The present invention provides photoluminescent iron-doped barium stannate materials absorbing ultraviolet (UV) light and exhibiting strong near-infrared (NIR) luminescence. Such materials exhibit increased integrated photoluminescence intensity in comparison to known BaSnO.sub.3 and iron-doped barium stannate materials, and therefore they are particularly useful for the production of photoluminescent security ink compositions and transparent covert security features with improved anti-counterfeiting resistance that can be used for protection of documents and articles against counterfeit and illegal reproduction.

Provided are a manufacturing method of a dispersion including a step A of preparing a mixture containing an edible pigment, an edible dispersant, and water, a step B of applying a hydrostatic pressure equal to or higher than 30 MPa to the mixture, and a step C of performing a dispersion treatment on the mixture to which the hydrostatic pressure is applied; a pigment dispersion for ink jet recording and a manufacturing method thereof; and an ink composition for an ink jet and a manufacturing method thereof.

Provided are a manufacturing method of a dispersion including a step A of preparing a mixture containing an edible pigment, an edible dispersant, and water, a step B of applying a hydrostatic pressure equal to or higher than 30 MPa to the mixture, and a step C of performing a dispersion treatment on the mixture to which the hydrostatic pressure is applied; a pigment dispersion for ink jet recording and a manufacturing method thereof; and an ink composition for an ink jet and a manufacturing method thereof.

Provided is a pretreatment liquid for aqueous pigment inkjet printing which excels in adhesion to non-permeable substrates such as film substrates and which can provide printed material having good printed image quality with little mixed color bleeding and color unevenness. Also provided is an ink set including the pretreatment liquid and an aqueous pigment inkjet ink. The pretreatment liquid for aqueous pigment inkjet ink printing comprises polyolefin resin particles (A), a flocculant (B), and water. The softening temperature of the polyolefin resin particles (A) is from 50 to 100° C., and the flocculant (B) contains at least one type of substance selected from metal salts and cationic polymer compounds.

Provided is a pretreatment liquid for aqueous pigment inkjet printing which excels in adhesion to non-permeable substrates such as film substrates and which can provide printed material having good printed image quality with little mixed color bleeding and color unevenness. Also provided is an ink set including the pretreatment liquid and an aqueous pigment inkjet ink. The pretreatment liquid for aqueous pigment inkjet ink printing comprises polyolefin resin particles (A), a flocculant (B), and water. The softening temperature of the polyolefin resin particles (A) is from 50 to 100° C., and the flocculant (B) contains at least one type of substance selected from metal salts and cationic polymer compounds.

One embodiment relates to a water-based inkjet ink containing at least water, a pigment, a water-soluble organic solvent and a binder resin, wherein the water-soluble organic solvent contains at least a water-soluble organic solvent having a surface tension of 30 to 50 mN/m and a boiling point at 1 atmosphere of 180 to 230° C., in an amount of 15 to 50% by weight relative to the total weight of the water-based inkjet ink, and the acid value of the binder resin is at least 5 mgKOH/g but less than 60 mgKOH/g.

One embodiment relates to a water-based inkjet ink containing at least water, a pigment, a water-soluble organic solvent and a binder resin, wherein the water-soluble organic solvent contains at least a water-soluble organic solvent having a surface tension of 30 to 50 mN/m and a boiling point at 1 atmosphere of 180 to 230° C., in an amount of 15 to 50% by weight relative to the total weight of the water-based inkjet ink, and the acid value of the binder resin is at least 5 mgKOH/g but less than 60 mgKOH/g.

An ink set according to one embodiment of the disclosure includes a colored ink composition, which contains a pigment and is a water-based ink jet ink, and a water-based resin liquid composition which contains a resin, in which the resin liquid composition contains a urethane resin having an alicyclic structure or an aromatic ring structure and an acid value of 50 to 100 mg KOH/g.

An ink set according to one embodiment of the disclosure includes a colored ink composition, which contains a pigment and is a water-based ink jet ink, and a water-based resin liquid composition which contains a resin, in which the resin liquid composition contains a urethane resin having an alicyclic structure or an aromatic ring structure and an acid value of 50 to 100 mg KOH/g.

Provided is a processing fluid including nonionic acrylic resin particles, and a polyvalent metal salt. A volume average particle diameter of the nonionic acrylic resin particles is 100 nm or greater but 300 nm or less. A proportion of the nonionic acrylic resin particles in the processing fluid is greater than 2.0% by mass. An average reflectance of the processing fluid to light having a wavelength of 400 nm or greater but 700 nm or less is 70% or greater.