A composition, method, and system for directly printing and creating complete functional 3D electronic circuits and devices without any thermal or laser post-processing treatment, by using at least Triphenylamine (TPA) as a powder binding agent. The composition can have mechanical characteristics that allow it to be melted and extruded on a structure, and electrical properties that allow it to function as at least one of a conductor, insulator, resistor, p-type semiconductor, n-type semiconductor, or capacitor.

Provided is a method for producing a cured product film, which is capable of increasing the formation accuracy of a fine cured product film and also increasing the adhesion of the cured product film.

The method for producing a curable film according to the present invention includes an application step in which a curable composition that is photocurable and thermocurable and also is in liquid form is applied using an ink jet device, a first light irradiation step in which the curable composition is irradiated with light from a first light irradiation part, and a heating step in which a precured product film irradiated with light is heated, the ink jet device has an ink tank to store the curable composition, a discharge part, and a circulation flow path part, and in the application step, the curable composition is applied while being circulated in the ink jet device.

Provided is a method for producing a cured product film, which is capable of increasing the formation accuracy of a fine cured product film and also increasing the adhesion of the cured product film.

The method for producing a curable film according to the present invention includes an application step in which a curable composition that is photocurable and thermocurable and also is in liquid form is applied using an ink jet device, a first light irradiation step in which the curable composition is irradiated with light from a first light irradiation part, and a heating step in which a precured product film irradiated with light is heated, the ink jet device has an ink tank to store the curable composition, a discharge part, and a circulation flow path part, and in the application step, the curable composition is applied while being circulated in the ink jet device.

The present invention relates to a powder of spherical crosslinkable polyamide particles, which is suitable for the selective laser sintering (SLS) technique, and also to a process for obtaining such a powder of spherical crosslinkable polyamide particles. The present invention also relates to the production of articles by SLS, followed by a crosslinking step, using said powder of spherical crosslinkable polyamide particles.

The present invention relates to a powder of spherical crosslinkable polyamide particles, which is suitable for the selective laser sintering (SLS) technique, and also to a process for obtaining such a powder of spherical crosslinkable polyamide particles. The present invention also relates to the production of articles by SLS, followed by a crosslinking step, using said powder of spherical crosslinkable polyamide particles.

In one aspect, inks for use with a three-dimensional printing system are described herein. In some embodiments, an ink described herein comprises up to about 90 wt. % monofunctional curable material, up to about 10 wt. % difunctional curable material, and up to about 10 wt. % liquid rubber, based on the total weight of the ink, wherein the liquid rubber comprises one or more curable moieties. In some cases, the liquid rubber comprises one or more ethyleneically unsaturated moieties. For example, in some instances, the liquid rubber comprises a butadiene acrylonitrile copolymer.

In one aspect, inks for use with a three-dimensional printing system are described herein. In some embodiments, an ink described herein comprises up to about 90 wt. % monofunctional curable material, up to about 10 wt. % difunctional curable material, and up to about 10 wt. % liquid rubber, based on the total weight of the ink, wherein the liquid rubber comprises one or more curable moieties. In some cases, the liquid rubber comprises one or more ethyleneically unsaturated moieties. For example, in some instances, the liquid rubber comprises a butadiene acrylonitrile copolymer.

Provided herein is a method of forming a three-dimensional object in which the polymerizable liquid includes a mixture of (i) a light polymerizable first component, and (ii) a heat polymerizable second component; the heat polymerizable second component comprising (i) a first blocked reactive constituent that is blocked with a volatile blocking group, and optionally (ii) a curative. Upon heating a formed three-dimensional intermediate sufficiently, the volatile blocking group is cleaved and vaporizes out of the three-dimensional intermediate, to form the three-dimensional object. Also provided is a three-dimensional object produced by the method. Further provided is a polymerizable liquid composition useful for carrying out the method, and prepolymers and monomers useful for the polymerizable liquid composition.

Provided herein is a method of forming a three-dimensional object in which the polymerizable liquid includes a mixture of (i) a light polymerizable first component, and (ii) a heat polymerizable second component; the heat polymerizable second component comprising (i) a first blocked reactive constituent that is blocked with a volatile blocking group, and optionally (ii) a curative. Upon heating a formed three-dimensional intermediate sufficiently, the volatile blocking group is cleaved and vaporizes out of the three-dimensional intermediate, to form the three-dimensional object. Also provided is a three-dimensional object produced by the method. Further provided is a polymerizable liquid composition useful for carrying out the method, and prepolymers and monomers useful for the polymerizable liquid composition.

A radiation curable inkjet ink comprising a polymerizable compound, a photoinitiator and a co-initiator, wherein the co-initiator is an aliphatic tertiary amine co-initiator or an aromatic co-initiator, the aromatic co-initiator selected from the group consisting of an amino substituted benzoic acid derivative, an amino substituted aromatic aldehyde and an amino substituted aromatic ketone, characterized in that the co-initiator comprises at least one functional group selected from the group consisting of an aliphatic thioether and an aliphatic disulfide.