A non-Newtonian photo-curable ink composition that includes a metal oxide/alkoxysilane complex in an amount ranging from about 0.1 wt % to about 10 wt %, a salt in an amount ranging from about 0.05 wt % to about 20 wt %, a photo-initiator, an organic solvent, and water, wherein the ink composition has a first dynamic viscosity ranging from 25 cps to 10,000 cps at a first sate and a second dynamic viscosity ranging from 1 cps to 50 cps at a second state. Also described herein is a method for making such non-Newtonian photo-curable ink composition and a method for producing printed images using such non-Newtonian pho to-curable ink composition.

In one aspect, inks for use with a 3D printer are described herein. In some embodiments, an ink described herein comprises a cyclic carbonate monomer and an amine monomer. Further, in some instances, an ink described herein also comprises an ethylenically unsaturated monomer such as a (meth)acrylate. Additionally, an ink described herein, in some cases, further comprises a colorant, such as a molecular dye, a particulate inorganic pigment, or a particulate organic colorant. An ink described herein may also comprise one or more additives selected from the group consisting of inhibitors, stabilizing agents, photoinitiators, and photosensitizers.

An active-energy-ray-curable composition, a cured material of the active-energy-ray-curable composition satisfying a critical load of 5.0 g or more but 25.0 g or less, the critical load being obtained by a continuous loading test method using a variable normal load friction and wear measurement device, the cured material having an average thickness of 10 μm and being formed by coating the active-energy-ray-curable composition on a substrate and by irradiating and curing the active-energy-ray-curable composition with active energy rays having illuminance of 1.5 W/cm.sup.2 and an amount of irradiation of 200 mJ/cm.sup.2.

An active-energy-ray-curable composition, a cured material of the active-energy-ray-curable composition satisfying a critical load of 5.0 g or more but 25.0 g or less, the critical load being obtained by a continuous loading test method using a variable normal load friction and wear measurement device, the cured material having an average thickness of 10 μm and being formed by coating the active-energy-ray-curable composition on a substrate and by irradiating and curing the active-energy-ray-curable composition with active energy rays having illuminance of 1.5 W/cm.sup.2 and an amount of irradiation of 200 mJ/cm.sup.2.

The present invention relates to a novel PVC-free plastisol composition that cures at a temperature much lower than conventional plastisols. Also disclosed is a method of applying the composition.

The present invention relates to a novel PVC-free plastisol composition that cures at a temperature much lower than conventional plastisols. Also disclosed is a method of applying the composition.

To provide a non-aqueous photopolymerizable composition, which contains: a polymerizable monomer; a polymerization initiator; and a polyether-modified polysiloxane compound represented by the following general formula (1): <General Formula (1)> (CH.sub.3).sub.3Si—O—[Si(CH.sub.3).sub.2—O].sub.a—[Si(CH.sub.3)(X)—O].sub.b—Si(CH.sub.3).sub.3 where X represents R(C.sub.2H.sub.4O).sub.c(C.sub.3H.sub.6O).sub.d—R′, R is a single bond or an alkylene group, R′ is a hydrogen atom or an alkyl group, and a to d each denote an average polymerization degree including a case where either c or d is 0.

A decorative sheet manufacturing method of the present invention is for manufacturing a frosted glass-like decorative sheet using an inkjet printer including a head unit provided with a plurality of nozzles for jetting liquid droplets of an ultraviolet curable ink and an ultraviolet irradiation unit that moves together with the head unit in a main scanning direction of the head unit and irradiates the liquid droplets jetted from the nozzles and landed on a main surface of a transparent base material with ultraviolet rays, the frosted glass-like decorative sheet having the transparent base material and a plurality of dots formed in a print region on the main surface of the transparent base material and formed of a cured product of the ultraviolet curable ink by carrying out inkjet printing having predetermined printing conditions in a multi-pass manner.

A decorative sheet manufacturing method of the present invention is for manufacturing a frosted glass-like decorative sheet using an inkjet printer including a head unit provided with a plurality of nozzles for jetting liquid droplets of an ultraviolet curable ink and an ultraviolet irradiation unit that moves together with the head unit in a main scanning direction of the head unit and irradiates the liquid droplets jetted from the nozzles and landed on a main surface of a transparent base material with ultraviolet rays, the frosted glass-like decorative sheet having the transparent base material and a plurality of dots formed in a print region on the main surface of the transparent base material and formed of a cured product of the ultraviolet curable ink by carrying out inkjet printing having predetermined printing conditions in a multi-pass manner.

Disclosed is an ink composition for photo-curable ink jet printing, comprising (A) at least one selected from the group consisting of hexanediol acrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, and hydroxy pivalic acid neopentyl glycol diacrylate, (B) at least one of vinyl amide monomer and acryloyl amine monomer, (C) an acrylated amine compound having two photopolymerizable functional groups and two amino groups in a molecule, (D) a monofunctional monomer (excluding vinyl amide monomer which is the (B) component), and a photopolymerization initiator, wherein a content of the (A) component is 40 to 70% by mass, wherein a content of the (B) component is 5 to 30% by mass, wherein a content of the (C) component is 0.1 to 15% by mass, and wherein a viscosity is 200 mPa.Math.s or less.