A near-infrared curable ink composition on a predetermined substrate that has excellent adhesion to the substrate when irradiated with near-infrared rays and cured, a near-infrared curable film obtained from the near-infrared curable ink composition, and stereolithography using the near-infrared curable ink composition, and contains composite tungsten oxide fine particles as near-infrared absorbing fine particles and uncured thermosetting resin, wherein the composite tungsten oxide fine particles have a XRD peak top intensity ratio value of 0.13 or more based on a XRD peak intensity ratio value of 1 on plane (220) of a silicon powder standard sample (640c produced by NIST).

A near-infrared curable ink composition on a predetermined substrate that has excellent adhesion to the substrate when irradiated with near-infrared rays and cured, a near-infrared curable film obtained from the near-infrared curable ink composition, and stereolithography using the near-infrared curable ink composition, and contains composite tungsten oxide fine particles as near-infrared absorbing fine particles and uncured thermosetting resin, wherein the composite tungsten oxide fine particles have a XRD peak top intensity ratio value of 0.13 or more based on a XRD peak intensity ratio value of 1 on plane (220) of a silicon powder standard sample (640c produced by NIST).

An aqueous radiation curable dispersant formulation includes water and styrene acrylic resin stabilized thioxanthone derivative photoinitiator particles dispersed in the water. The styrene acrylic resin stabilized thioxanthone derivative photoinitiator particles have a volume-weighted mean diameter of less than 40 nm. The styrene acrylic resin stabilized thioxanthone derivative photoinitiator particles include a water-insoluble, thioxanthone derivative photoinitiator core having one, two, or three units, wherein a structure of the unit is: and x=2-12. When the water-insoluble, thioxanthone derivative photoinitiator core includes two units or three units, the units are covalently bonded together.

The present invention provides an inkjet ink comprising: 5-40% by weight of an N-vinyl monomer selected from N-vinyl caprolactam, N-vinyl pyrrolidone, N-vinyl piperidone, N-vinyl carbazole, N-vinyl formamide, N-vinyl indole, N-vinyl imidazole, N-vinyl acetamide, and mixtures thereof, based on the total weight of the ink; one or more difunctional monomers in which the only radiation-curable functional groups present in the monomer are (meth)acrylate groups; 9% or less by weight of a monofunctional monomer, other than the N-vinyl monomer, together with a multifunctional monomer, based on the total weight of the ink; a radical photoinitiator; and a colouring agent. The present invention also provides a method of inkjet printing using the inkjet ink of the present invention and use of an N-vinyl monomer selected from N-vinyl caprolactam, N-vinyl pyrrolidone, N-vinyl piperidone, N-vinyl carbazole, N-vinyl formamide, N-vinyl indole, N-vinyl imidazole, N-vinyl acetamide, and mixtures thereof to increase the cure speed of an inkjet ink comprising one or more of difunctional monomers.

The present invention is related to a surface control additive for a radiation curing system, the method for its preparation as well as its application. The surface control additive has the following structure: ##STR00001##
wherein A is ##STR00002##
wherein m is an integer from 0 to 400, n is an integer from 1 to 500, x is an integer from 0 to 800, p is an integer from 0 to 600, q is an integer from 1 to 800, R.sup.4 and R.sup.5 are H or CH.sub.3 respectively, R.sup.6 is H or a linear or a branched alkyl group containing 1-18 carbon atoms or an acyl group containing 2-5 carbon atoms. The surface control additive of the present invention is applied to radiation curing (UV/EB) paint and inks, enables the coatings to maintain non-adhesive and smooth for a long time, and minimizes transferable precipitates from a cured film. In addition, by using different combinations of EO and PO, the surface control additive of the present invention can adapt to a free selection from high-polarity aquosity to a low-polarity aliphatic hydrocarbon solvent system.

The present invention is related to a surface control additive for a radiation curing system, the method for its preparation as well as its application. The surface control additive has the following structure: ##STR00001##
wherein A is ##STR00002##
wherein m is an integer from 0 to 400, n is an integer from 1 to 500, x is an integer from 0 to 800, p is an integer from 0 to 600, q is an integer from 1 to 800, R.sup.4 and R.sup.5 are H or CH.sub.3 respectively, R.sup.6 is H or a linear or a branched alkyl group containing 1-18 carbon atoms or an acyl group containing 2-5 carbon atoms. The surface control additive of the present invention is applied to radiation curing (UV/EB) paint and inks, enables the coatings to maintain non-adhesive and smooth for a long time, and minimizes transferable precipitates from a cured film. In addition, by using different combinations of EO and PO, the surface control additive of the present invention can adapt to a free selection from high-polarity aquosity to a low-polarity aliphatic hydrocarbon solvent system.

A method for preparing a material for use as a surface of a medical device may include printing, with an ink jet printer and using ink that is curable with ultraviolet light, content onto a surface of material that includes woven ticking fabric laminated with polyurethane. The method may also include curing the ink with the ultraviolet light. The method may also include cutting a section of the material in registration to the content printed on the surface for use in a medical device.

The present invention provides a metal oxide dispersion comprises a metal oxide, a millbase and a dispersant. The dispersant in the metal oxide is selected from a group consisting of a phosphoric acid polyester copolymer, a trimethoxysilane compound, a triethoxysilanes compound, dimethylamino ethyl methacrylate (DMAEMA) and a combination thereof, and the dispersion is substantially free of water. The metal oxide dispersion of the invention is useful for manufacturing an inkjet ink to provide a high-quality color image on a contact lens or a mold so as to produce a colored contact lens.

A print method includes a) applying an activator composition onto a recording medium, the activator composition comprising a photoinitiator; b) applying an inkjet ink composition onto the recording medium, the inkjet ink composition comprising a curable monomer and a gellant, the inkjet ink composition comprising no photo initiator or comprising a photo initiator in an amount of 1.0 wt % or less, based on the total amount of the ink composition; and c) curing the ink and the activator composition. Step c is started within a time period of 2 s-1000 s after applying the ink composition onto the recording medium. an ink set comprising an activator composition and an inkjet ink composition, a software product, and an inkjet printing apparatus are also disclosed.

A radiation curable composition including at least one organic silver salt, at least one reducing agent for the organic silver salt, and a polymerizable composition of at least one polymerizable compound, wherein the radiation curable composition is a radiation curable inkjet ink containing at least 50 wt % of a monofunctional polymerizable compound based on the total weight of the polymerizable composition. The radiation curable composition is especially useful for generating black UV light blocking borders in laminated safety glass for automotive applications.