Disclosed is a composite particle for use in a marking that is suitable for identification/authentication purposes. The particle comprises at least one superparamagnetic portion and at least one thermoluminescent portion coated with an thermoisolating portion. Optionally also a thermoconductive portion between the superparamagnetic and thermoluminscent portions.

Provided is an image recording method including an applying step of applying a pretreatment liquid containing water and an aggregating agent onto an impermeable base material and applying an ink containing water and a colorant onto a region of the impermeable base material where the pretreatment liquid has been applied, and a drying step of drying the ink applied onto the region to obtain an image, in which the drying step includes blowing of hot air at a wind speed of greater than 15 m/s to the ink applied onto the region, and in a case where the number of grams of the ink applied per 1 m.sup.2 in an image area with a density of 100% is defined as X, and the number of grams of the pretreatment liquid applied per 1 m.sup.2 in the image area with a density of 100% is defined as Y, a viscosity of a kneaded material obtained by adding (6.5Y/X) mg of the pretreatment liquid to 10 g of the ink and defoaming and kneading the mixture at 200 rpm for 5 minutes is in a range of 30 mPa.Math.s to 500 mPa.Math.s.

The present disclosure sets forth ink compositions having a biodegradable polyurethane binder that can be used for textile printing. In one example, an ink composition can include water, an organic co-solvent, a colorant, and a biodegradable polyurethane binder. The biodegradable polyurethane binder can include prepolymer segments including polymerized monomers of a diisocyanate and a diol. The diol can include to terminal 6-hydroxyhexanoate groups linked by an organic linking group. Chain extenders can connect the prepolymer segments. The chain extenders can include a polymerized diamine.

The present disclosure sets forth ink compositions having a biodegradable polyurethane binder that can be used for textile printing. In one example, an ink composition can include water, an organic co-solvent, a colorant, and a biodegradable polyurethane binder. The biodegradable polyurethane binder can include prepolymer segments including polymerized monomers of a diisocyanate and a diol. The diol can include to terminal 6-hydroxyhexanoate groups linked by an organic linking group. Chain extenders can connect the prepolymer segments. The chain extenders can include a polymerized diamine.

A white ink jet ink composition according to the present disclosure includes hollow resin particles, resin particles, and water. The hollow resin particles have a glass transition temperature of 120° C. or more, the resin particles are composed of an acrylic resin or a urethane resin, and the content of the resin particles is 5% by mass or more relative to the total mass of the ink composition.

A white ink jet ink composition according to the present disclosure includes hollow resin particles, resin particles, and water. The hollow resin particles have a glass transition temperature of 120° C. or more, the resin particles are composed of an acrylic resin or a urethane resin, and the content of the resin particles is 5% by mass or more relative to the total mass of the ink composition.

Provided are compositions and processes formulated and practiced to reduce the friction-coefficient of the printed area and also of the non-printed areas around the image, wherein the compositions are formulated for use by wet-on-wet techniques in-line of the pre-curing printing process, without pretreating the fabric for softness and smoothness prior to the printing process. The compositions comprise at least 15% by weight of a friction-coefficient reduction agent and having a pH lower than 6.5 so as to effect upon contact immobilization of an ink composition that is being digitally applied on the substrate.

Provided are compositions and processes formulated and practiced to reduce the friction-coefficient of the printed area and also of the non-printed areas around the image, wherein the compositions are formulated for use by wet-on-wet techniques in-line of the pre-curing printing process, without pretreating the fabric for softness and smoothness prior to the printing process. The compositions comprise at least 15% by weight of a friction-coefficient reduction agent and having a pH lower than 6.5 so as to effect upon contact immobilization of an ink composition that is being digitally applied on the substrate.

A printing method includes discharging ink to a substrate, heating a non-ink-discharged side of the substrate at T1, and heating an ink-discharged side of the substrate at T2, wherein the ink contains an organic solvent A (boiling point lower than 250 degrees C.), an organic solvent B (boiling point of 250 degrees C.), and a resin, where 0 degrees C. C≤T2−T1≤90 degrees C. is satisfied, the proportion (organic solvent A/ink) is 30 percent by mass or less, the proportion (organic solvent B/ink) is 1 to 3 percent by mass, the proportion (resin/ink) is 5 to 15 percent by mass, the ink has a viscosity of 8.0 to 11.0 mPa-s at 25 degrees C. and 5.5 to 11.0 mPa-s at 36 degrees C., and a 2.5 μL ink droplet discharged to the substrate shrinks to 0.1 μL within 10.0 seconds at 25 degrees C.

A form of an ink set is an ink set including a flocculant-containing treatment liquid and an ink jet ink composition and is for use in recording on a low- or non-absorbent recording medium. The ink jet ink composition is a water-based ink containing at least one colorant, at least one water-soluble organic compound, having a solubility of more than 10 g in 100 g of water at 20° C., and at least one organic compound sparingly soluble in water, having a solubility of 0.1 to 10 g in 100 g of water at 20° C. The organic compound sparingly soluble in water includes a diol or glycol ether having a normal boiling point of 180° C. to 300° C., with the diol or glycol ether constituting 2.3% by mass or less of the total mass of the ink composition.