An oligomer bearing at least one crosslinkable ethylenic unsaturation and at least one ionic bond comprises in its structure at least one aminoacrylate group and at least one tertiary amine in a form salified with at least one carboxylic acid. Also described are a process for preparing a solution of the oligomer in a reactive diluent, a crosslinkable composition comprising the oligomer, the use thereof as binder in crosslinkable compositions for temporary-use water-removable materials in coatings, hydrogels and 3D object printing, and the crosslinked material which results from polymerizing the oligomer. As a temporary-use material, the cured oligomer can be easily removed after a temporary function, by simple cleaning with water and optionally at a suitable temperature greater than the glass transition temperature of the crosslinked product.

Disclosed is an ink composition for a 3D printing supporter and a 3D printing production method using the same, in which the ink composition is usable for an inkjet 3D printer, has excellent jetting properties and is easily dissolved in water after curing so that a supporter can be easily removed. The ink composition for a 3D printing supporter comprises: an amine-containing monomer, a curing agent, and a water-soluble polymer having an amine-containing polymer.

The present invention relates to the field of 3D printing technology, and provides a photocurable 3D printing polyimide ink, and a preparation method and application thereof. The photocurable 3D printing polyimide ink includes the following components in the following weight percentages: 40 to 60% of a photocurable polyamic acid, 5 to 40% of an organic solvent, 10 to 50% of a reactive diluent, 1 to 10% of a chain extender, and 1 to 3% of a photoinitiator. The photocurable 3D printing polyimide ink provided by the present invention has excellent mechanical properties, thermal stability, relatively high printing accuracy and relatively low shrinkage; a molded device obtained by 3D printing has excellent properties including high accuracy, great dimensional stability, high strength and corrosion resistance, excellent flexibility, high temperature resistance and relatively low shrinkage. The method for preparing the photocurable 3D printing polyimide ink has a simple process and lower energy consumption.

The present invention relates to the field of 3D printing technology, and provides a photocurable 3D printing polyimide ink, and a preparation method and application thereof. The photocurable 3D printing polyimide ink includes the following components in the following weight percentages: 40 to 60% of a photocurable polyamic acid, 5 to 40% of an organic solvent, 10 to 50% of a reactive diluent, 1 to 10% of a chain extender, and 1 to 3% of a photoinitiator. The photocurable 3D printing polyimide ink provided by the present invention has excellent mechanical properties, thermal stability, relatively high printing accuracy and relatively low shrinkage; a molded device obtained by 3D printing has excellent properties including high accuracy, great dimensional stability, high strength and corrosion resistance, excellent flexibility, high temperature resistance and relatively low shrinkage. The method for preparing the photocurable 3D printing polyimide ink has a simple process and lower energy consumption.

An object is to obtain a photocurable inkjet printing ink composition that demonstrates excellent preservation stability and discharge stability, good adhesion, bending tolerance property, and tackiness, and high hardness. As a solution, a photocurable inkjet printing ink composition containing photopolymerizable compounds and photopolymerization initiator is provided, wherein the photocurable inkjet printing ink composition satisfies the requirements of A to E: A. 3,3,5-trimethyl cyclohexyl acrylate is contained by 5 to 50 percent by mass in all photopolymerizable compounds; B. multifunctional monomers and/or multifunctional oligomers of 10° C. or lower in glass transition temperature are contained by 1 to 15 percent by mass in all photopolymerizable compounds; C. monofunctional monomers are contained by a total of 40 percent by mass or more in all photopolymerizable compounds; D. amino group and/or amide group-containing monomers and/or oligomers are contained; and E. the ink composition has a viscosity of 10 mPa.Math.s or lower at 25° C.

An object is to obtain a photocurable inkjet printing ink composition that demonstrates excellent preservation stability and discharge stability, good adhesion, bending tolerance property, and tackiness, and high hardness. As a solution, a photocurable inkjet printing ink composition containing photopolymerizable compounds and photopolymerization initiator is provided, wherein the photocurable inkjet printing ink composition satisfies the requirements of A to E: A. 3,3,5-trimethyl cyclohexyl acrylate is contained by 5 to 50 percent by mass in all photopolymerizable compounds; B. multifunctional monomers and/or multifunctional oligomers of 10° C. or lower in glass transition temperature are contained by 1 to 15 percent by mass in all photopolymerizable compounds; C. monofunctional monomers are contained by a total of 40 percent by mass or more in all photopolymerizable compounds; D. amino group and/or amide group-containing monomers and/or oligomers are contained; and E. the ink composition has a viscosity of 10 mPa.Math.s or lower at 25° C.

This disclosure relates to a printing device for printing or dispensing a curable printing composition which is capable of changing color in response to the application of a magnetic field in the non-cured state. The printing device may be a handheld device such as a portable pen. The present disclosure further relates to curable compositions, cartridges and methods which may be used in combination with the aforementioned printing devices or in other applications.

This disclosure relates to a printing device for printing or dispensing a curable printing composition which is capable of changing color in response to the application of a magnetic field in the non-cured state. The printing device may be a handheld device such as a portable pen. The present disclosure further relates to curable compositions, cartridges and methods which may be used in combination with the aforementioned printing devices or in other applications.

Provided is a monomer mixture that is rapidly cured to form a cured product having high hardness, excellent alkali resistance, and excellent adhesion to a substrate. The monomer mixture of the present invention is a monomer mixture containing at least: a compound represented by Formulas (a-1) and/or (a-2); a compound (2B) including two cationically polymerizable groups per molecule, at least one of the cationically polymerizable groups being an epoxy group; a compound (3B) including three or more cationically polymerizable groups per molecule, at least one of the cationically polymerizable groups being an epoxy group; and a compound represented by Formula (c-1).

Provided is a monomer mixture that is rapidly cured to form a cured product having high hardness, excellent alkali resistance, and excellent adhesion to a substrate. The monomer mixture of the present invention is a monomer mixture containing at least: a compound represented by Formulas (a-1) and/or (a-2); a compound (2B) including two cationically polymerizable groups per molecule, at least one of the cationically polymerizable groups being an epoxy group; a compound (3B) including three or more cationically polymerizable groups per molecule, at least one of the cationically polymerizable groups being an epoxy group; and a compound represented by Formula (c-1).