The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b 1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization product A is between 0.1 and 0.8, and wherein the (meth)acrylated compound (I) that is obtained has a number average molecular weight (Mn) of between 500 and 5,000 Dalton. Typically PET is used as starting material. Typically compounds (I) of the invention have a PET content of at least 15 wt %, preferably at least 25 wt %. The present invention also relates to (meth)acrylated compounds (I) thus obtained and to coating compositions and inks based upon these materials. Materials of the invention allow the use of a high amount of PET waste. Inks and coatings prepared from these materials exhibit an excellent pigment wetting and/or ink-water balance.

The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b 1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization product A is between 0.1 and 0.8, and wherein the (meth)acrylated compound (I) that is obtained has a number average molecular weight (Mn) of between 500 and 5,000 Dalton. Typically PET is used as starting material. Typically compounds (I) of the invention have a PET content of at least 15 wt %, preferably at least 25 wt %. The present invention also relates to (meth)acrylated compounds (I) thus obtained and to coating compositions and inks based upon these materials. Materials of the invention allow the use of a high amount of PET waste. Inks and coatings prepared from these materials exhibit an excellent pigment wetting and/or ink-water balance.

A platelet-shaped pigment with a layer construction comprises the following layers in the order, optionally a carrier substrate; a transparent embossing lacquer layer with an embossed relief structure; a reflection-increasing coating which follows the relief structure and forms a reflecting microstructure, wherein the reflecting microstructure is present in the form of a mosaic of a multiplicity of reflecting mosaic elements and the reflecting mosaic elements do not reflect the incident light in the direction of the specular reflex, regarding the plane of the platelet, but in a spatial direction deviating therefrom and respectively have a lateral dimension 1 greater than 2 m.

A platelet-shaped pigment with a layer construction comprises the following layers in the order, optionally a carrier substrate; a transparent embossing lacquer layer with an embossed relief structure; a reflection-increasing coating which follows the relief structure and forms a reflecting microstructure, wherein the reflecting microstructure is present in the form of a mosaic of a multiplicity of reflecting mosaic elements and the reflecting mosaic elements do not reflect the incident light in the direction of the specular reflex, regarding the plane of the platelet, but in a spatial direction deviating therefrom and respectively have a lateral dimension 1 greater than 2 m.

An aqueous dispersion of a capsule is composed of a polymeric shell surrounding a core, the core includes one or more chemical reactants capable of forming a reaction product upon application of heat and/or radiation and the shell is stabilized by cationic dispersing groups.

The present invention provides energy curable ink and coating compositions that comprise polymerizable compounds, photoinitiators, and colorants. The polymerizable compounds comprise one or more polymerizable monomers and/or oligomers, wherein at least a portion is 3-methyl-1,5-pentanediol diacrylate. The inks and coatings of the invention exhibit excellent print properties after UV-LED, standard UV mercury vapor lamp, and electron beam cure.

The present invention provides energy curable ink and coating compositions that comprise polymerizable compounds, photoinitiators, and colorants. The polymerizable compounds comprise one or more polymerizable monomers and/or oligomers, wherein at least a portion is 3-methyl-1,5-pentanediol diacrylate. The inks and coatings of the invention exhibit excellent print properties after UV-LED, standard UV mercury vapor lamp, and electron beam cure.

An inkjet method for producing a solder mask in the manufacture of a Printed Circuit uses a solder mask inkjet ink containing at least one photo-initiator, at least one free radical polymerizable compound and at least one allyl sulfone compound as adhesion promoter. A high quality solder mask withstanding the high thermal stress during the soldering process while maintaining excellent physical properties is produced.

An inkjet method for producing a solder mask in the manufacture of a Printed Circuit uses a solder mask inkjet ink containing at least one photo-initiator, at least one free radical polymerizable compound and at least one allyl sulfone compound as adhesion promoter. A high quality solder mask withstanding the high thermal stress during the soldering process while maintaining excellent physical properties is produced.

The present invention relates to the field of and processes and printing apparatuses for producing optical effect layers (OEL) comprising magnetically oriented platelet-shaped magnetic or magnetizable pigment particles on a substrate. In particular, the present invention relates to processes using printing apparatuses comprising a first magnetic-field-generating device mounted on a transferring device (TD) and a static second magnetic-field-generating device for producing said OELs as anti-counterfeit means on security documents or security articles or for decorative purposes.