Provided are an aqueous fluorescent ink with which a fluorescent color image having an excellent color developability and lightfastness can be recorded, and an ink cartridge and an ink jet recording method using this aqueous fluorescent ink. The aqueous fluorescent ink contains a resin particle dyed with a fluorescent dye, and a quinacridone pigment. The fluorescent dye includes a basic dye having a xanthene skeleton. The resin particle has a cyano group-containing unit. A mass ratio of a content (% by mass) of the quinacridone pigment to a content (% by mass) of the fluorescent dye is 1.0 times or less. The ink cartridge includes an ink storage portion storing this aqueous fluorescent ink. An image is recorded onto a recording medium by the ink jet recording method comprising ejecting the aqueous fluorescent ink from an ink jet recording head.

This disclosure describes hydrogel three-dimensional printing kits, methods of three-dimensional printing hydrogels, and hydrogel three-dimensional printing systems. In one example, a hydrogel three-dimensional printing kit can include a particulate build material and a crosslinking agent. The particulate build material can include from about 90 wt % to 100 wt % of a polyhydroxylated swellable polymer. The crosslinking agent can include water and a crosslinker that is reactive with hydroxyl groups of the polyhydroxylated swellable polymer to crosslink the polyhydroxylated swellable polymer.

This disclosure describes hydrogel three-dimensional printing kits, methods of three-dimensional printing hydrogels, and hydrogel three-dimensional printing systems. In one example, a hydrogel three-dimensional printing kit can include a particulate build material and a crosslinking agent. The particulate build material can include from about 90 wt % to 100 wt % of a polyhydroxylated swellable polymer. The crosslinking agent can include water and a crosslinker that is reactive with hydroxyl groups of the polyhydroxylated swellable polymer to crosslink the polyhydroxylated swellable polymer.

The ink composition contains titanium oxide particles having an average particle size of 0.1 μm or more and 0.4 μm or less, hollow resin particles having an average particle size of 1.0 μm or more and 2.0 μm or less, a polysaccharide and water, wherein the titanium oxide particles and the hollow resin particles are negatively charged.

The ink composition contains titanium oxide particles having an average particle size of 0.1 μm or more and 0.4 μm or less, hollow resin particles having an average particle size of 1.0 μm or more and 2.0 μm or less, a polysaccharide and water, wherein the titanium oxide particles and the hollow resin particles are negatively charged.

One embodiment relates to a water-based ink for an inkjet containing a pigment, a fixing resin, an organic solvent and water, wherein the fixing resin includes an A-B block polymer having an A block and a B block, the A block contains a structural unit (P-1) having an anionic functional group, and the acid value of the A-B block polymer is from 5 to 80 mgKOH/g.

A curable resin composition includes: an oxetane compound (A) having one oxetanyl group as a cationic polymerizable reactive group and at least one hydroxyl group; a cationic polymerizable compound (B) which is a cationic polymerizable compound other than the oxetane compound (A) and has two or more cationic polymerization reactive groups; a rubber particle (C); and a curing agent (D), wherein the oxetane compound (A) is contained at 30 parts by mass or more and 60 parts by mass or less, based on 100 parts by mass of total mass of the oxetane compound (A) and the cationic polymerizable compound (B), and the rubber particle (C) has a group capable of reacting with the oxetane compound (A) or the cationic polymerizable compound (B) on a surface of the rubber particle (C).

The aqueous ink for ink jet contains a resin particle dyed with a fluorescent dye, and a water-soluble resin. The fluorescent dye contains a fluorescence-emitting dye selected from the group consisting of basic dye, disperse dye and oil-soluble dye, the resin particle has a core portion that contains an aromatic group-containing unit and cyano group-containing unit, and a shell portion that contains an aromatic group-containing unit, an anionic group-containing unit and a crosslinking agent-derived unit, but free of cyano group-containing unit, percentage (% by mass) of the crosslinking agent-derived unit in the shell portion is 30% by mass or more to 80% by mass or less, the water-soluble resin having an aromatic group-containing unit and an anionic group-containing unit, and the water-soluble resin having an acid value of 100 mgKOH/g or more to 180 mgKOH/g or less.

The aqueous ink for ink jet contains a resin particle dyed with a fluorescent dye, and a water-soluble resin. The fluorescent dye contains a fluorescence-emitting dye selected from the group consisting of basic dye, disperse dye and oil-soluble dye, the resin particle has a core portion that contains an aromatic group-containing unit and cyano group-containing unit, and a shell portion that contains an aromatic group-containing unit, an anionic group-containing unit and a crosslinking agent-derived unit, but free of cyano group-containing unit, percentage (% by mass) of the crosslinking agent-derived unit in the shell portion is 30% by mass or more to 80% by mass or less, the water-soluble resin having an aromatic group-containing unit and an anionic group-containing unit, and the water-soluble resin having an acid value of 100 mgKOH/g or more to 180 mgKOH/g or less.

Provided is a method of preparing a vinyl chloride-acrylic copolymer latex.

Specifically, in one embodiment of the present invention, provided is a method of preparing a latex including vinyl chloride-acrylic copolymer particles with a high degree of polymerization and high molecular weight by performing an emulsion polymerization of a vinyl chloride monomer and an acrylic monomer in the presence of an aqueous dispersion medium and an emulsifier while optimizing a feeding mode of the monomers and the emulsifier.