub.PT) at the wavelength λ of less than or equal to 2×D.sub.p.

In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (D.sub.p), a critical energy (E.sub.c), and a print through depth (D.sub.PT) at the wavelength λ of less than or equal to 2×D.sub.p.

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerisable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerisable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

The present disclosure is drawn inkjet inks, which can include an aqueous ink vehicle and a pigment particle having a block copolymer attached to a surface of the pigment particle. The block copolymer can be linked to the surface through a nitrogen atom-containing coupling group bonded to the surface through the nitrogen atom. The block copolymer can include a steric stabilizing block formed by polymerizing a monomer having a sterically bulky group, and an ionic stabilizing block formed by polymerizing a monomer having an acidic group or a basic group.

Described herein are inks and coating compositions curable by exposure to UV energy sources including UV-LED energy sources, which include a polymerizable component selected from an ethylenically unsaturated materials, a photoinitiator component that is one or more photoinitiators, one of which is an acyl phosphine oxide photoinitiator; and a Group IV metal chelating agent. Improved cured is realized for the described inks and coating compositions.

Described herein are inks and coating compositions curable by exposure to UV energy sources including UV-LED energy sources, which include a polymerizable component selected from an ethylenically unsaturated materials, a photoinitiator component that is one or more photoinitiators, one of which is an acyl phosphine oxide photoinitiator; and a Group IV metal chelating agent. Improved cured is realized for the described inks and coating compositions.

An object is to obtain a photocurable inkjet printing ink composition that demonstrates excellent preservation stability and discharge stability, good adhesion, bending tolerance property, and tackiness, and high hardness. As a solution, a photocurable inkjet printing ink composition containing photopolymerizable compounds and photopolymerization initiator is provided, wherein the photocurable inkjet printing ink composition satisfies the requirements of A to E: A. 3,3,5-trimethyl cyclohexyl acrylate is contained by 5 to 50 percent by mass in all photopolymerizable compounds; B. multifunctional monomers and/or multifunctional oligomers of 10° C. or lower in glass transition temperature are contained by 1 to 15 percent by mass in all photopolymerizable compounds; C. monofunctional monomers are contained by a total of 40 percent by mass or more in all photopolymerizable compounds; D. amino group and/or amide group-containing monomers and/or oligomers are contained; and E. the ink composition has a viscosity of 10 mPa.Math.s or lower at 25° C.

An object is to obtain a photocurable inkjet printing ink composition that demonstrates excellent preservation stability and discharge stability, good adhesion, bending tolerance property, and tackiness, and high hardness. As a solution, a photocurable inkjet printing ink composition containing photopolymerizable compounds and photopolymerization initiator is provided, wherein the photocurable inkjet printing ink composition satisfies the requirements of A to E: A. 3,3,5-trimethyl cyclohexyl acrylate is contained by 5 to 50 percent by mass in all photopolymerizable compounds; B. multifunctional monomers and/or multifunctional oligomers of 10° C. or lower in glass transition temperature are contained by 1 to 15 percent by mass in all photopolymerizable compounds; C. monofunctional monomers are contained by a total of 40 percent by mass or more in all photopolymerizable compounds; D. amino group and/or amide group-containing monomers and/or oligomers are contained; and E. the ink composition has a viscosity of 10 mPa.Math.s or lower at 25° C.