A printing apparatus includes an ejection head including a first nozzle row configured to eject, toward a recording medium, a first liquid containing a photopolymerization initiator and a second nozzle row configured to eject, toward the recording medium, a second liquid containing the polymerizable compound and a color material and not containing the photopolymerization initiator, a driving unit configured to change relative positions of the ejection head and the recording medium, and an irradiation unit configured to irradiate, with the light, the recording medium onto which the first liquid and the second liquid are deposited. The first liquid and the second liquid are ejected from the ejection head so that the second liquid overlaps the first liquid on a surface of the recording medium. A distance between the irradiation unit and the first nozzle row is longer than a distance between the irradiation unit and the second nozzle row.

An ink includes the following ingredients by weight: pigment: 5 to 10 wt %; dispersant: 1 to 5 wt %; photoinitiator: 5 to 8 wt %; monofunctional reactive monomer 10 to 15 wt %; multifunctional reactive monomer: 25 to 40 wt %; acrylic resin: 20 to 35 wt %; coupling agent: 2 to 5 wt %; defoamer: 0.1 to 1 wt %; and leveling agent: 0.1 to 1 wt %. The ink according to this application can concurrently meet various performance requirements such as deep curing, high adhesion, high resistance to abrasion and perspiration, and ease of correction.

The present invention relates to [1] a water-based ink containing an azomethine metal complex pigment (A), an aromatic group-containing polymer (B), an organic solvent (D) and water, in which a mass ratio of the azomethine metal complex pigment (A) to the aromatic group-containing polymer (B) [(A)/(B)] is not less than 1.4 and not more than 4, and the aromatic group-containing polymer (B) is a crosslinked polymer obtained by crosslinking an aromatic group-containing polymer (b) having an acid value of not less than 80 mgKOH/g and not more than 400 mgKOH/g with a water-insoluble polyfunctional epoxy compound (c), said water-based ink being excellent in storage stability and maintenanceability, and [2] a process for producing a pigment water dispersion liquid of particles of the aromatic group-containing polymer (B) containing the azomethine metal complex pigment (A).

The present invention relates to [1] a water-based ink containing an azomethine metal complex pigment (A), an aromatic group-containing polymer (B), an organic solvent (D) and water, in which a mass ratio of the azomethine metal complex pigment (A) to the aromatic group-containing polymer (B) [(A)/(B)] is not less than 1.4 and not more than 4, and the aromatic group-containing polymer (B) is a crosslinked polymer obtained by crosslinking an aromatic group-containing polymer (b) having an acid value of not less than 80 mgKOH/g and not more than 400 mgKOH/g with a water-insoluble polyfunctional epoxy compound (c), said water-based ink being excellent in storage stability and maintenanceability, and [2] a process for producing a pigment water dispersion liquid of particles of the aromatic group-containing polymer (B) containing the azomethine metal complex pigment (A).

An example of a composition includes a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the composition. A flow additive is present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the composition. The flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than or equal to a sintering temperature of the host metal. The elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object. The composition is spreadable, having a Hausner Ratio less than 1.25.

An example of a composition includes a host metal present in an amount ranging from about 95.00 weight percent to about 99.99 weight percent, based on a total weight of the composition. A flow additive is present in an amount ranging from about 0.01 weight percent to about 5.00 weight percent, based on the total weight of the composition. The flow additive consists of a metal containing compound that is reducible to an elemental metal in a reducing environment at a reducing temperature less than or equal to a sintering temperature of the host metal. The elemental metal is capable of being incorporated into a bulk metal phase of the host metal in a final metal object. The composition is spreadable, having a Hausner Ratio less than 1.25.

[Problem to be Solved] Provided is a curable composition for inkjet printing, a coating film obtained from which has higher heat resistance than conventional coating films. [Solution] It is a curable composition for inkjet printing, comprising (A) a (meth)acrylate monomer having a cyclic skeleton and having a number of alkylene oxide modifications of one or more and six or less, (B1) a bifunctional (meth)acrylate monomer having no cyclic skeleton and having two or more alkylene glycol structures, (B2) a bifunctional (meth)acrylate monomer having no cyclic skeleton and having a monoalkylene glycol structure, and (C) a photopolymerization initiator. Accordingly, an obtained coating film does not crack, has excellent adhesion to a conductor, and maintains sufficient hardness even after a thermal history that corresponds to a plurality of times of soldering. The above problem to be solved is also solved by a curable composition for inkjet printing, comprising (A′) a (meth) acrylate monomer having a cyclic skeleton and having a number of alkylene oxide modifications of one or more and six or less, (B1′) a bifunctional (meth)acrylate monomer having no cyclic skeleton and having two or more alkylene glycol structures, (B2′) a bifunctional (meth)acrylate monomer having no cyclic skeleton and having a monoalkylene glycol structure, and (C′) a photopolymerization initiator.

An aqueous dispersion of a capsule composed of a polymeric shell surrounding a core, the core containing an amine blocked isocyanate, the amine blocked isocyanate comprises at least two isocyanate groups blocked by a blocking group, the blocking groups are independently from each other represented by a secondary amine The aqueous dispersion is suitable as reactive binder chemistry in coatings and inks.

An aqueous dispersion of a capsule composed of a polymeric shell surrounding a core, the core containing an amine blocked isocyanate, the amine blocked isocyanate comprises at least two isocyanate groups blocked by a blocking group, the blocking groups are independently from each other represented by a secondary amine The aqueous dispersion is suitable as reactive binder chemistry in coatings and inks.

A radiation curable inkjet ink set comprising a cyan inkjet ink containing a beta-copper phthalocyanine pigment and a polymerizable composition; a magenta inkjet ink containing a magenta or red pigment and a polymerizable composition; a yellow inkjet ink containing a yellow pigment and a polymerizable composition; and a black inkjet ink containing a carbon black pigment and a polymerizable composition; wherein the polymerizable compositions of the cyan, magenta, yellow and black inkjet inks include on average: a) 20.0 to 40.0 wt % of phenoxyethyl acrylate; b) 23.0 to 32.0 wt % of isobornyl acrylate; c) 1.0 to 14.4 wt % of monomer selected from the group consisting of 4-acryloylmorpholine and a monomer according to Formula (I), wherein X represents C or O, n represents 1, 2 or 3 and m represents 0 or 1; and d) up to 14.0 wt % of a multifunctional monomer or oligomer; wherein all weight percentages (wt %) are based upon the total weight of the inkjet ink; and wherein 0, 1 or 2 of the cyan, magenta, yellow and black inkjet inks deviate in a range a) to d) and this deviation is no more than 1.0 wt %.

##STR00001##