Hollow particles containing monocrystalline titanium oxide and silica, and having a titanium oxide content of 86.0-99.5 mol % and a silica content of 0.5-14.0 mol %; and a method of producing the particles. A white ink containing the hollow particles as a coloring agent; the use of the white ink in inkjet recording; and a method for inkjet recording using the white ink.

Hollow particles containing monocrystalline titanium oxide and silica, and having a titanium oxide content of 86.0-99.5 mol % and a silica content of 0.5-14.0 mol %; and a method of producing the particles. A white ink containing the hollow particles as a coloring agent; the use of the white ink in inkjet recording; and a method for inkjet recording using the white ink.

An inkjet printing device includes an ink containing unit to contain a clear aqueous ink containing a resin, a compound represented by the following Chemical formula, and water, ##STR00001##
where R.sup.1 represents an alkyl group having 1 to 4 carbon atoms, a discharging head to discharge the clear aqueous ink to printed matter to form a layer thereon in a low gloss printing mode or high gloss printing mode, and a heating device to heat the printed matter, wherein the heating device heats the printed matter satisfying the following relationship 1: Tlgloss>Thgloss 1, where Tlgloss represents the temperature of the printed matter at a low gloss printing region in the low gloss printing mode and Thgloss represents the temperature of the printed matter in the high gloss printing mode when the clear aqueous ink is attached to the printed matter.

An inkjet printing device includes an ink containing unit to contain a clear aqueous ink containing a resin, a compound represented by the following Chemical formula, and water, ##STR00001##
where R.sup.1 represents an alkyl group having 1 to 4 carbon atoms, a discharging head to discharge the clear aqueous ink to printed matter to form a layer thereon in a low gloss printing mode or high gloss printing mode, and a heating device to heat the printed matter, wherein the heating device heats the printed matter satisfying the following relationship 1: Tlgloss>Thgloss 1, where Tlgloss represents the temperature of the printed matter at a low gloss printing region in the low gloss printing mode and Thgloss represents the temperature of the printed matter in the high gloss printing mode when the clear aqueous ink is attached to the printed matter.

Disclosed are functional materials for use in additive manufacturing (AM). The functional material can comprise an elastomeric composition (e.g., a silicone composite) for use in, for example, direct ink writing. The elastomeric composition can include and elastomeric resin, and a magnetic nanorod filler dispersed within the elastomeric resin. Nanorod characteristics (e.g., length, diameter, aspect ratio) can be selected to create 3D-printed constructs with desired mechanical properties along different axes. Furthermore, since nickel nanorods are ferromagnetic, the spatial distribution and orientation of nanorods within the continuous phase can be controlled with an external magnetic field. This level of control over the nanostructure of the material system offers another degree of freedom in the design of functional parts and components with anisotropic properties. Magnetic fields can be used to remotely sense compression of the constructs, or alternatively, control the stiffness of these materials.

A fluid set for nail printing can include a primer composition including from 40 wt % to 90 wt % primer vehicle selected from an aqueous primer vehicle, an alcohol-based primer vehicle, or a combination thereof, and from 5 wt % to 50 wt % soluble polymer binder that is soluble in the primer vehicle. The fluid set can also include an aqueous inkjet ink composition including an ink vehicle and a colorant. The fluid set can also include a clear coat composition including a water-insoluble polymer.

A fluid set for nail printing can include a primer composition including from 40 wt % to 90 wt % primer vehicle selected from an aqueous primer vehicle, an alcohol-based primer vehicle, or a combination thereof, and from 5 wt % to 50 wt % soluble polymer binder that is soluble in the primer vehicle. The fluid set can also include an aqueous inkjet ink composition including an ink vehicle and a colorant. The fluid set can also include a clear coat composition including a water-insoluble polymer.

Methods for forming latexes are provided. In an embodiment, such a method comprises adding a monomer emulsion comprising water, a monomer, an acidic monomer, a hydrophilic monomer, a difunctional monomer, a first reactive surfactant, and a chain transfer agent, to a reactive surfactant solution comprising water, a second reactive surfactant, and an initiator, at a feed rate over a period of time so that monomers of the monomer emulsion undergo polymerization reactions to form resin particles in a latex. The reactive surfactant solution does not comprise monomers other than the second reactive surfactant, the reactive surfactant solution does not comprise a resin seed, and the monomer emulsion does not comprise the resin seed. The latex is characterized by a viscosity in a range of from about 10 cP to about 100 cP as measured at a solid content of about 30% and at room temperature. The latexes are also provided.

Processes for tailoring the macroscopic shape, metallic composition, mechanical properties, and pore structure of nanoporous metal foams prepared through combustion synthesis via direct write 3D printing of metal energetic ligand precursor inks made with water and an organic thickening agent are disclosed. Such processes enable production of never before obtainable metal structures with hierarchical porosity, tailorable from the millimeter size regime to the nanometer size regime. Structures produced by these processes have numerous applications including, but not limited to, catalysts, heat exchangers, low density structural materials, biomedical implants, hydrogen storage medium, fuel cells, and batteries.

Methods for forming a monodisperse latex are provided. In an embodiment, such a method comprises adding a monomer emulsion comprising water, a monomer, an acidic monomer, a multifunctional monomer, a first reactive surfactant, and a chain transfer agent, to a reactive surfactant solution comprising water, a second reactive surfactant, and an initiator, at a feed rate over a period of time so that monomers of the monomer emulsion undergo polymerization reactions to form resin particles in a monodisperse latex, wherein the reactive surfactant solution does not comprise monomers other than the second reactive surfactant, the reactive surfactant solution does not comprise a resin seed, and the monomer emulsion does not comprise the resin seed. The monodisperse latexes are also provided.