An aqueous polyurethane resin having a cationic group in a side chain thereof is obtainable by reacting a polyester polyol, a polyisocyanate, and a diol containing a quaternary N-atom or amino group, the quaternary N-atom or amino group being not present in the carbon chain between the two hydroxyl groups of the diol. The polyester polyol is obtained by reacting an aromatic polycarboxylic acid and a polyol. The polyurethane resin is suitable as a resin in treatment liquids for inkjet printing.

Polymer resins for the vat photopolymerization of thermoplastics are provided, in particular for the vat photopolymerization of thermoplastics with exception thermal stability and mechanical properties. In some aspects, the polymer resins are prepared by ring opening of an aromatic dianhydride with an alcohol containing an acrylate or methacrylate to produce a photocrosslinkable diacid monomer; conversion of the photocrosslinkable diacid monomer to a photocrosslinkable diacyl chloride; and polymerization of the photocrosslinkable diacyl chloride with an aromatic diamine to produce a photocrosslinkable precursor polymer. Upon crosslinking and drying, a thermal imidization can yield aromatic polyimide polymers with high yield and with micron-scale structural resolution.

Polymer resins for the vat photopolymerization of thermoplastics are provided, in particular for the vat photopolymerization of thermoplastics with exception thermal stability and mechanical properties. In some aspects, the polymer resins are prepared by ring opening of an aromatic dianhydride with an alcohol containing an acrylate or methacrylate to produce a photocrosslinkable diacid monomer; conversion of the photocrosslinkable diacid monomer to a photocrosslinkable diacyl chloride; and polymerization of the photocrosslinkable diacyl chloride with an aromatic diamine to produce a photocrosslinkable precursor polymer. Upon crosslinking and drying, a thermal imidization can yield aromatic polyimide polymers with high yield and with micron-scale structural resolution.

Disclosed are an electroluminescent polymer based on phenanthroimidazole units, a preparation method therefor, and the use thereof. The electroluminescent polymer based on phenanthroimidazole units has a structure as shown in the formula (I), and the side chain thereof contains phenanthroimidazole units. The electroluminescent polymer (1) has the properties of hybridized local and charge-transfer states, which can improve the utilization of excitons and the electroluminescence properties of devices by means of reverse inter-system crossing to effectively utilize triplet state excitons; (2) the phenanthroimidazole unit has a large degree of conjugation and a strong rigidity, which can not only improve the thermal stability of a material, but can also increase the radiation transition rate of the material and improve the light-emitting efficiency thereof; and (3) the raw materials of the polymer are cheap, the synthetic route is simple, and purification is convenient, which is beneficial for industrial scaled-up production thereof. The polymer has a good solubility, and can be used to prepare large-area flexible display devices by means of a solution processing technology. The polymer has great development potential and prospects in the field of organic electronic display.

##STR00001##

Disclosed are an electroluminescent polymer based on phenanthroimidazole units, a preparation method therefor, and the use thereof. The electroluminescent polymer based on phenanthroimidazole units has a structure as shown in the formula (I), and the side chain thereof contains phenanthroimidazole units. The electroluminescent polymer (1) has the properties of hybridized local and charge-transfer states, which can improve the utilization of excitons and the electroluminescence properties of devices by means of reverse inter-system crossing to effectively utilize triplet state excitons; (2) the phenanthroimidazole unit has a large degree of conjugation and a strong rigidity, which can not only improve the thermal stability of a material, but can also increase the radiation transition rate of the material and improve the light-emitting efficiency thereof; and (3) the raw materials of the polymer are cheap, the synthetic route is simple, and purification is convenient, which is beneficial for industrial scaled-up production thereof. The polymer has a good solubility, and can be used to prepare large-area flexible display devices by means of a solution processing technology. The polymer has great development potential and prospects in the field of organic electronic display.

##STR00001##

An ink composition includes an acrylic resin including a polymerization product of a first monomer having a hydroxyl group, a second monomer having an epoxy group, a third monomer having an acrylate group, and a fourth monomer having a substituted or unsubstituted phenyl group, a first curing agent having an isocyanate group, and a second curing agent having an amine group. Durability and abrasion resistance of a window may be improved.

An ink composition includes an acrylic resin including a polymerization product of a first monomer having a hydroxyl group, a second monomer having an epoxy group, a third monomer having an acrylate group, and a fourth monomer having a substituted or unsubstituted phenyl group, a first curing agent having an isocyanate group, and a second curing agent having an amine group. Durability and abrasion resistance of a window may be improved.

A conductive ink is provided, which includes an ink solvent and a conductive composition dispersed in the ink solvent. The conductive composition includes a silver nanoparticle and a molecular chain of polyaniline formed on a surface of the silver nanoparticle. A method for preparing a conductive ink and a flexible display device are further provided. The conductive ink has good film forming property and good conductivity.

A conductive ink is provided, which includes an ink solvent and a conductive composition dispersed in the ink solvent. The conductive composition includes a silver nanoparticle and a molecular chain of polyaniline formed on a surface of the silver nanoparticle. A method for preparing a conductive ink and a flexible display device are further provided. The conductive ink has good film forming property and good conductivity.

The present invention relates to the technical field of security documents comprising a security feature, such as a windowed security thread, a security foil, a security patch, a hologram or an ink printed security feature, and a protective coating, and methods of manufacturing of said security documents. The security feature has a security feature thickness t.sub.f of at least about 5 μm (micrometers) and a security feature surface facing away from the substrate consisting of a first region adjacent to the edges of the security feature and a second region non-adjacent to the edges of the security feature. The protective coating covers the security feature surface facing away from the substrate, a first substrate surface adjacent to the edges of the security feature, and a second substrate surface, which is different from the substrate surface covered by the security feature and the first substrate surface. The protective coating covering the security feature surface facing away from the substrate and the first substrate surface is transparent, the protective coating covering the first region has a thickness t.sub.b1, the protective coating covering the second region has a thickness t.sub.b2, the protective coating covering the first substrate surface has a thickness t.sub.c, and the protective coating covering the second substrate surface has a thickness t.sub.a. The thickness t.sub.c is larger than the thickness t.sub.f, which is larger than the thickness t.sub.a; the thickness t.sub.b2 is larger than the thickness t.sub.a; and either the thickness t.sub.c is larger than the thickness t.sub.b1, which is larger than or equal to the thickness t.sub.b2; or the thickness t.sub.c is equal to the thickness t.sub.b1, which is larger than the thickness t.sub.b2. The variable protective coating thickness on the surface of the security document provides the inventive security document with an increased resistance against physical and chemical attacks from the environment, while maintaining the mechanical resistance properties required for such security documents.