This disclosure describes three-dimensional printing kits, methods, and systems for three-dimensional printing with directionally-dependent reflective particles. In one example, a three-dimensional printing kit can include a powder bed material and a fusing agent to selectively apply to the powder bed material. The powder bed material can include polymer particles and directionally-dependent reflective particles. The directionally-dependent reflective particles can be chemically and thermally stable at a melting point temperature of the polymer particles. The fusing agent can include water and a radiation absorber to absorb radiation energy and convert the radiation energy to heat.

Aspects of the present disclosure relate to a printable medium including a polyurethane dispersion. As an example, a printable medium may include a fabric base substrate, with an image-side and a back-side. A film-forming layer may be applied to the image-side of the fabric base substrate, including an anionic polyurethane dispersion having a reactive group on a backbone of the polyurethane dispersion and a reactive group on a capping unit of the polyurethane dispersion. An ink-receiving coating layer may be applied over the film-forming layer, including a crosslink agent.

A fixer fluid can include a fixer vehicle with water, an NH-type or N-alkylated lactam co-solvent, and a phosphate ester surfactant. The fixer fluid can further include from 0.5 wt % to 12 wt % an azetidinium-containing polyamine polymer dispersed in the fixer vehicle.

Embodiments of the invention relate to a method of indirect printing with an aqueous ink. In some embodiments, an intermediate transfer member (ITM) comprising a silicone-based release layer surface is employed. For example, the release layer surface satisfies at least one of the following properties: (i) a receding contact angle of a drop of distilled water deposited on the silicone-based release layer surface is at most 60°; and (ii) a 10-second dynamic contact angle (DCA) of a drop of distilled water deposited on the silicone-based release layer surface is at most 108°. Related apparatus, systems and treatment formulations are disclosed herein.

Embodiments of the invention relate to a method of indirect printing with an aqueous ink. In some embodiments, an intermediate transfer member (ITM) comprising a silicone-based release layer surface is employed. For example, the release layer surface satisfies at least one of the following properties: (i) a receding contact angle of a drop of distilled water deposited on the silicone-based release layer surface is at most 60°; and (ii) a 10-second dynamic contact angle (DCA) of a drop of distilled water deposited on the silicone-based release layer surface is at most 108°. Related apparatus, systems and treatment formulations are disclosed herein.

A ceramic ink for digital printing, preferably for inkjet printing, comprises at least one solid part comprising at least one ceramic pigment or dye; and at least one liquid part into which said ceramic pigment or dye is dispersed and comprising one or more vehicles and/or one or more dispersants; wherein at least one of either the one or more vehicles or the one or more dispersants comprises one or more organic or inorganic silicon compounds.

A ceramic ink for digital printing, preferably for inkjet printing, comprises at least one solid part comprising at least one ceramic pigment or dye; and at least one liquid part into which said ceramic pigment or dye is dispersed and comprising one or more vehicles and/or one or more dispersants; wherein at least one of either the one or more vehicles or the one or more dispersants comprises one or more organic or inorganic silicon compounds.

The ink-jet ink of the present invention comprises a solvent S having an SP value of 9.1-9.4, resin emulsion particles and water. It is preferable that the resin emulsion particles contain a (meth)acrylic polymer. It is also preferable that the resin emulsion particles contain a structural unit derived from styrene. It is also preferable that the solvent S is tripropylene glycol monomethyl ether and/or monoethylene glycol monoisopropyl ether.

An ink, having a viscosity of 2.5 to 15 centipoise at 25° C., for textile printing includes pigment; a water dispersible anionic polymeric resin; a water soluble zero volatile organic compound solvent with a boiling point of 250° C. or greater; a crosslinking agent; and water. The water dispersible polymeric resin has particles with a median volume weighted size of less than 150 nm and a 95.sup.th percentile volume weighted size of less than 250 nm. The water dispersible polymeric resin has an acid number value of 5 to 40, a resin film elongation of 500 to 1200%, and a film tensile strength of 10 to 60 mPa.

An ink, having a viscosity of 2.5 to 15 centipoise at 25° C., for textile printing includes pigment; a water dispersible anionic polymeric resin; a water soluble zero volatile organic compound solvent with a boiling point of 250° C. or greater; a crosslinking agent; and water. The water dispersible polymeric resin has particles with a median volume weighted size of less than 150 nm and a 95.sup.th percentile volume weighted size of less than 250 nm. The water dispersible polymeric resin has an acid number value of 5 to 40, a resin film elongation of 500 to 1200%, and a film tensile strength of 10 to 60 mPa.