A photocurable composition can comprise a polymerizable material and an initiator. The polymerizable material can include at least one first multi-functional monomer containing an allyloxymethyl methacrylate structure in an amount at least 5 wt % and not greater than 20 wt % based on the polymerizable material. The photocurable composition can be suitable for use in inkjet adaptive planarization and may be adapted to form cured layers having a glass transition temperature of at least 120° C.

A photocurable composition can comprise a polymerizable material and an initiator. The polymerizable material can include at least one first multi-functional monomer containing an allyloxymethyl methacrylate structure in an amount at least 5 wt % and not greater than 20 wt % based on the polymerizable material. The photocurable composition can be suitable for use in inkjet adaptive planarization and may be adapted to form cured layers having a glass transition temperature of at least 120° C.

The present invention relates to the field of the protection of security documents, especially banknotes, against illegal actions such as robbery or theft. In particular, the present invention relates to the field of ink compositions for producing irreversibly magnetically induced images or patterns, said inks comprising multichromal microspheres, preferably bichromal microspheres (1) that are orientable upon application of a magnetic field and that comprise at least a first portion (2) comprising one or more dyes and/or pigments and at least a second portion (3) comprising one or more magnetic or magnetizable materials, wherein said microspheres (1) comprise as the first portion a core (2) having a surface and comprising the one or more dyes and/or pigments and as the second portion a partial coating (3) covering at least a portion of the surface of said core (2) and comprising the one or more magnetic or magnetizable materials.

The present invention relates to the field of the protection of security documents, especially banknotes, against illegal actions such as robbery or theft. In particular, the present invention relates to the field of ink compositions for producing irreversibly magnetically induced images or patterns, said inks comprising multichromal microspheres, preferably bichromal microspheres (1) that are orientable upon application of a magnetic field and that comprise at least a first portion (2) comprising one or more dyes and/or pigments and at least a second portion (3) comprising one or more magnetic or magnetizable materials, wherein said microspheres (1) comprise as the first portion a core (2) having a surface and comprising the one or more dyes and/or pigments and as the second portion a partial coating (3) covering at least a portion of the surface of said core (2) and comprising the one or more magnetic or magnetizable materials.

An ultraviolet ray curable ink composition adapted to be ejected by using an ink jet method is provided. The ultraviolet ray curable ink composition includes a polymerizable compound, metal powder, and a liquid component having an alicyclic structure including a hetero atom. The metal powder is constituted from metal particles subjected to a surface treatment with a fluorine type silane compound and/or a fluorine type phosphoric acid ester as a surface treatment agent. An amount of the liquid component contained in the ultraviolet ray curable ink composition is in the range of 0.05 mass % or more but 7.0 mass % or less. A printed object is also provided. Such a printed object is produced by using the ultraviolet ray curable ink composition.

An ultraviolet ray curable ink composition adapted to be ejected by using an ink jet method is provided. The ultraviolet ray curable ink composition includes a polymerizable compound, metal powder, and a liquid component having an alicyclic structure including a hetero atom. The metal powder is constituted from metal particles subjected to a surface treatment with a fluorine type silane compound and/or a fluorine type phosphoric acid ester as a surface treatment agent. An amount of the liquid component contained in the ultraviolet ray curable ink composition is in the range of 0.05 mass % or more but 7.0 mass % or less. A printed object is also provided. Such a printed object is produced by using the ultraviolet ray curable ink composition.

An ink jet method records a radiation-curable ink composition containing a polymerizable compound. The radiation-curable ink composition includes a first ink composition and a second ink composition. The ink jet method includes a first discharging step of discharging the first ink composition with an ink jet head to adhere the composition to a recording medium, a first curing step of irradiating the first ink composition adhered to the recording medium with radioactive rays, a cooling step of cooling the recording medium, a second discharging step of discharging the second ink composition with the ink jet head to adhere the composition to the cooled recording medium at least in a part of the region where the first ink composition adhered; and a second curing step of irradiating the second ink composition adhered to the recording medium with radioactive rays.

A method of manufacturing metallic articles (6) including the steps of: —applying a radiation curable composition comprising a monomer including at least two polymerisable groups on a surface of a substrate thereby forming an image (2); —curing the image; —plating (4) or etching (3) a surface of the substrate not covered by the cured image by means of an alkaline solution; —removing (5) the cured image by means of an acidic solution; characterized in that a linking group between the polymerisable groups comprises at least one acid degradable or hydrolysable group selected from the group consisting of an acetal, a ketal, an orthoester, an orthocarbonate, a tertiary ester, a tertiary carbonate and a tertiary urethane and wherein the composition further comprises less than 10 wt % of other monomers including at least two polymerisable groups relative to the total weight of the polymerisable composition.

A method of manufacturing metallic articles (6) including the steps of: —applying a radiation curable composition comprising a monomer including at least two polymerisable groups on a surface of a substrate thereby forming an image (2); —curing the image; —plating (4) or etching (3) a surface of the substrate not covered by the cured image by means of an alkaline solution; —removing (5) the cured image by means of an acidic solution; characterized in that a linking group between the polymerisable groups comprises at least one acid degradable or hydrolysable group selected from the group consisting of an acetal, a ketal, an orthoester, an orthocarbonate, a tertiary ester, a tertiary carbonate and a tertiary urethane and wherein the composition further comprises less than 10 wt % of other monomers including at least two polymerisable groups relative to the total weight of the polymerisable composition.

The present invention relates to the field of security documents and their protection against counterfeit and illegal reproduction and relates to the field of intaglio printing processes for the printing of said security documents. In particular, the present invention relates to radiation curable intaglio inks suitable for intaglio printing a pattern or image, wherein said intaglio printing comprises wiping off ink excess with a polymeric wiping cylinder and cleaning said cylinder with an alkaline aqueous wiping solution, The disclosed radiation curable intaglio inks comprise one or more radiation curable compounds, wherein at least one of said one or more radiation curable compounds is a fatty acid polyester (meth)acrylate oligomer; one or more photoinitiators; and a high molecular weight acid modified alkyd surfactant and/or an alkylarene sulfonic acid surfactant; one or more fillers or extenders.