An image recording apparatus includes: a jetting head which is movable in a main scanning direction and which has nozzles configured to jet an ultraviolet-curable type ink onto a printing medium; a light source which is configured to irradiate the ultraviolet-curable type ink jetted onto the printing medium with an ultraviolet ray; a movement mechanism which is configured to relatively move the printing medium with respect to the jetting head in a subsidiary scanning direction orthogonal to the main scanning direction; and a controller. The controller is configured to cause the ink contained in the jetting head to be agitated without jetting the ink at least during irradiation with the ultraviolet ray by the light source.

Provided is an active energy ray-curable ink composition for offset printing capable of achieving superior gloss of printed matter. The ink composition comprises a compound having at least one ethylenically unsaturated bond and a photopolymerization initiator, wherein a group of materials having no ethylenically unsaturated bonds, having a specified SP value, and exhibiting a liquid state at room temperature is added to the ink composition up to the upper limit depending on the SP value. Examples of such a group of materials include castor oil, hardened castor oil, polymerized castor oil, coconut oil, palm kernel oil, epoxidized fats and oils, alkylphenols having C15-C18 alkyl groups, cashew nut shell liquid, polymers of cashew nut shell, and modified derivatives of cashew nut shell liquid.

Provided is an active energy ray-curable ink composition for offset printing capable of achieving superior gloss of printed matter. The ink composition comprises a compound having at least one ethylenically unsaturated bond and a photopolymerization initiator, wherein a group of materials having no ethylenically unsaturated bonds, having a specified SP value, and exhibiting a liquid state at room temperature is added to the ink composition up to the upper limit depending on the SP value. Examples of such a group of materials include castor oil, hardened castor oil, polymerized castor oil, coconut oil, palm kernel oil, epoxidized fats and oils, alkylphenols having C15-C18 alkyl groups, cashew nut shell liquid, polymers of cashew nut shell, and modified derivatives of cashew nut shell liquid.

A decorative sheet manufacturing method of the present invention is for manufacturing a frosted glass-like decorative sheet using an inkjet printer including a head unit provided with a plurality of nozzles for jetting liquid droplets of an ultraviolet curable ink and an ultraviolet irradiation unit that moves together with the head unit in a main scanning direction of the head unit and irradiates the liquid droplets jetted from the nozzles and landed on a main surface of a transparent base material with ultraviolet rays, the frosted glass-like decorative sheet having the transparent base material and a plurality of dots formed in a print region on the main surface of the transparent base material and formed of a cured product of the ultraviolet curable ink by carrying out inkjet printing having predetermined printing conditions in a multi-pass manner.

A decorative sheet manufacturing method of the present invention is for manufacturing a frosted glass-like decorative sheet using an inkjet printer including a head unit provided with a plurality of nozzles for jetting liquid droplets of an ultraviolet curable ink and an ultraviolet irradiation unit that moves together with the head unit in a main scanning direction of the head unit and irradiates the liquid droplets jetted from the nozzles and landed on a main surface of a transparent base material with ultraviolet rays, the frosted glass-like decorative sheet having the transparent base material and a plurality of dots formed in a print region on the main surface of the transparent base material and formed of a cured product of the ultraviolet curable ink by carrying out inkjet printing having predetermined printing conditions in a multi-pass manner.

A white ink composition comprises an ink vehicle comprising at least one compound chosen from acrylate monomers, methacrylate monomers, acrylate oligomers and methacrylate oligomers; at least one polyol adhesive resin that is solid at 25° C.; at least one photoinitiator; and at least one white colorant. A method of printing the ink composition is also disclosed.

A white ink composition comprises an ink vehicle comprising at least one compound chosen from acrylate monomers, methacrylate monomers, acrylate oligomers and methacrylate oligomers; at least one polyol adhesive resin that is solid at 25° C.; at least one photoinitiator; and at least one white colorant. A method of printing the ink composition is also disclosed.

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

The present invention addresses the problem of providing a protection member which is for a semiconductor and has excellent pattern retention at high temperatures and moisture resistance and has good adhesion to a semiconductor circuit, etc. for long period of time. The protection member which is for a semiconductor and solves said problem, includes a cured article of an organic polymerizable compound having a functional group containing an oxygen atom and/or a nitrogen atom. The absolute value of the difference between the linear expansion coefficient at 150° C. of the cured article and the linear expansion coefficient at 25° C. of the cured article is 55 or less.

The present invention addresses the problem of providing a protection member which is for a semiconductor and has excellent pattern retention at high temperatures and moisture resistance and has good adhesion to a semiconductor circuit, etc. for long period of time. The protection member which is for a semiconductor and solves said problem, includes a cured article of an organic polymerizable compound having a functional group containing an oxygen atom and/or a nitrogen atom. The absolute value of the difference between the linear expansion coefficient at 150° C. of the cured article and the linear expansion coefficient at 25° C. of the cured article is 55 or less.