A 3D printing kit can include a powder bed material comprising from about 80 wt % to 100 wt % polymer particles, a fusing agent to selectively apply to the powder bed material, and a hardener to selectively apply to the powder bed material. The polymeric particles can include a polyalkylene backbone with both ethylene and propylene polymerized monomeric units with from 2 mol % to 15 mol % of the polymerized monomeric units include a grafted side chain having an epoxide moiety. The fusing agent can include water and a radiation absorber that absorbs electromagnetic energy and converts the electromagnetic energy to heat. The hardener can be present in the fusing agent or can be included in a hardening agent that is separate from the fusing agent.

A 3D printing kit can include a powder bed material comprising from about 80 wt % to 100 wt % polymer particles, a fusing agent to selectively apply to the powder bed material, and a hardener to selectively apply to the powder bed material. The polymeric particles can include a polyalkylene backbone with both ethylene and propylene polymerized monomeric units with from 2 mol % to 15 mol % of the polymerized monomeric units include a grafted side chain having an epoxide moiety. The fusing agent can include water and a radiation absorber that absorbs electromagnetic energy and converts the electromagnetic energy to heat. The hardener can be present in the fusing agent or can be included in a hardening agent that is separate from the fusing agent.

The present disclosure describes methods of printing, textile printing systems, and printers. In one example, a method of printing can include jetting an ink composition onto a substrate, the ink composition including an evaporable solvent, a colorant, and a non-curable polymeric binder. The ink composition on the substrate can be exposed to electromagnetic radiation having a wavelength from 350 nm to 420 nm. The exposure of the ink composition can begin from 0 ms to 600 ms after jetting the ink composition. The electromagnetic radiation can heat the ink composition to evaporate a portion of the evaporable solvent from the ink composition within 5 ms to 500 ms after the beginning of the exposure.

The present disclosure describes methods of printing, textile printing systems, and printers. In one example, a method of printing can include jetting an ink composition onto a substrate, the ink composition including an evaporable solvent, a colorant, and a non-curable polymeric binder. The ink composition on the substrate can be exposed to electromagnetic radiation having a wavelength from 350 nm to 420 nm. The exposure of the ink composition can begin from 0 ms to 600 ms after jetting the ink composition. The electromagnetic radiation can heat the ink composition to evaporate a portion of the evaporable solvent from the ink composition within 5 ms to 500 ms after the beginning of the exposure.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.

Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. Formation of printed objects having various colors may sometimes be desirable. Thermoplastic particulates incorporating a color-changing material capable of forming different colors under specified activation conditions may impart different colors to a printed object. Such particulate compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer and a color-changing material associated with the thermoplastic particulates, wherein the color-changing material is photochromic and thermochromic. Conjugated diynes, such as 10,12-pentacosadiynoic acid or a derivative thereof, may be particularly suitable color-changing materials having photochromic and thermochromic properties for forming a range of colors upon a printed object. Nanoparticles, particularly silica nanoparticles, associated with an outer surface of the thermoplastic particulates may enhance the brightness of the color obtained under various activation conditions and afford coloration permanence.

Provided is a resin composition, a filament and resin powder for a three-dimensional printer, a shaped object, and a production method for the shaped object, all of which make it easy to produce a shaped object and can improve, in shaping using a three-dimensional printer, the resistance to delamination of the shaped object and the resistance to warpage and shrinkage of the shaped object. A resin composition contains: inorganic fibers having an average fiber length of 1 μm to 300 μm and an average aspect ratio of 3 to 200; and a thermoplastic resin and serves as a shaping material for a three-dimensional printer.

This disclosure relates to a material set including a build material for 3-D printing including particles of a polymer comprising polymer chains having at least one reactive group that is protected with a protecting group. The material set further includes an inkjet composition including a de-protecting agent for removal of the protecting group, and a liquid carrier.

Illustrative examples of forming material suitable for use in additive manufacturing processes includes operations of: exposing a first polymer powder to a first plasma, such that an amine-functionalized powder is formed; exposing a second polymer powder to a second plasma, such that an epoxide-functionalized powder is formed; and combining the amine-functionalized powder and the epoxide-functionalized powder to form a precursor material. The precursor material is subsequently heated in an additive manufacturing process to form a structure, where heating of the precursor material causes covalent chemical bonds to form between the first polymer powder and the second polymer powder.

Illustrative examples of forming material suitable for use in additive manufacturing processes includes operations of: exposing a first polymer powder to a first plasma, such that an amine-functionalized powder is formed; exposing a second polymer powder to a second plasma, such that an epoxide-functionalized powder is formed; and combining the amine-functionalized powder and the epoxide-functionalized powder to form a precursor material. The precursor material is subsequently heated in an additive manufacturing process to form a structure, where heating of the precursor material causes covalent chemical bonds to form between the first polymer powder and the second polymer powder.